Morphology globular

The method is then applied to the study of global and local structure of polyelectrolyte chains, as well as the distribution of counterions and condensation. We also explain the morphologies (globular, rod, toroid, etc.) of polyelectrolyte complexes as a consequence of the chain stiffness itself. 

The morphology of globular type is the most favourable when superplastic deformation is to occur in AI78wt%Zn alloy. This type of structure is formed by decomposition of the a solid solution a -> a + P However, plates usually dominate in the structure of this alloy. To obtain the non-plate or globular type, a special heat treatment is neccesary i.e. the optimal cooling rate as well as the temperature and time of ageing. 

The most metal-deficient stars comprise field stars in the solar neighbourhood (where in some cases distances and luminosities can be found from parallaxes) and stars in globular clusters where the morphology of the HR diagram can be studied (Fig. 4.8). Such stars are of particular interest because their content of heavy elements (synthesized in still earlier generations of stars) is so low that they can... 

In the case of human amylin and Afi our understanding of the diversity in amyloid fibril architecture is the result of a recursive process, since the early morphological observations were followed by assessment of the assembly pathway which in turn yielded a better understanding of fibril polymorphism. However, this structural knowledge is secondary compared to the discovery of small oligomers, globular oligomers, and early protofibrils that appear to be extremely cytotoxic (Hartley etal., 1999 Lambert et al, 1998 Walsh et al, 1999). 

The peptide chain in globular proteins is folded into fairly compact conformations. Water-soluble enzymes are typical globular proteins which have most of the hydrophobic amino acid residues located in the interior and the hydrophilic residues located mainly at the surface in contact with solvent water. The average radii are 20-40 A (Boyer, 1970). It is clear that there are common morphological features between surfactant micelles and enzyme molecules. This fact has prompted many chemists to use micelles as enzyme models. However, it must be emphasized that micelles exist in dynamic equilibria with monomeric surfactant and their hydrophobic core is quite fluid, whereas enzyme molecules have precisely fixed three-dimensional structures. 

The crystalline structure of the metal is also affected by the metal-support interaction. Metal particles supported on CNFs have a highly crystalline structure due to strong metal-support interaction [155], whereas Pt particles supported on Vulcan and OMCs have a more dense globular morphology due to weak metal-support... 

Zig-zag fiber morphology persists at later stages of digestion and is attributed to retention of the globular domain of LH in fiber The three-dimensional organization of nucleosomes in extended (low ionic strength) chromatin fibers requires the globular domain of LHs and either the tails of LH or the N-terminal tails of H3... 

The inter-relationship between colloid and polymer chemistries is completed by colloidal polymer particles. The formation of 50-nm-diameter, 100- to 200-nm-long polyaniline fibrils in a poly(acrylic acid)-template-guided polymerization, similar in many ways to those produced from polymerized SUVs (see above), provides a recent example of polymer colloids [449], The use of poly(styenesulfonic acid) as a template yielded globular polyaniline particles which were found to be quite different morphologically from those observed in the regular chemical synthesis of polyaniline [449]. 

Supramolecular 10-105 nm Packing defects, nodular/globular morphology, multiphase structure Materials science Microscopies, scattering methods, thermal analysis... 

Inhomogeneous open networks characterized by spatial fluctuations of the crosslink density (nodular/globular morphologies, microgels, see Chapter 7). 

Owing to their size and the feasibility of controlling the dendrimer structure and globular morphology via their synthesis, dendrimers with chiral branching scaffold are of interest as potential protein mimics. In addition, the introduction of chiral branching units or spacers into the molecular scaffold should lead to the development of non-symmetrical macromolecular conformations and provide chiral cavities for asymmetrical catalysis or chiral recognition processes. 

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