Nature gas steam reformation process

This paper analyzes the sources of hydrogen for ammonia production, presents the feed and fuel requirements of the natural gas steam reforming process, estimates the relative economics of alternate feedstocks and briefly discusses the outlook for the ammonia industry. 

Fig. 1.8 Two-steps RMM natural gas steam reforming process with electric power production and recycle layout [25, 29]...

Natural gas steam reforming process is an ideal candidate for hydrogen selective membrane integration tanks to its high reaction endothermicity and the fast kinetics leading to equilibrium condition inside traditional reactors. 

De Falco M, Basile A, Gallucci F (2010) Solar membrane natural gas steam reforming process evaluation of reactor performance. Asia Pacific J Chem Eng Memb React 5 179-190... 

The process assessed in this section, in order to illustrate to the readers an IMR modelling case study, is the natural gas steam reforming process, being the most applied process in producing hydrogen industrially. 

Mini Electricity Generation with SOFC. Development of 1 to 2 kW SOFC for application in distributed generation. The process for hydrogen production is natural gas steam reforming. 

By far the most widespread method of producing synthesis gas for methanol production today is via steam reforming of naphtha and lighter hydrocarbons. The process routes for both natural gas steam reforming and naphtha reforming are virtually identical, so we shall consider only natural gas reforming. Since the ICI LP methanol process was... 

Feedstock (process) Natural gas (steam reforming) Vacuum residue (partial oxidation) Coal (partial oxidation)... 

Natural Gas Steam Reforming Production - A two step process where in the first step natural gas is exposed to a high-temperature steam to produce hydrogen, carbon monoxide, and carbon dioxide. 

Pd-based membranes, mainly Pd-Ag (23%wt), have been extensively tested for natural gas steam reforming, which is the main process to produce large amount of hydrogen. Many experimental works are reported in the literature [7-11], attesting the good performance in terms of natural gas conversion at much lower operating temperature than traditional process (methane conversions up to 90-95% at 450-550 vs. 850-1000°C). 

As we said before, potential of membrane reactors is enormous, and in particular, they could play a key role with endothermic reactions because the higher reactant conversion at lower temperature allows less energetic and more efficient processes to be developed. As an example, natural gas steam-reforming is a rather expensive process, energy and capital expensive due to the endothermicity of the reaction. 

Hydrocarbon steam reforming catalysts are classified into natural gas steam reforming catalysts and light-oil steam reforming catalysts according to the feedstock, and primary- and secondary- steam reforming catalysts according to the processes. 

Multitubular natural gas steam reformer with furnace. From Froment [1974], after High Performance Process Furnaces, M. W. Kellogg Co. 

The conversion of natural gas to methanol via syngas is a widely used industrial process. A typical conventional process includes desulfurization of natural gas, steam reforming, methanol synthesis and purification by distillation. Steam reforming of natural is an endothermic reaction and operates at high temperatures (reformed gas effluent at about 800880°C). Methanol synthesis from syn is an exothermic reaction and operates at 200300°C. Heat integration and recovery is an important feature of the process. The trend in methanol production has been toward larger capacity and improved energy efficiency. 

Steam Reforming Processes. In the steam reforming process, light hydrocarbon feedstocks (qv), such as natural gas, Hquefied petroleum gas, and naphtha, or in some cases heavier distillate oils are purified of sulfur compounds (see Sulfurremoval and recovery). These then react with steam in the presence of a nickel-containing catalyst to produce a mixture of hydrogen, methane, and carbon oxides. Essentially total decomposition of compounds containing more than one carbon atom per molecule is obtained (see Ammonia Hydrogen Petroleum). 

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