Nuclear reaction analysis

This overview covers the major teclnhques used in materials analysis with MeV ion beams Rutherford backscattering, chaimelling, resonance scattering, forward recoil scattering, PIXE and microbeams. We have not covered nuclear reaction analysis (NRA), because it applies to special incident-ion-target-atom combinations and is a topic of its own [1, 2]. 

All the techniques discussed here involve the atomic nucleus. Three use neutrons, generated either in nuclear reactors or very high energy proton ajccelerators (spallation sources), as the probe beam. They are Neutron Diffraction, Neutron Reflectivity, NR, and Neutron Activation Analysis, NAA. The fourth. Nuclear Reaction Analysis, NRA, uses charged particles from an ion accelerator to produce nuclear reactions. The nature and energy of the resulting products identify the atoms present. Since NRA is performed in RBS apparatus, it could have been included in Chapter 9. We include it here instead because nuclear reactions are involved. 

Nuclear reaction analysis (NRA) is used to determine the concentration and depth distribution of light elements in the near sur ce (the first few lm) of solids. Because this method relies on nuclear reactions, it is insensitive to solid state matrix effects. Hence, it is easily made quantitative without reference to standard samples. NRA is isotope specific, making it ideal for isotopic tracer experiments. This characteristic also makes NRA less vulnerable than some other methods to interference effects that may overwhelm signals from low abundance elements. In addition, measurements are rapid and nondestructive. 

Figure 7 Lateral profiles of carbon and lithium measured by nuclear reaction analysis.

W. K. Chu, J. W. Mayer, and M. -A. Nicolet. Backscattering Spectrometry. Academic Press, New York, 1978, brief section on nuclear reaction analysis, discussions on energy loss of ions in materials, energy resolution, surface barrier detectors, and accelerators also applicable to NRA ... 

Metastable quenching spectroscopy Nuclear Reaction Analysis Rutherford back-scattering spectroscopy (or HEIS high-energy ion scattering)... 

Fig. 5. Hydrogen depth profile of a deuterated polystyrene PS(D) film deposited on a protonated polystyrene PS(H) film on top of a silicon wafer as obtained by l5N-nuclear reaction analysis ( 5N-NRA). The small hydrogen peak at the surface is due to contamination (probably water) of the surface. The sharp interface between PS(D) and PS(H) is smeared by the experimental resolution (approx. 10 nm at a depth of 80 nm) [57], The solid line is a guide for the eye...

Neutron Activation Analysis X-Ray Fluorescence Particle-Induced X-Ray Emission Particle-Induced Nuclear Reaction Analysis Rutherford Backscattering Spectrometry Spark Source Mass Spectrometry Glow Discharge Mass Spectrometry Electron Microprobe Analysis Laser Microprobe Analysis Secondary Ion Mass Analysis Micro-PIXE... 

Nuclear reaction analysis (NRA) also identifies emitted particles which are different from the incident ones. In order to avoid permanent radioactivity, the energy of the projectile is maintained below 6 MeV, so that it is used primarily to determine the concentration and depth of light elements (Z < 9) in the near surface of solids. 

The conservation of energy during the nuclear reaction analysis experiment may be expressed ... 

Demortier, G. (2000) Nuclear Reaction Analysis in Encyclopedia of Analytical Chemistry , John Wiley Sons, Chichester. 

ZnS Mn ZnCl2,MnCl2 Na2S XRD, UV, RBS, nuclear reaction analysis, SEM 9, 61... 

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