N-Isopropyl

Carbazole, 2-hydroxy-reactions with citral, 4, 235 Carbazole, 2-hydroxy-9-methyl-synthesis, 4, 294 Carbazole, N-hydroxymethyl-as metabolite of carbazole, 1, 230 Carbazole, N-isopropyl-PE spectroscopy, 4, 190 Carbazole, A7-methyl- N NMR, 4, 175 X-ray spectroscopy, 4, 163 Carbazole, 1-nitro-synthesis, 4, 282 Carbazole, tetrahydro-dehydrogenation, 4, 282, 312 synthesis, 4, 107, 337, 353 Carbazole, 1,2,3,4-tetrahydro-reduction, 4, 255, 256 synthesis, 4, 312, 325, 352 Carbazole, 1,2,3,4-tetrahydro-1 -oxo-synthesis, 4, 337 Carbazole, 9-trifluoroacetyl-synthesis, 4, 218 Carbazole, vinyl-polymers, 1, 275, 301 Carbazole, 9-vinyl-copolymer... 

It is not known whether the amine assists the elimination of the nitrogen, but that the iminium salt retains its stereochemistry has been demonstrated (709). When a mixture of 68 and 69of 1 5 ratio is treated with diazomethane, the ratio of 70 71 obtained in 75% yield and determined spectroscopically was still 1 5. The traw-N-isopropyl-N-methylisobutylidinium perchlorate (69) was prepared by alkylation of an aldimine salt with diazomethanc and... 

FIGURE 4.13 Effect of the allosteric modulator 5-(N-ethyl-N-isopropyl)-amyloride (EPA) on the kinetics dissociation of [3H] yohimbine from c/j-adrenoceptors, (a) Receptor occupancy of [3H] yohimbine with time in the absence (filled circles) and presence (open circles) of EPA 0.03 mM, 0.1 mM (filled triangles), 0.3 mM (open squares), 1 mM (filled squares), and 3 mM (open triangles), (b) Regression of observed rate constant for offset of concentration of [3H] yohimbine in the presence of various concentrations of EPA on concentrations of EPA (abscissae in mM on a logarithmic scale). Data redrawn from [13]. 

Eine Losung von 0,378 g (2 mMol) N-Isopropyl-phthalimid und 0,312 g (8 mMol) Natriumboranat in 50 ml Isopropanol und 10 m/ Wasser wird 18 Stdn. bei 25°geriihrt. Man versetzt mit 2 ml 6 n Salzsaurc, dampft ein, ver-diinnt mit Wasser und extrahiert mit Diathylathcr. Die Ather-Schicht wird mit verd. Ammoniak und Wasser ge-waschen, getrocknet und eingeengt, Mankristallisiert den Riickstand aus Dichlormcthan/Petrolather Ausbeute 0,3 g (78% d. Th.) F 111-113°. 

Aceton-oxim + Propansaure — N-Propyl-N-isopropyl-hydroxylamin 68°/0 d. Th. 

N,N -Dimethyl-N-phenyI- 136 N,N -Dipropyl-N-butyI- 136 N,N -Dipropyl-N-phenyl- 136 N-Isopropyl-N -cyclohexyl- 135... 

N-Diphenylmethylen- 374 N-Diphenylmethylen-O-aminocarbonyl- 612 N-[l,3-Diphenyl-propyl-(2) - 374 N-[l,3-Diphenyl-propyliden-(2)]- 374, 377, 380 N-(4-Halogen-phenyI)- 683 N-Heptyl- 375 N-Heptyl-N-acetyl- 376 N-Heptyliden- 375 N-Hcptyliden-O-acetyl- 376 0-(2-Hydroxy-athyl)-N-athoxycarbonyl- 133 N-(4-Hydroxy-phenyl)- 683 0-(2-Hydroxy-l-phenyl-athyI)-N-athoxycarbonyI-aus 0-(ci-AthoxycarbonyI-benzyl)-N-athoxycar-bonyl-hydroxylamin und Lithiumalanat 133 N-Isopropyl- 682 N-Isopropylidcn- 613 N-Methyl- 133, 682 O-Methyl-N-bcnzyliden- 377 O-Methyl-N-benzyliden- 375 0-Methyl-N-(4-chlor-benzyl)- 375 0-Methyl-N-(4-chlor-benzyliden)- 375 N-Methy -N,0-diacetyI- 682 N-(4-Methyl-phenyl)- 683 0-McthyI-N-( 1 -phenyl-athyliden)- 375 N-(4-Methylthio-phenyl)- 684 N-(4-Nitro-benzyl)- 374 N-[4-Nitro-benzyliden - 374, 377 N-(2-Nitro-phenyl)- 562 N-(4-Nitro-phenyl)- 682 N-Nitroso-N-cyclohexyl- 697 N-Octyl- 374 N-Octyl-(2)-N-acetyl- 376 N-Octyliden- 374 N-0ctyliden-(2)-0-acctyl- 376 N-(Pentafluor-phenyl)-0,N-diacetyl- 697 N-Phenyl- 474, 481, 682, 783 N-Phenylacetyl-O-benzoyl- 265 N-(l-Phenyl-athyl)- 374 N-(l-Phenyl-athyl)-N-acetyl- 376 N-(l-Phenyl-athyliden)-374, 613 N-( l-Phenyl-athyliden)-0-acetyl- 376 N-[ 1 -Phenyl-buten-( 1 )-yl-(3)-iden]- 582 N-f4-Phenyl-butyl-(2)-iden]- 581 N-Phcnyl-N,0-diacetyl- 682 N-(4-Phenylthio-phenyl)- 684 N-Propyl-N-cyclohexyl- 376 N-Propyl-N-isopropyl- 376 O-Sulfonyl- 481 N-(4-Sulfonyl-phenyI)- 683 N-(2-Vinyl-phenyl)- 698... 

Uenoyama, S and Hoffman AS. Synthesis and characterization of acrylamide-N-isopropyl acrylamide copolymer grafts on silicone rubber substrates. Radiat. Phys. Chem., 1988, 32, 605-608. 

Ivan et al. [95] reported that 3,5-di-tert-butyM-hydroxybenzylcyanoacetate is a nonstaining antiozonant that affords similar protection to NR and to cw-polyisoprene compounds such as N-isopropyl-N -phenyl-para-phenylenediamine does (see Figure 15.12). This product lasts longer than conventional nonstaining antiozonants, like the styrenated phenols. 

Using potassium bis(trimethylsilyl)amide as a solid base, N -isopropyl-l,l-dimethyl-N,N -bis(trimethylsilyl)silanediimine and 2,4-diisopropyl-1,1,3,3-tetramethylcyclodisilazane were formed, accompanied by hexa-methyldisilazane. 

Antiozonant additives are employed with unsaturated rubbers such as natural rubber, nitrile rubber, styrene-butadiene rubber, etc., to minimise the atmospheric ozone degradation reaction. Common antiozonant types include the parapheny-lene diamines such as N-(l,3-dimethylbutyl)-AT-phenyl-p-phenylene diamine (6PPD) and N-isopropyl-N7 phenyl-p-phenylene diamine (IPPD). Both these antioxidants can be identified and quantified using GC- or LC-based techniques. 

It was found that in spite of the large excess of modifying amine (N-isopropyl-, -diethyl, -dipropyl, -diisopropyl, -n-hexyl, -cyclohexyl, -n-octyl), the extent of substitution did not exceed 5-10 molar %. For the case of the N-isopropyl derivative, i.e. [poly(AAm-co-NiPAAm)], the authors connected such results with the temperature-induced conformational transformation of partially hydrophobized copolymer acquiring the contracted conformation, "... which made it difficult for N-isopropylamine to react further with the amide groups [22], Unfortunately, no data on the solution behaviour of these interesting copolymers have been reported to date, although there is a high probability that they would demonstrate certain properties of the protein-like macromolecules. At least, in favour of similar supposition is supported by the results of our studies [23] of somewhat different PAAm partially hydrophobized derivative, whose preparation method is depicted in Scheme 3. 

Polydiallyldimethylammonium Chloride-co-N-Isopropyl Acrylamide 1.0-5.0 Synthesized by R. Pelton, McMaster Univ. 

Polydiallydimethylammonium Chloride-co-N-Isopropyl Acrylamide Medium Permanent Medium Flexible Cyclic Side Chain Weak... 

N-(2- [Ethoxy(methyl)phosphoryl]sulfanyl ethyl)-N-(isopropyl)propan-... 

N-(2- [Ethoxy(methyl)phosphoryl]sulfanyl ethyl)-IV-isopropyl-N-methylpropan-2-aminium Iodide N-(2- [Ethoxy(methyl)phosphoryl]sulfanyl ethyl)-IV-isopropylpropan-2-aminium Chloride N-(2-Chloroethyl)dimethylamine N-(2-Chloroethyl)-N,N-dimethylamine N-(2-Hydroxyethyl)diethylamine N-(4-Oxy-3-methoxybenzyl)-8-methyl-6-nonenamide N-(Diethylamino)ethanol N-(Isopropyl)-2-propamine... 

N,N-Diethyl-2- [methyl(cyclohexyloxy)phosphoryl]sulfanyl -N-methylethanaminium Iodide N,N-Diethyl-2-aminoethanol N,N-Diethyl-2-hydroxyethylamine N,N-Diethylethanolamine N,N-Diethyl-N-(/3-hydroxyethyl)amine N,N-Diisopropyl-(jS)-aminoethanol N,N-Diisopropyl-2-aminoethanol /V,/V-I)i isopropylamine N,N-Diisopropylaminoethanol /V,/V,-l)iisopropylcarbodiimide N,N-Diisopropylethanolamine N,N-Dimethyl-2-chloroethylamine N/N -DimethyM -bipyridinium /V,/V,-I)imethylhydrazine N,N-Dimethyl-N-(2-chloroethyl)amine /V,/Vd)irnethyl-/i-chloroethylamine /V,/V,-Methanetetrayl Biscyclohexanamine /V./V -Thiod i-2,1 -ethanediyl Bis(N-isopropyl)-2-propanamine N,a-Dimethylphenethylam ine... 

This is a general method for making N-alkylallenimines, and the following ones have been made in this way N-methyl-,6 N-propyl-,6 N-isopropyl-,4 N-butyl-,4 N-hexyl-,e and N-(3,5,5-tri-methylhexyl)-.4 N-Z-Butylallenimine6 and l-(l-allenimino)-2-hydroxy-3-butene 7 have also been prepared by this method, but with sodium amide/2-bromoallylamine mole ratios of 1.75 and 2.1, respectively. This method has been used for the preparation of pure N-alkylpropargylamines from 2-chloroallylaminesA7 The optimum sodium amide/2-chloroallylamine ratio for the preparation of N-alkylpropargylamines is 2.1. 

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