Nickel thermal decomposition

Miscellaneous. Electron beams can be used to decompose a gas such as silver chloride and simultaneously deposit silver metal. An older technique is the thermal decomposition of volatile and extremely toxic gases such as nickel carbonyl [13463-39-3] Ni(CO)4, to form dense deposits or dendritic coatings by modification of coating parameters. 

Easily decomposed, volatile metal carbonyls have been used in metal deposition reactions where heating forms the metal and carbon monoxide. Other products such as metal carbides and carbon may also form, depending on the conditions. The commercially important Mond process depends on the thermal decomposition of Ni(CO)4 to form high purity nickel. In a typical vapor deposition process, a purified inert carrier gas is passed over a metal carbonyl containing the metal to be deposited. The carbonyl is volatilized, with or without heat, and carried over a heated substrate. The carbonyl is decomposed and the metal deposited on the substrate. A number of papers have appeared concerning vapor deposition techniques and uses (170—179). 

Traditionally, pure CO is not used industrially water gas or producer gas are used instead. However, pure CO is made by thermal decomposition of nickel carbonyl ... 

Antimony-based passivation was introduced by Phillips Petroleum in 1976 to passivate nickel compounds in the FCC feed. Antimony is injected into the fresh feed, usually with the help of a carrier such as light cycle oil. If there are feed preheaters in the unit, antimony should be injected downstream of the preheater to avoid thermal decomposition of the antimony solution in the heater tubes. 

Dimethyl-I,l -biphenyl has been prepared by a wide variety of procedures, but few of these are of any practical synthetic utility Classical radical biarjl syntheses such as the Gomberg reaction or the thermal decomposition of diaroyl peroxides give complex mixtures of products m which 4,4 dimethyl-l.l -biphenyl is a minor constituent A radical process maj also be involved in the formation of 4,4 dimethyl-1, l -biphenyl (13%) by treatment of 4-bromotoluene with hydrazine hydrate 5 4,4 -Dimethyl-l,l -biphenyl has been obtained in moderate to good yield (68-89%) by treatment of either dichlorobis(4-methyl phenyl)tellurium or l,l -tellurobis(4-methylbenzene) with degassed Raney nickel in 2 methoxyethyl ether 6... 

Sintered Electrodes In these electrodes the active materials are present in pores of a sintered nickel support plate. This plate is manufactured by sintering of highly disperse nickel powder produced by thermal decomposition of nickel pentacarbonyl Ni(CO)5. The plates are filled by impregnating them in alternation with concentrated solutions of salts of the corresponding metals (Ni or Cd) and with an alkali solution serving to precipitate insoluble oxides or hydroxides. 

Garratt and Thompson [J. Chem. Soc., 1934, 524, 1817, 1822] have studied the photochemical and thermal decomposition of nickel tetra-carbonyl. Later work by Day, Pearson and Basolo [J. Am. Chem. Soc., 90 (6933), 1968] confirmed that the rate law postulated by Garratt and Thompson was obeyed for the homogeneous process. The mechanism postulated by both groups is ... 

The effect of metal oxides in sensitising the thermal decomposition and explosion of the salt is in the order manganese dioxide > copper oxide > nickel oxide. 

The thermal decomposition of nickel ammonium chloride powder, [Ni(NH3)4]Cl2 = [Ni(NH3)2]Cl2 + 2NH3... 

Fig. 6.1 (a) TEM image and (b) Raman spectrum of graphene prepared by the thermal decomposition of methane (70 seem), (c) FESEM image and (d) Raman spectrum of graphene obtained by benzene (argon passed through benzene with flow rate of 200 seem) at 1000 °C on a nickel sheet (from [8]). 

The magnetic susceptibility, measured with a vibrating sample magnetometer (Foner), calibrated with nickel (purity 99.99% — specific susceptibility at 293°K 55 cgs/g) at 293 0.2°K with a magnetic field of 17,700 G, is 101.39 0.20 10"6 cgs/g. This value may be compared with 101.65 0.20 10 6 cgs/g for manganese diphosphate prepared by thermal decomposition of the ammonium manganese phosphate. The value calculated from Reference 7 is 101.96 0.20 cgs/g. 

RNi Raney nickel DNi catalyst prepared by the thermal decomposition of nickel formate HNi powder prepared by the hydrogenolysis of nickel oxide. 

Monammino-nickel Chloride, [Ni(NH3)]Cl2, is also known, and is produced by the thermal decomposition of the hexammine. It is yellow in colour and decomposes completely at 378° C.4... 

Diammino-nickel Bromide, [Ni(NH3)2]Br2, is produced during the thermal decomposition of the hexammino-derivative. 

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