Mesoporous graphitic carbon nitride

Fischer, A., Antonietti, M., Thomas, A. 2007. Growth confined by the nitrogen source S)fnthesis of pure metal nitride nanoparticles in mesoporous graphitic carbon nitride. Adv. Mater. 19 264-267. 

DAD 14b] Dadashi-Silab S., Tasdelen M.A., Kiskan B. et al., Photochemically nediated atom transfer radical polymerization using polymeric semiconductor mesoporous graphitic carbon nitride , Macromolecular Chemistry and Physics, vol. 215, pp. 675-681,2014. 

Compared with homogeneous catalysis, the heterogeneous photoredox catalysis is mainly underdeveloped. The CdS, Ti02, mesoporous graphitic carbon nitride. 

Recently, Blechert s group used a heterogeneous photocatalyst, mesoporous graphitic carbon nitride (mpg-CN), to achieve the trifluoromethylation of heteroarenes with CF3SO2CI under visible-light irradiation (Scheme 13.32) [67]. 

As a rather unusual application of 1,2,4-triazine, it is necessary to mention the preparation of highly ordered and graphitic mesoporous carbon nitride with an ordered porous structure and a high nitrogen content by a nano-hard-templating approach through a simple polymerization of 3-amino-l,2,4-triazine inside the pore channels of a mesoporous silica template (13JMCA2913). 

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