Niobium isotope

Unstable niobium isotopes that are produced in nuclear reactors or similar fission reactions have typical radiation hazards (see Radioisotopes). The metastable Nb, = 14 yr, decays by 0.03 MeV gamma emission to stable Nb Nb, = 35 d, a fission product of decays to stable Mo by... 

Unstable niobium isotopes that are produced in nuclear reactors or similar fission reactions have typical radiation hazards. See also Radioactivity. 

Eighteen isotopes of niobium are known. The metal can be isolated from tantalum, and prepared in several ways. 

Separation of tantalum from niobium requires several complicated steps. Several methods are used to commercially produce the element, including electrolysis of molten potassium fluorotantalate, reduction of potassium fluorotantalate with sodium, or reacting tantalum carbide with tantalum oxide. Twenty five isotopes of tantalum are known to exist. Natural tantalum contains two isotopes. 

Tin hold the record with 10 stable isotopes. There are 19 so-called "pure elements" of which there is only one isotope. These anisotopic elements are beryllium, fluorine, sodium, aluminum, phosphorus, scandium, manganese, cobalt, arsenic, yttrium, niobium, rhodium, iodine, cesium, praseodymium, terbium, holmium, thulium, gold, and bismuth. 

Chromium iron manganese brown spinel, formula and DCMA number, 7 348t Chromium iron nickel black spinel, formula and DCMA number, 7 348t Chromium isotopes, 6 476 Chromium magnesium oxide, 5 583 Chromium manganese zinc brown spinel, formula and DCMA number, 7 348t Chromium-nickel alloys, 77 100-101 Chromium-nickel-iron alloys, 17 102-103 Chromium-nickel stainless steels, 15 563 Chromium niobium titanium buff rutile, formula and DCMA number, 7 347t Chromium(III) nitrate, 6 533 Chromium nitride, 4 668... 

Schonbachler M, Rehkamper M, Halliday AN, Lee D, Bourot-Denise M, Zanda B, Hattendorf B, Gunther D (2002) Niobium-zirconium chronometry and early solar system development. Science 295 1705-1708 Schonbachler M, Lee DC, Rehkamper M, Halliday A, Fehr AM, Hattendorf B, Gunther D (2003) Zirconium isotope evidence for incomplete admixing of r-process components in the solar nebula. Earth Planet Sci Lett accepted... 

ISOTOPES There are 49 isotopes of niobium, ranging from Nb-81 to Nb-113. All are radioactive and made artificially except nloblum-93, which Is stable and makes up all of the element s natural existence In the Earth s crust. 

The group IV B elements titanium, zirconium, and hafnium exhibit the normal isotope effect. Most of the data for the titanium-hydrogen system have been obtained at elevated temperatures. However, extrapolation of the available data (II, 13,31) to room temperature indicates a normal effect for hydrogen and deuterium. The group VB metals vanadium, niobium, and tantalum, on the other hand, exhibit inverse isotope effects indeed, these are the only pure metals that exhibit the inverse effect near room temperature. Extensive data have been reported for these systems. The P-C-T data obtained by Wiswall and Reilly (32) for vanadium hydrogen and deuterium clearly show a greater stability for... 

Nuclear reactions producing exotic nuclei at the limits of stability are usually very non-specific. For the fast and efficient removal of typically several tens of interfering elements with several hundreds of isotopes from the nuclides selected for study mainly mass separation [Han 79, Rav 79] and rapid chemical procedures [Her 82] are applied. The use of conventional mass separators is limited to elements for which suitable ion sources are available. There exists a number of elements, such as niobium, the noble metals etc., which create problems in mass separation due to restrictions in the diffusion-, evaporation- or ionization process. Such limitations do not exist for chemical methods. Although rapid off-line chemical methods are still valuable for some applications, continuously operated chemical procedures have been advanced recently since they deliver a steady source of activity needed for measurements with low counting efficiencies and for studies of rare decay modes. The present paper presents several examples for such techniques and reports briefly actual applications of these methods for the study of exotic nuclei. 

Chondritic relative abundances of strongly incompatible RLEs (lanthanum, niobium, tantalum, uranium, thorium) and their ratios to compatible RLEs in the Earth s mantle are more difficult to test. The smooth and complementary patterns of REEs in the continental crust and the residual depleted mantle are consistent with a bulk REE pattern that is flat, i.e., unfractionated when normalized to chondritic abundances. As mentioned earlier, the isotopic compositions of neodymium and hafnium are consistent with chondritic Sm/Nd and Lu/Hf ratios for bulk Earth. Most authors, however, assume that RLEs occur in chondritic relative abundances in the Earth s mantle. However, the uncertainties of RLE ratios in Cl-meteorites do exceed 10% in some cases (see Table 4) and the uncertainties of the corresponding ratios in the Earth are in same range (Jochum et ai, 1989 W eyer et ai, 2002). Minor differences (even in the percent range) in RLE ratios between the Earth and chondritic meteorites cannot be excluded, with the apparent exception of Sm/Nd and Lu/Hf ratios (Blicher-Toft and Albarede, 1997). 

The presence of uranium in a sample exposed to a flux of thermal neutrons can cause errors if the nuclide or nuclides determined are fission products or are isotopic with them. Hudgens and Dabagian (39) determined zirconium in zirconium-hafnium mixtures by separating the Nb , daughter of Zr formed by n,y reaction, after the addition of carrier. Contributions from fission product niobium (Nb ) can be allowed foi by irradiating a further sample, isolating fission product Ba ° and from the fission yield curve making allowance for radioactive niobium derived from any uranium impurity. 

Niobium-93 NMR data other than chemical shifts are even more scarce. The information on temperature gradients tg, coupling constants J and isotope effects A available to date is sununarized in Table 4. The temperature behaviour of Nb shielding and linewidth compares with that discussed for in Section 2.1.3. The trinuclear complex Cp3Nb3(CO)7 (20), with one of the... 

Only one namrally occurring isotope of niobium exists niobium-93. Isotopes are two or more forms of an element. Isotopes differ from each other according to their mass number. The number written to the right... 

Forty-four radioactive isotopes of niobium are known also. A radioactive isotope is one that breaks apart and gives off some form of radiation. Radioactive isotopes are produced when very small particles are fired at atoms. These particles stick in the atoms and make them radioactive. 

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