Nitrous oxide , dissolved gases water

A car with this modification produces NO carbon dioxide and NO carbon monoxide, but since air is mixed with the gas combustion, it is likely that the greenhouse gas Nitrous Oxide is produced. But Nitrous Oxide dissolves reasonably well in water, so since the exhaust gasses are passed through the header tank which contains the water fuel, it is likely that this engine arrangement is a good deal greener than most. 

As shown in Table II, in the presence of polymer, the enclosed nitrous oxide is completely consumed during irradiation. In the place of nitrous oxide, nitrogen and water are formed. The yield of nitrogen or water corresponds stoichiometrically to the loss of nitrous oxide. A large G value, about 2000, is given for the disappearance of nitrous oxide. Estimation of the G value is based on the assumption that the available energy for the consumption is only that absorbed directly by the gas dissolved in the polymer solid. The G values for the formation of water and nitrogen should be equal to 2000. Moreover, the summation of the amount of the excess formation of crosslinks and unsaturation becomes stoichiometrically almost equal to the loss of nitrous oxide, as shown in Table III. The equation of material balance of nitrous oxide, therefore, should be written as follows ... 

Assuming the randomness factor is about the same, the gas with the larger heat effect (favoring dissolving) should have the higher solubility. The measured solubilities at one atmosphere pressure and 20°C of oxygen and nitrous oxide in water are, respectively, 02, 1.4 X 10-3 mole/liter and N20, 27 X 10-3 mole/liter, consistent with our prediction.. 

The blue gas dinitrogen trioxide, N203 (Fig. 15.6, 1), in which the oxidation number of nitrogen is +3, is the anhydride of nitrous acid, HN02, and forms that acid when it dissolves in water ... 

Nitrous oxide (N20), commonly known as laughing gas, is a colorless and virtually odorless, tasteless, nontoxic gas. Nitrous oxide is an oxidizer that will support combustion, but it is a nonflammable gas. It is water-soluble but when it is dissolved, its acidity does not change. 

Nitrous oxide is quite soluble in water. At 0 °C, a volume of water dissolves 1.3 times its volume of N20 at 1 atm pressure. It is used as a propellant gas in canned whipped cream, and it has been used as an anesthetic (laughing gas). The melting point of N20 is -91 °C and the boiling point is -88 °C. 

Nitrous Oxide occurs as a colorless gas. One liter at 0° and 760 mm Hg weighs about 1.97 g. One volume dissolves in about 1.4 volumes of water at 20° and 760 mm Hg. It is freely soluble in alcohol and soluble in ether and in oils. 

Figure 16.10 (A) Nitrous oxide (N2O) concentrations and isotopic composition for water samples collected at Station ALOHA. [Left] Depth profile of N2O showing a distinct mid-depth maximum of 60 nM coincident with the dissolved oxygen minimum. [Center] N isotope composition of N2O. [Right] 0 isotope composition of N2O. Data from Dore et al. (1998) and B. Popp and J. Dore (unpublished). (B) N2O saturation state, expressed as a percentage of air saturation, for the upper portion of the water column at Station ALOHA during the period September 1992— September 1994. The vertical dashed line indicates equilibrium (100% saturation) with atmospheric N2O. With the exception of one measured value on cruise HOT-45, all determinations indicate significant N2O saturation relative to the atmosphere which implies both a local source and a net ocean-to-air gas flux.From Dore and Karl (1996a).

Sodamide is first prepared, and is transformed into sodium azide by warming at 300° C. in a stream of nitrous oxide gas. The sodium azide is dissolved in water, the solution is neutralised with very dilute nitric acid, and lead azide is precipitated by adding a solution of lead nitrate. The reactions which take place are represented by the following equations (1) Na+NH3 = NII.. Na+Il, -... 

In solution, a dissolved trace gas in equilibrium with the atmosphere would have the same partial pressure as the gas in the air. Its absolute concentration in terms of molecules or mass per unit volume of water depends on its solubility. Gas solubility varies over many orders of magnitude depending on the affinity of water for the gas molecules and the volatility of the gas. Gases range widely in their solubility in sea water, from the permanent gases like nitrogen (N2), oxygen (O2), nitrous oxide (N2O) and methane (CH4) that have a low solubility in sea... 

An exception is the case that a critical reaction step takes place in the gas phase only. An interesting example is the nitric acid process, where evolved nitrous oxide is oxidized to nitrogen dioxide in the gas phase. The dioxide (or its dimer) dissolves again and reacts with water. In this process both the gas volume and the gas/liquid interfacial area determine the overall reaction rate. Of course, gas/liquid mass transfer has then to be taken into account (section 4.6). 

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