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Nonaromatic compounds

Macrocyclic quinolizidine or 1-oxaquinolizidine alkaloids, aragu-spongines B-H (236-242) and J (243) (206) and aragupetrosine A (244) (207) were isolated from an Okinawan sponge (Xestospongia sp.) together with the previously known petrosin (245) (208) and petrosin A (246) (209). These alkaloids show vasodilating activity. [Pg.75]

The Mediterranean sponge Reniera sarai is a rich source of new macro-cyclic alkaloids, named sarains, which may be biogenetically related to petrosin (246) or araguspongins (236-243). The structures of sarains 1-3 (247-249) (2/0) and isosarain 1 (250) (211) were clarified on the basis of extensive spectroscopic analyses. The position of the double bond in 249 remains to be determined. The more polar fraction of this sponge contained three UV-absorbing alkaloids, named sarains A-C. The structure of the diacetylated derivative of sarain A (251) was established by X-ray analyis (2/2). [Pg.76]

From a Japanese sponge of the genus Haliclona two cytotoxic alkaloids, haliclamines A and B (252 and 253), were isolated (213). They are proposed to be biogenetic precursors of the petrosins or sarains. [Pg.76]


In such cases, a side reaction that sometimes occurs is expansion of the six-membered ring. Ring expansion can occur even with nonaromatic compounds, when... [Pg.1088]

Some examples of different types of hydrocarbons are given in Figure 9.1. Nonaromatic compounds without ring structure are termed aliphatic, whereas those with a ring structure (e.g., cyclohexane) are termed alicyclic. Aromatic hydrocarbons often consist of several fused rings, as in the case of benzo[a]pyrene. [Pg.181]

Reduction of dienes and polyenes has attracted much attention since it is important from both practical and theoretical aspects. In these reactions the major interest is the selective reduction of a double bond in the presence of another. In general, saturation of all the multiple double bonds of nonaromatic compounds can be carried out with any of the catalysts which are suitable for low-pressure reductions or with some reducing chemicals. [Pg.991]

Note May contain minute quantitities of benzene, butylbenzene, xylenes, and nonaromatic compounds as impurities. Technical grades may contain as much as 10% benzene. [Pg.1053]

The refractive index, d, is a measure of induced polarizability. Dispersion forces are especially high for aromatic hydrocarbons, which have highly polarizable k electrons. This is reflected in the high refractive indices of aromatic compounds, often 0.1 to 0.2 units higher than comparable nonaromatic compounds (table 3.5). Solvents with high polarizabilities are often good solvents for soft anions (i.e., those with high polarizabilities) such as SCN, F, and fF... [Pg.57]

The most obvious compound in which to look for a closed loop of four electrons is cyclobutadiene (44).135 Hiickel s rule predicts no aromatic character here, since 4 is not a number of the form 4n + 2. There is a long history of attempts to prepare this compound and its simple derivatives, and, as we shall see, the evidence fully bears out Hiickel s prediction— cyclobutadienes display none of the characteristics that would lead us to call them aromatic. More surprisingly, there is evidence that a closed loop of four electrons is actually ami-aromatic.1 If such compounds simply lacked aromaticity, we would expect them to be about as stable as similar nonaromatic compounds, but both theory and experiment show that they are much less stable.137 An antiaromatic compound may be defined as a compound that is destabilized by a closed loop of electrons. [Pg.53]

No specific review of aromatic azapentalenes exists, though much of the work before 1960 is covered in a more general article on bicyclic heterocycles with bridgehead nitrogen atoms by Mosby6 in the Weissberger series on heterocyclic chemistry. That article makes no distinction between aromatic and saturated systems, and the present review, though not exhaustive, deals mainly with aromatic systems and covers most of the literature to the end of 1975. Nonaromatic compounds will not be treated except where they are sufficiently important. [Pg.185]

However, certain nonaromatic compounds are included, e.g., 25a38 and 26a39 for which it is possible to write aromatic tautomers (25b and 26b). [Pg.191]

Other examples of intramolecularly coordinated (by 0 as well as by N groups) organolithium compounds can be found in Setzer and Schleyer (2) and Seebach (4). Two recent reviews are also pertinent. Klumpp (34) deals with 0- and N-assisted lithiation and carbolithiation of nonaromatic compounds, and Snieckus (34a) deals with directed (by amide and carbamate groups) ortho metalation in polysubstituted aromatics. [Pg.51]

Cyclooctatetraene (or simply cyclooctatetraene) is a bright-yellow, nonplanar, nonaromatic compound (Section 21-9A). Apparently the resonance energy of a planar structure is insufficient to overcome the unfavorable angle strain the planar structure would have with its C-C-C bond angles of 135°. Cyclooctatetraene normally assumes a tub structure with alternating single and double bonds ... [Pg.1085]

Somewhat similar are the so-called adductive crystallization processes, often (wrongly) called extractive crystallization, where reactions of complex/ adduct formation are used to separate compounds that are otherwise difficult to separate. Examples of adductive crystallization include separation of p- and m-cresols (137), separation of o- and p - n i troch I oro ben zcn cs (138), separation of quinaldine and isoquinoline (139), separation of nonaromatic compounds from naphtha-cracking raffinate (140), and separation of p-cresol from 2,6-xylenol (141). Other examples of reactive crystallization/precipitation reported in the literature are listed in Table 5. [Pg.284]

Strong nucleophiles such as organolithium or organomagnesium derivatives do not react with substituted or unsubstituted phosphabenzene or arsabenzene (39, Y = P or As) by nucleophilic substitution as in the case of pyridines, but by addition to the heteroatom forming intermediate anions 40. These can then be converted into nonaromatic compounds by reaction with water to yield 1-alkyl-1,2-dihydro-derivatives 41, or they can be alkylated by an alkyl halide with the same or a different alkyl group, when two products may result a 1,2-dialkyl-1,2-dihydro 40-derivative 42, or a -derivative 43. The former products are kinetically controlled, whereas the latter compounds are thermodynamically controlled, so that one may favor the desired product by choosing the appropriate reaction conditions. [Pg.229]

Nitro alcohols are nonaromatic compounds containing both -OH and -N02 groups. A typical example of such a compound is 2-nitro-l-butanol, shown below. These compounds are used in chemical synthesis to introduce nitro functional groups or (after reduction) amino groups onto molecules. They tend to have low volatilities and moderate toxicities. The aromatic nitrophenol, / -nitrophenol, is an industrially important compound with toxicological properties resembling those of phenol and nitrobenzene. [Pg.331]

From all the above calculations, one arrives at a conclusion that 1,2-dihydrodiazetes are simply constrained nonaromatic heterocycles that do not benefit from aromatic stabilization. Also, these compounds undergo facile Diels-Alder reactions or bromination reactions, with no tendency to regain the 7t-structure and are thus characteristic for typical nonaromatic compounds. [Pg.628]

The heavier feedstocks produce appreciable amounts of butadiene aromatic mixtures, commonly referred to as BTXs and heavy nonaromatic compounds. [Pg.536]

The classical Claisen rearrangement is the first and slow step of the isomerization of allyl aryl ethers to orlho-a ly lated phenols (Figure 14.46). A cyclohexadienone A is formed in the actual rearrangement step, which is a [3,3]-sigmatropic rearrangement. Three valence electron pairs are shifted simultaneously in this step. Cyclohexadienone A, a nonaromatic compound, cannot be isolated and tautomerizes immediately to the aromatic and consequently more stable phenol B. [Pg.632]

Aromatic, Antiaromatic, and Nonaromatic Compounds 722 16-6 Huckel s Rule 722... [Pg.16]


See other pages where Nonaromatic compounds is mentioned: [Pg.55]    [Pg.59]    [Pg.104]    [Pg.170]    [Pg.457]    [Pg.6]    [Pg.6]    [Pg.26]    [Pg.307]    [Pg.381]    [Pg.106]    [Pg.262]    [Pg.57]    [Pg.49]    [Pg.248]    [Pg.342]    [Pg.647]    [Pg.345]    [Pg.244]    [Pg.74]    [Pg.63]    [Pg.627]    [Pg.150]    [Pg.288]    [Pg.12]    [Pg.447]    [Pg.448]    [Pg.722]    [Pg.747]   
See also in sourсe #XX -- [ Pg.722 ]

See also in sourсe #XX -- [ Pg.714 ]

See also in sourсe #XX -- [ Pg.643 ]

See also in sourсe #XX -- [ Pg.649 , Pg.650 ]




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