Organic Chemistry 1 Saturated Hydrocarbons

Shkrob, LA., Sauer, M.C., Jr., Trifunac, A.D. Radiation chemistry of organic liquids saturated hydrocarbons. In Radiation Chemistry Present Status and Future Trends, Studies in Physical and Theoretical Chemistry 87, Jonah, C.D., Rao, B.S.M., Eds. Elsevier Amsterdam, 2001 175 pp. 

Radiation Chemistry of Organic Liquids Saturated Hydrocarbons. 

Orga.nic Chemistry. The organic chemistry of sulfur dioxide, particularly as it relates to food appHcations, has been discussed (246). Although no reaction takes place with saturated hydrocarbons at moderate temperatures, the simultaneous passage of sulfur dioxide and oxygen into an alkane in the presence of a free-radical initiator or ultraviolet light affords a sulfonic acid such as hexanesulfonic acid [13595-73-8]. This is the so-called sulfoxidation reaction (247) ... 

Classical organic chemistry provides a wide variety of potential analytes for electron ionization, the only limitation being that the analyte should be accessible to evaporation or sublimation without significant thermal decomposition. These requirements are usually met by saturated and unsaturated aliphatic and aromatic hydrocarbons and their derivatives such as halides, ethers, acids, esters, amines, amides etc. Heterocycles generally yield useful El spectra, and flavones, steroids, terpenes and comparable compounds can successfully be analyzed by El, too. Therefore, El represents the standard method for such kind of samples. 

Compounds of carbon with hydrogen and other elements form the vast area of organic chemistry. Silanes and germanes are Si and Ge analogous of methane and short-chain saturated hydrocarbons, and can be prepared by various methods, such as reduction of halides with LiAlH4 ... 

Ultra high vacuum studies of nickel and platinum with simple organic molecules like olefins and arenes are described. These surface chemistry studies were done as a function of surface crystallography and surface composition. The discussion is limited to the chemistry of methyl isocyanide, acetonitrile, benzene and toluene, pyridine, trimethylphosphine, ethylene, acetylene and saturated hydrocarbons. Molecular orbital calculations are presented that support the experimental identification of the importance of C-H-M metal bonding for metal surfaces. 

Define or identify each of the following terms (a) organic chemistry, (b) total bond order, (c) condensed formula, (d) structural formula, (e) fine formula, (/) hydrocarbon, (g) alkane, (h) aUcene, (/) alkyne, j) aromatic hydrocarbon, (k) saturated, (1) delocalized double bond, (m) isomerism, (n) cycloalkane, (o) radical, (p) functional group, (q) alcohol, (r) ether, (s) aldehyde, (f) ketone, (u) carbonyl group, and (v) ester. 

Every teacher of the first course of organic chemistry, towards its beginning, emphasizes the different behavior of saturated and olefinic hydrocarbons towards halogens. The influence of ring strain is discussed rather later in the course. And a good thing too, for... 

As first noted by Seki and coworkers [12] and later confirmed by Kahn and coworkers [13] even in the most simple cases this approximation does not hold. When saturated hydrocarbons, which are among the least reactive molecules in organic chemistry, are deposited onto the most inert metal, Au, a reduction of the work function on the order of 1 eV can be seen. It is interesting to note that this work function lowering has about the same amount encountered when an electro-positive element like Cs is deposited on a metal surface. These changes of the work-function even in the absence of any chemical interaction (like charge transfer or bond formation) are attributed to the formation of an interface dipole located between the molecule and the metal substrate. 

Chapter 11 An Introduction to Organic Chemistry The Saturated Hydrocarbons... 

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