Must browning, mechanism

Fig. 4.1 Mechanism of formation of oxidized polymers responsible for must browning...

Must browning depends of course on the flavonoid concentration and consequently on mechanical treatments of that favor grape stalk maceration. These operations are also involved in the solubilization of the tyrosinase bound to the chloroplast membranes. 

The moisture content of peat or brown coal that is briquetted for fuel must be reduced to about 15% for satisfactory briquetting. Mechanical or natural means are used because of the cost of thermal drying. Moisture is sometimes desirable. About 8% is necessary for prevention of combustible loss from a chain-grate stoker. 

An example of a practical dielec trofilter which uses both of the features described, namely, sharp electrodes and dielectric field-warping filler materials, is that described in Fig. 22-34 [H. I. Hall and R. F. Brown, Lubric. Eng., 22, 488 (1966)]) It is intended for use with hydrauhc fluids, fuel oils, lubricating oils, transformer oils, lubricants, and various refineiy streams. Performance data are cited in Fig. 22-35. It must be remarked that in the opinion of Hall and Brown the action of the dielec trofilter was electrostatic and due to free charge on the particles dispersed in the hquids. It is the present authors opinion, however, that both elec trophoresis and dielectrophoresis are operative here but that the dominant mechanism is that of DEP, in wdiich neutral particles are polarized and attracted to the regions of highest field intensity. 

Figure 10-153C. Shell-side film coefficient, h , for longitudinal fins, flow turbulent. See Figure 10-153A and mechanical data from Table 10-42 for applicable details. The value of h must be corrected using Figure 10-154 and data of Table 10-42. (Used by permission Brown Fintube Co., A Koch Engineering Company, Houston, Texas.)...

In order to provide heat when it is required to maintain or increase body temperature, a mechanism must exist for the regulation of the activity of this uncoupling protein. The mechanism has been established by following the principles described in Chapter 3. The properties of the uncoupling protein are studied using mitochondria isolated from brown adipose tissue in vitro (as described in Appendix 9.9). 

Of a special astronomical interest is the absorption due to pairs of H2 molecules which is an important opacity source in the atmospheres of various types of cool stars, such as late stars, low-mass stars, brown dwarfs, certain white dwarfs, population III stars, etc., and in the atmospheres of the outer planets. In short absorption of infrared or visible radiation by molecular complexes is important in dense, essentially neutral atmospheres composed of non-polar gases such as hydrogen. For a treatment of such atmospheres, the absorption of pairs like H-He, H2-He, H2-H2, etc., must be known. Furthermore, it has been pointed out that for technical applications, for example in gas-core nuclear rockets, a knowledge of induced spectra is required for estimates of heat transfer [307, 308]. The transport properties of gases at high temperatures depend on collisional induction. Collision-induced absorption may be an important loss mechanism in gas lasers. Non-linear interactions of a supermolecular nature become important at high laser powers, especially at high gas densities. 

A maltol-ammonia browning reaction produced thirteen pyrazines, two pyrroles, two oxazoles, and one pyridine (12). The major products of this system were 2-ethyl-3-hydroxy-6-methylpyridine and 2-ethyl-3,6-dimethylpyrazine. It is difficult to construct possible formation mechanisms for these compounds from maltol and ammonia. All the carbon atoms must come from maltol. It is possible, then, that maltol degrades into smaller carbon units and that these fragments recombine to form larger carbon units, producing these compounds. Recently, the formation of thiophenones and thiophenes from the reaction of 2,5-dimethyl-4-hydroxy-3(2H)-furanone and cysteine or cystine was reported (13. 14). All these reaction mixtures were reported to possess a cooked meat-like flavor. 

Although the Berthelot benzene synthesis must obviously be a multi-step process, its detailed mechanism surprisingly remains unknown to the present day. Being interested in the actual ring-producing step (see below), several years ago we postulated [4] that the overall process might be initiated by the isomerization of 1 to vinylidene carbene (3), a reaction that has been studied in detail by Brown and co-workers (Scheme 2) [5] ... 

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