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Methane, preparation

Substituted thioureas have been extensively studied over the decades. Reaction of CoX2 (X = C1, Br) with substituted phenylthioureas yield a range of complexes involving halide and thiourea as ligands, characterized by spectroscopy and thermogravimetric analysis.503 Both [Co(Rtu)4(OH2)2]2+ (Rtu = thiourea, phenylthiourea, allylthiourea) and [Co(Rtu)2(OH2)4]2+ (Rtu = diphenylthiourea) have been prepared and characterized as low-spin octahedral species.504 The octahedral bis(phenylthiourea)bis(dithiolate)cobalt(II) complex, one of a number of complexes of phenylthiourea, chlorophenylthiourea and bis(diphenylphospinothioyl)methane prepared and characterized,505 proved the most biologically active of those tested. [Pg.53]

Leanza, R Rossetti, 1 Fabbrini, L Oliva, C Fomi, L. Perovskite catalysts for the catalytic flameless combustion of methane Preparation by flame-hydrolysis and charaeterisation by TPD-TPR-MS and EPR. Appl. Catal, B Environmental, 2000, Volume 28, Issue 1, 55-64. [Pg.71]

Applied to the synthesis of hydrocarbons the following results have been obtained by this new method. 9 10-Diphenyl-9 10-dihydroanthracene is formed by the condensation of benzene and chloroform, whilst in the ordinary Friedel-Crafts reaction (A., 194, 254 227, 107) triphenyl-methane (Preparation 6) is the main product, traces of chlorarylmethanes and tetraphenylethane (B., 26, 1952) being also formed. The same compound is also obtained from benzal chloride and benzene. Carbon tetrachloride and benzene give 9 9 10 10-tetraphenyl-9 10-dihydroanthracene as do also phenylchloroform and benzene. In the older reaction triphenylchloromethane (p. 432) is the chief product. [Pg.60]

If liquid air is available, the hydrogen in the methane prepared above is best removed by fractional distillation. The following is an outline of the method (see Fig. 52) —... [Pg.182]

The failure of cuscohygrine to condense with benzaldehyde, ethyl oxalate and amyl nitrite is hard to accommodate on formula X. Because of the formation of two isomeric hydrazones, and on the erroneous assumptions that base A was di-(a-iV -methylpyrrolidyl)-methane and that methylene di-isonitramine came from a methyl ketone group, Hess and Fink (22) altered Liebermann s formula X so as to represent cuscohygrine as an unsymmetrical di-(JV-methylpyrrolidyl)-propan-2-one (XIII). It has since been found, however, that base A is not identical with di-(a-IV-methyI-pyrrolidyl)-methane prepared by the action of phosgene on pyrrylmagne-sium bromide followed by reduction and methylation (25). Moreover,... [Pg.97]

The methane prepared in this way is contaminated with small quantities of other substances, which are formed as the result of the action of heat on sodium acetate alone. When a very pure sample of the hydrocarbon is desired, it is prepared by treating an alcoholic solution of methyl iodide, CH3I, with a zinc-copper couple. In order to make clear this statement and others which are made later, the following facts are given at this point. [Pg.26]

J. Veil,M. Pudor,D. Elcock,R. Redweik- White Paper Describing Produced Waterfmm Production of Crude Oil, Natural Gas, and Coal Bed Methane. Prepared for the US Department of Energy, January 2004... [Pg.292]

Leanza, R., Rossetti, I., Fabbrini, L., et al. (2000). Perovskite Catalysts for the Catalytic Flameless Combustion of Methane - Preparation by Flame-hydrolysis and Characterisation by TPD-TPR-MS and EPK.Appl. Catal. B Environ., 28, pp. 55-64. [Pg.87]

A soln. of tricyclohexylborane in tetrahydrofuran added to a-lithiobis(phenylthio)-methane prepared at -30° from bis(phenylthio)methane and n-butyllithium in dry tetrahydrofuran under argon, then treated with pH 7.0 buffer and 30%-H2O2... [Pg.216]

HOCH2CH2CH2CH2OH. B.p. 228"C. Prepared ethyne plus methanal, hydrogenated to butanediol. Used in production of y-buty-rolactone and 2-pyrrolidone. Widely used in polyurethane products, butylenes See butenes. [Pg.72]

HOCH2C = CCH2OH. White solid, m.p. 58 C, b.p. 238- C prepared by the high pressure reaction between ethyne and methanol and also from BrMgCCMgBr and methanal. Used in electroplating (Ni), as a corrosion inhibitor, and in paint and varnish removal. [Pg.73]

CH2CI2. A colourless liquid with a chloroform-like odour b.p. 4I°C. Prepared by heating chloroform with zinc, alcohol and hydrochloric acid manufactured by the direct chlorination of methane. Decomposed by water at 200°C to give methanoic and hydrochloric acids. Largely used as a solvent for polar and non-polar substances, particularly for paint removal (30%), dissolving cellulose acetate and degreasing (10%). It is more stable than carbon tetrachloride or chloroform especially towards moisture or alkali. It is somewhat toxic. U.S. production 1981 280000 tonnes. [Pg.135]

Colourless solid m.p. 132-134 C. An important intermediate for preparing indole derivatives, produced by treating indole under Mannich reaction conditions with methanal and dimethylamine. [Pg.140]

Prepared by the action of chloroethanoic acid upon anthranilic acid. It can also be prepared by the action of KCN and methanal on anthranilic acid, followed by hydrolysis with NaOH of the nitrile of anthranilic acid first produced. [Pg.305]

CH2 CH-0-CH CH2 Colourless inflammable liquid, with a characteristic ethereal odour, b.p. 28-31°C. Prepared by the action of KOH on 2,2 -dichiorodiethyl ether. It is unstable, breaking down to methanal and methanoic acid. [Pg.420]

Methylene chloride CHjCl, b.p. 41°, is obtained as a by product in the com mercial preparation of chloroform by the reduction of carbon tetrachloride with moist iron and also as one of the products in the chlorination of methane it is a useful extraction solvent completely immiscible with water. [Pg.300]

The superacid-catalyzed electrophile oxygenation of saturated hydrocarbons, including methane with hydrogen peroxide (via H302 ) or ozone (via HOs ), allowed the efficient preparation of oxygenated derivatives. [Pg.166]

Silyl ethers serve as preeursors of nucleophiles and liberate a nucleophilic alkoxide by desilylation with a chloride anion generated from CCI4 under the reaction conditions described before[124]. Rapid intramolecular stereoselective reaction of an alcohol with a vinyloxirane has been observed in dichloro-methane when an alkoxide is generated by desilylation of the silyl ether 340 with TBAF. The cis- and tru/u-pyranopyran systems 341 and 342 can be prepared selectively from the trans- and c/.y-epoxides 340, respectively. The reaction is applicable to the preparation of 1,2-diol systems[209]. The method is useful for the enantioselective synthesis of the AB ring fragment of gambier-toxin[210]. Similarly, tributyltin alkoxides as nucleophiles are used for the preparation of allyl alkyl ethers[211]. [Pg.336]

Chlorination of methane provides approximately one third of the annual U S pro duction of chloromethane The reaction of methanol with hydrogen chloride is the major synthetic method for the preparation of chloromethane... [Pg.167]

Bromination of methane is exothermic but less exothermic than chlorination The value calculated from bond dissociation energies is AH° = -30 kJ Al though bromination of methane is energetically fa vorable economic considerations cause most of the methyl bromide prepared commercially to be made from methanol by reaction with hydrogen bromide... [Pg.174]

The reaction is endothermic and the equilibrium favors ethylene at low temperatures but shifts to favor acetylene above 1150°C Indeed at very high temperatures most hydro carbons even methane are converted to acetylene Acetylene has value not only by itself but IS also the starting material from which higher alkynes are prepared... [Pg.364]

A mixture of the two reactants carbon monoxide and hydrogen is called synthesis gas and IS prepared by several processes The most widely used route to synthesis gas employs methane (from natural gas) and gives a 3 1 hydrogen to carbon monoxide ratio... [Pg.624]

The elimination of alcohol from P-alkoxypropionates can also be carried out by passing the alkyl P-alkoxypropionate at 200—400°C over metal phosphates, sihcates, metal oxide catalysts (99), or base-treated zeoHtes (98). In addition to the route via oxidative carbonylation of ethylene, alkyl P-alkoxypropionates can be prepared by reaction of dialkoxy methane and ketene (100). [Pg.156]

Docusate Calcium. Dioctyl calcium sulfosuccinate [128-49-4] (calcium salt of l,4-bis(2-ethylhexyl)ester butanedioic acid) (11) is a white amorphous soHd having the characteristic odor of octyl alcohol. It is very slightly soluble in water, and very soluble in alcohol, polyethylene glycol 400, and com oil. It may be prepared directly from dioctyl sodium sulfo succinate dissolved in 2-propanol, by reaction with a methan olic solution of calcium chloride. [Pg.201]

Hafnium Carbide. Hafnium carbide, HfC, is a dark gray brittle soHd. This carbide can be prepared by heating an intimate mixture of the elements or by the reaction of hafnium tetrachloride with methane at 2100°C, but is commonly produced by the reaction of hafnium oxide with lampblack... [Pg.444]


See other pages where Methane, preparation is mentioned: [Pg.191]    [Pg.191]    [Pg.303]    [Pg.45]    [Pg.812]    [Pg.239]    [Pg.191]    [Pg.191]    [Pg.303]    [Pg.45]    [Pg.812]    [Pg.239]    [Pg.141]    [Pg.262]    [Pg.405]    [Pg.405]    [Pg.1075]    [Pg.113]    [Pg.69]    [Pg.304]    [Pg.3]    [Pg.446]    [Pg.216]    [Pg.307]    [Pg.151]    [Pg.385]    [Pg.241]   
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See also in sourсe #XX -- [ Pg.106 , Pg.118 ]

See also in sourсe #XX -- [ Pg.24 , Pg.25 , Pg.26 ]

See also in sourсe #XX -- [ Pg.113 , Pg.114 , Pg.796 ]

See also in sourсe #XX -- [ Pg.237 , Pg.617 ]




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