Niobium joining

Cathodic protection applications in fresh water include use of ferrite-coated niobium , and the more usual platinum-coated niobium . Platinised niobium anodes have been used in seawater, underground and in deep wells " and niobium connectors have been used for joining current leads Excellent service has been reported in open-seawater, where anodic potentials of up to 120V are not deleterious, but crevice corrosion can occur at 20 to 40V due to local surface damage, impurities such as copper and iron, and under deposits or in mud ... 

The most recently developed anode for the cathodic protection of steel in concrete is mixed metal oxide coated titanium mesh The anode mesh is made from commercially pure titanium sheet approximately 0-5-2mm thick depending upon the manufacturer, expanded to provide a diamond shaped mesh in the range of 35 x 75 to 100 x 200 mm. The mesh size selected is dictated by the required cathode current density and the mesh manufacturer. The anode mesh is supplied in strips which may be joined on site using spot welded connections to a titanium strip or niobium crimps, whilst electrical connections to the d.c. power source are made at selected locations in a suitably encapsulated or crimped connection. The mesh is then fitted to the concrete using non-metallic fixings. 

Use Brazes to join molybdenum, tungsten, tantalum, and niobium parts, especially electronic components, corrosion and abrasion-resistant parts, cutting tools, refractory cermets. 

Channel tubes (88 mm o.d. and 4 mm thick) are of welded design and contain fuel assemblies which are cooled by boiling light water. The upper and lower parts of the channel are made of stainless steel and the central part, located in the active zone, is made from a zirconium/2% niobium alloy. The central part is joined to the upper and lower parts by vacuum diffusion-welded stainless steel/zirconium transition joints. The channel tube is attached to the upper duct by a welded joint, and to the lower one by a compensator unit, which is necessary to compensate for the difference in thermal expansion of the channels and ducts without destroying the leak-tightness of the reactor cavity. This type of joint makes it possible to replace a channel during reactor shutdown. 

FIG. 6—Weld decay and methods for its prevention. The four different panels were joined by weiding and then exposed to a hot soiution of nitric-hydrofiuoric acids. The weid decay, such as shown in Type 304 steel, is prevented by reduction of the carbon content (Type 304L) or stabilization of carbon with titanium (Type 321) or niobium (Type 347). 

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