Mill behavior

Figure 5. Mill behavior of Ti-BR. Mooney viscosity (ML 1 + 4/100°C), 47 compound, 50 parts carbon black N 330/5 parts oil.

The particle size distribution resulting from a milling operation is primarily determined by both the method of particle size reduction as well as the mechanical properties of the material such as fracture toughness, elastic modulus, and hardness. Thus, two extrudate samples with different mechanical properties milled under the same conditions will yield different particle size distributions. Beyond the intrinsic properties of the system, the mechanical behavior of extruded material is also affected by features of the bulk extrudate itself such as air bubbles, particle inclusions, or other defects that can increase the apparent brittleness of the material. Foamed extrudate, for example, could have different milling behavior as compared to a nonfoamed extmdate of the same composition. 

Flowahility, hulk density, roughness, amorphous content, milling behavior... 

Extraction of hemiceUulose is a complex process that alters or degrades hemiceUulose in some manner (11,138). Alkaline reagents that break hydrogen bonds are the most effective solvents but they de-estetify and initiate -elimination reactions. Polar solvents such as DMSO and dimethylformamide are more specific and are used to extract partiaUy acetylated polymers from milled wood or holoceUulose (11,139). Solvent mixtures of increasing solvent power are employed in a sequential manner (138) and advantage is taken of the different behavior of various alkaUes and alkaline complexes under different experimental conditions of extraction, concentration, and temperature (4,140). Some sequences for these elaborate extraction schemes have been summarized (138,139) and an experimenter should optimize them for the material involved and the desired end product (102). 

The second process to finish phthalocyanine, which is more important for P-copper phthalocyanine, involves grinding the dry or aqueous form in a ball mill or a kneader (64). Agents such as sodium chloride, which have to be removed by boiling with water after the grinding, are used. Solvents like aromatic hydrocarbons, xylene, nitrobenzene or chlorobenzene, alcohols, ketones, or esters can be used (1). In the absence of a solvent, the cmde P-phthalocyanine is converted to the a-form (57,65) and has to be treated with a solvent to regain the P-modification. The aggregate stmcture also has an impact on the dispersion behavior of a- and P-copper phthalocyanine pigments (66). 

Acid milling dyes are intermediate in behavior being appHed with acetic or formic acid in the presence of sodium sulfate. 

The energy laws of Bond, Kick, and Rittinger relate to grinding from some average feed size to some product size but do not take into account the behavior of different sizes of particles in the mill. Computer simulation, based on population-balance models [Bass, Z. Angew. Math. Phys., 5(4), 283 (1954)], traces the breakage of each size of particle as a function of grinding time. Furthermore, the simu-... 

Rajamani and Herbst (loc. cit.) compared control of an experimental pilot-mill circuit using feedback and optimal control. Feedback control resulted in oscillatory behavior. Optimal control settled rapidly to the final value, although there was more noise in the results. A more complete model should give even better results. 

Simpson (1988) reviewed studies which considered individual differences in risk perception and the effects of these differences on behavior. A study by Verhaegen et al. (1985) looked at three groups of workers in wire mills. The first group comprised those who had been directly involved in events which led to the accident (the "active" group). The second group ("passive") were those who had only been involved indirectly ("innocent bystanders") and the third group were a control group who had not been involved in accidents at all. 

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