Organization, organic molecules

Endogeneous organics Organic molecules made on the surface of a planet as part of a prebiotic chemistry, perhaps generated by Urey-Miller syntheses. 

Exogeneous organics Organic molecules delivered to a planet that may seed life in prebiotic chemistry organic molecules delivered by meteorites or comets. 

In addition, LDHs are able to concentrate selectively and organize organic molecules [198-200] For example, Pitsch et al. reported that glycolalde-hyde phosphate intercalated in LDHs from highly dilute aqueous solution can condense to racemic aldotetrose-2,4-diphosphates and aldolhexose-2,4,6-triphosphates [200], which has led to speculation about the possible role of LDHs in chemical evolution and the origins of fife. 

Dan Reger, University of South Carolina Using water to organize organic molecules into a nanostructure. 

Substances are generally soluble in like solvents. Organic molecules in molecular solvents such as CCI4, C2H5OH, ether, propanone. Inorganic salts are often soluble in water and less soluble in organic solvents. 

Sulfur might be present in inorganic forms elemental S, hydrogen sulfide H2S, carbonyl sulfide COS, or positioned within organic molecules as in the following ... 

Commercial compounds are oil-soluble organic molecules containing chlorine, sulfur or phosphorus atoms (Figure 9.12). 

Cyr D M, Venkataraman B and Flynn G W 1996 STM investigations of organic molecules physisorbed at the liquid-solid interface Chem. Mater. 8 1600... 

The BZ reaction involves the oxidation of an organic molecule (citric acid, malonic acid (MA)) by an... 

Figure Bl.1.3. State energy diagram for a typical organic molecule. Solid arrows show radiative transitions A absorption, F fluorescence, P phosphorescence. Dotted arrows non-radiative transitions.

Typical singlet lifetimes are measured in nanoseconds while triplet lifetimes of organic molecules in rigid solutions are usually measured in milliseconds or even seconds. In liquid media where drfifiision is rapid the triplet states are usually quenched, often by tire nearly iibiqitoiis molecular oxygen. Because of that, phosphorescence is seldom observed in liquid solutions. In the spectroscopy of molecules the tenn fluorescence is now usually used to refer to emission from an excited singlet state and phosphorescence to emission from a triplet state, regardless of the actual lifetimes. 

Flehre W J, Ditchfieid R and Popie J A 1972 Self-consistent molecular-orbital methods XII. Further extension of Gaussian-type basis sets for use in molecular orbital studies of organic molecules J. Chem. Phys. 56 2257-61 Flariharan P C and Popie J A 1973 The influence of polarization functions on molecular orbital hydrogenation energies Theoret. Chim. Acta. 28 213-22... 

Csizmadia I G, Flarrison M C, Moscowitz J Wand Sutcliffe B T 1966 Commentationes. Non-empirical LCAO-MO-SCF-Cl calculations on organic molecules with Gaussian type functions. Part I. Introductory review and mathematical formalism Theoret. Chim. Acta 6 191-216... 

Bigwood R, Gruebele M, Leitner D M and Wolynes P G 1998 The vibrational energy flow transition in organic molecules theory meets experiment Proc. Nati Acad. Sc/. 95 5960... 

Table B3.5.1 Number of cycles to converge for geometry optimizations of some typical organic molecules usmg Cartesian, Z-matrix and delocalized internal coordinates. ...

Hi) Surface blockers. Type 1 tlie inliibiting molecules set up a geometrical barrier on tlie surface (mostly by adsorjDtion) such as a variety of ionic organic molecules. The effectiveness is directly related to tlie surface coverage. The effect is a lowering of tlie anodic part of tlie polarization curve witliout changing tlie Tafel slope. 

Free apertures in second channel system are too small for organic molecules to diffuse readily, making the channel system of mordenite essentially monodimensional. 

Ireland J F and Wyatt PAH 1976 Acid-base properties of electronically excited states of organic molecules Adi/. Rhys. Org. Chem. 12 131-221... 

To use direct dynamics for the study of non-adiabatic systems it is necessary to be able to efficiently and accurately calculate electronic wave functions for excited states. In recent years, density functional theory (DFT) has been gaining ground over traditional Hartree-Fock based SCF calculations for the treatment of the ground state of large molecules. Recent advances mean that so-called time-dependent DFT methods are now also being applied to excited states. Even so, at present, the best general methods for the treatment of the photochemistry of polyatomic organic molecules are MCSCF methods, of which the CASSCF method is particularly powerful. 

MMVB is a hybrid force field, which uses MM to treat the unreactive molecular framework, combined with a valence bond (VB) approach to treat the reactive part. The MM part uses the MM2 force field [58], which is well adapted for organic molecules. The VB part uses a parametrized Heisenberg spin Hamiltonian, which can be illustrated by considering a two orbital, two electron description of a sigma bond described by the VB determinants... 

Jones et al. [144,214] used direct dynamics with semiempirical electronic wave functions to study electron transfer in cyclic polyene radical cations. Semiempirical methods have the advantage that they are cheap, and so a number of trajectories can be run for up to 50 atoms. Accuracy is of course sacrificed in comparison to CASSCF techniques, but for many organic molecules semiempirical methods are known to perform adequately. 

M. Klessinger and J, Michl, Excited states and photochemistry of organic molecules, VCH New York, 1994. 

Like bromine, iodine is soluble in organic solvents, for example chloroform, which can be used to extract it from an aqueous solution. The iodine imparts a characteristic purple colour to the organic layer this is used as a test for iodine (p. 349). NB Brown solutions are formed when iodine dissolves in ether, alcohol, and acetone. In chloroform and benzene a purple solution is formed, whilst a violet solution is produced in carbon disulphide and some hydrocarbons. These colours arise due to charge transfer (p. 60) to and from the iodine and the solvent organic molecules. 

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