Methyl 2-methylpropenoic acid

Synonyms Methacrylic acid, methyl ester methyl 2-methylpropenoic acid methyl a-methyl acrylate methyl methylacrylate 2-(methyoxycarbonyl)-1 -propene... [Pg.488]

Methylpropenoic acid, see Methacrylic acid, 1525 f Methyl propionate, 1615... [Pg.2113]

Its IUPAC name is 2-methylpropenoic acid and it is well known from its reaction with methyl alcohol to produce the ester, methyl methacrylate. [Pg.131]

Very few reports have been concerned with phosphorus chlorides of the types (RO)2PCl or ROPCI2. For the former (R = Et), the product from propenoic acid consists of the linear ester 465 (R = OR, R = Et R = R" = although readily transformed, when heated comparatively gently, into the corresponding 2-ethoxy-2-oxo-l,2-oxaphospholan-5-one (466), and that from 2-methylpropenoic acid consisted of the corresponding 4-methyl derivative 466 (R" = However, a detailed study of the reaction between (EtO)2PCl... [Pg.236]

Synonyms Acrylic acid, 2-methyl- MAA 2-Melhylacrylic acid a-Methylacrylic acid a-Methylacrylic acid (monomer) 2-Melhylene propionic acid 2-Methylpropenoic acid 2-Methyl-2-propenoic acid 2-Propenoic acid, 2-methyl- Propionic acid, 2-melhylene-... [Pg.1188]

Methyl propenoate Methyl 2-propenoate. See Methyl acrylate 2-Methylpropenoic acid 2-Methyl-2-propenoic acid. See Methacrylic acid 2-Methyl-2-propenoic acid anhydride. See Methacrylic anhydride 2-Methyl-2-propenoic acid, ethyl ester. See Ethyl methacrylate 2-Methyl-2-propenoic acid, 2-ethylhexyl ester. See2-Ethylhexyl methacrylate... [Pg.1205]

Methylpropenoic acid 2-Methyl-2-propenoic acid. See Methacrylic acid 2-Methyl-2-propenoic acid anhydride. See Methacrylic anhydride... [Pg.2680]

C5H802 80-62-6 2-Methylpropenoic acid methyl ester see Methyl 2-methylpropenoate... [Pg.56]

Methylphenol) see p-Cresol (2-Methyl-1-phenylpropane) see Isobutylbenzene (2-Methylpropane) see Isobutane (Methylpropenoate) see Methyl acrylate (2-Methylpropenoic acid) see Methacrylic acid (2-Methylpropylamine) see Isobutylamine (Methyl propyl ketone) see 2-Pentanone (2-Methylpyridine) see a-Picoline (3-Methylpyridine) see p-Picoline A-Methyl-2-pyrrolidone (NMP)... [Pg.85]

Addition of optically active 1-phenylethylhydroxylamines to a,/ -unsaturated esters proceeds in good yield but with modest diastereoselectivity for the isolated substituted /J-amino acid esters12. Thus, reaction of (S)-l-phenylethylhydroxylamine with methyl 2-methylpropenoate in diethyl ether affords the corresponding conjugate-adduct in 86% yield12. This is subsequent-... [Pg.1097]

In the search of new non-peptide glycoprotein GPIIb/GPIIIa antagonists, heterocyclic scaffolds such as oxazolepiperidine have been explored. Such framework has both acidic and basic functionalities, which may confer the pharmacological properties to the desired molecule. The Heck reaction of bromooxazolopyridines 104 with methyl acrylate in the presence of palladium acetate afforded methylpropenoate-oxazolopyridines 105 in 70 and 88% yields, respectively [60]. [Pg.400]

METHYL-2-METHYLPROPENOATE (80-62-6) Forms heat-sensitive explosive mixture with air (flash point 50°F/10°C). Unless inhibited, forms unstable peroxides. Violent reaction with strong oxidizers, benzoyl peroxide, or other polymerization initiators. Elevated temperatures, light, contamination can cause spontaneous, explosive polymerization. Incompatible with caustics, nitrates, strong acids, aliphatic amines, alkanolamines, peroxides. Flow or agitation of substance may generate electrostatic charges due to low conductivity. The uninhibited monomer vapor may block vents and confined spaces by forming a solid polymer material. [Pg.791]

Ageflex FM-10 CCRIS 4660 EINECS 249-978-2 HSDB 5065 Isodecyl 2-methyl-2-propenoate Isodecyl 2-methylpropenoate Isodecyl methacrylate Methacryllc acid, Isodecyl ester 2-Methyl-2-propenolc acid, l ecyl ester 2-Propenolc acid, 2-methyl-, Isodecyl ester. Pressure-sensitive adhesives, coatings for leather, textiles, paper, nonwovens, polymer modifier/stabilizer, viscosity index Improver, dispersion for plastic and rubber, floor waxes, potting compounds, sealants, adhesives. Liquid d 8 = 0.878 bp - 126° flash pt. 121 ° insoluble in H2O, soluble in organic solvents LDso (rat ip) = 2467 mg/kg. Rohm Haas Co. [Pg.346]

Synonyms methacrylic acid methyl ester methyl-2-methyl-2-propenoate MME MMA 2-methylacrylic acid methyl ester methyl niethylacrylate methyl ot-methylacrylate Diakon methyl-2-methylpropenoate... [Pg.1225]

Poly(methacrylates) are polymers of the esters of methacrylic acids. The most commonly used among them is poly(methyl methacrylate) (PMMA). Poly(methyl methacrylate) or poly(methyl 2-methylpropenoate) is the polymer of methyl methacrylate, with chemical formula It is a clear, colorless polymer available on the market... [Pg.390]

Global danand of acetic acid exceeds 6.5 milUon tons (6.5 X lO kg) annually. It is used to manufacture monomers for polymerization, such as methyl 2-methylpropenoate (methyl... [Pg.844]

Maleic acid reacts with itself very slowly, and its homopolymer is difficult to form. Styrene readily reacts to form a homopolymer. However, a styrene group at the end of a growing polymer chain reacts faster with maleic anhydride than with itself. After the addition of styrene to maleic anhydride, a radical is produced that does not react with maleic anhydride. As a result, the next alkene that is added is styrene. Monomers that provide perfect alternating copolymers are highly desirable because the product can be reproduced. The amount of alternation compared to random sequencing in copolymers depends on two selectivity ratios. Consider the copolymerization of styrene and methyl-2-methylpropenoate. [Pg.1002]

Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...