Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Masticadienonic acid

Terebinthales Anacardiaceae Pistacia (mastic) Euphanes (masticadienonic acid, isomasticadienonic acid), oleanananes (oleanonic acid, moronic acid), dammaranes... [Pg.13]

Moronic, isomasticadienonic and masticadienonic acids are considered as characteristic and diagnostic molecules for assessing the presence of mastic resin in ancient samples [2,88,94,123,124],... [Pg.16]

D.H.R. Barton, E. Seoane, Triterpenoids. Part XXII. The constitution and stereochemistry of masticadienonic acid, Journal of the Chemical Society, 4150 4157 (1956). [Pg.33]

Figure 12.4 THM GC/MS curve of mastic resin. Peak assignments 1, nor f3 amyrone 2, (8R) 3 oxo hydroxypolipoda 13E,17E,21 triene 3, nor 28 olean 18 en 3 one 4, moronic acid methyl ester 5, oleanonic acid methyl ester 6, oleanonic aldehyde 7,8, (iso)masticadienonic acid methyl ester... Figure 12.4 THM GC/MS curve of mastic resin. Peak assignments 1, nor f3 amyrone 2, (8R) 3 oxo hydroxypolipoda 13E,17E,21 triene 3, nor 28 olean 18 en 3 one 4, moronic acid methyl ester 5, oleanonic acid methyl ester 6, oleanonic aldehyde 7,8, (iso)masticadienonic acid methyl ester...
Several studies have dealt with the problem of discriminating between mastic and dammar, and three marker compounds of mastic have been identified moronic, masticadienonic and acetyl masticadienolic acids [42], The chemical structure of (iso)masticadienonic acid and 3-0-acetyl-3-epi(iso)masticadienonic acid is characterized by a side chain, as for dammarane molecules, but with a carboxylic acid end group (Table 12.1). Under pyrolysis conditions this side chain is susceptible to cleavage as demonstrated by the presence, among the pyrolysis products of mastic, of 2-methyl-pent-2,4-dienoic acid, that perfectly matches with the chemical structure of the side chain end. In addition 3-(9-acetyl-3-epi-(iso)masticadienolic acid also loses the acetyl group and, in contrast to masticadienonic acid, is not detected at all. [Pg.339]

Figure 7.10 Some triterpenoid compounds found in mastic (Pistacia resin) (a) moronic acid, (b) oleanonic acid, (c) zsomasticadienonic acid, (d) masticadienonic acid. Figure 7.10 Some triterpenoid compounds found in mastic (Pistacia resin) (a) moronic acid, (b) oleanonic acid, (c) zsomasticadienonic acid, (d) masticadienonic acid.
Resin-like exudate (wound secretion) from pistachio trees (Pistacia lentiscus, Anacardiaceae) indigenous in the Mediterranean region soluble in diethyl ether, partly soluble in ethanol and turpentine oil mp. 105-120°C. The resin fraction contains triterpene acids such as masticadienonic acid (C30H46O3, Mr... [Pg.384]

The first online TLC-MS attempt in the field of triterpenoids was done only in 2005 in the study of the photo-oxidation of natural di- and triterpenoid resins used as paint varnishes [10], The resinous samples were applied onto a cellulose-coated TLC plate, which afterward was subjected to direct MALDI-TOF-MS analysis without any development. The plates were only sprayed with a saturated ethanol solution of 2,5-dihydroxybenzoic acid as matrix to assist the ionization of compounds. Triterpenoids were observed as protonated molecules or as sodium clusters. Dammaradienone, dammaradienol, nor-a-amyrone, and dammarenolic, oleanonic, and ursonic acid were detected in dammar resin moronic acid, masticadienonic acid, and 3-0-acetyl-3-epi(iso)masticadienonic acid were found in mastic resin and diterpenoid abietane and pimarane acids were present in colophony. The induced aging process produced oxidized triterpenoids, which were observed in the MS spectra... [Pg.315]

FIGURE 12.1 Typical terpenes. (a) Isoprene is the nominal buSding block of the teipenoids. (b) Pinene is a major constituent of oil of turpentine, (c) Abietic acid is a major constituent of rosin (colophony). (d) Masticadienonic acid is a major constituent of mastic resin. The wavy lines in (b) and (c) indicate the junctions between the five carbon monomer units (isoprene), two of which form a terpene. [Pg.257]

Pistacia vera include masticadienonic aldehyde (62) and the acetates (63) and (64) of 3-epimasticadienolic acid and 3-epi-isomasticadienolic acid. A partial synthesis of corollatadiol (65) from tirucallol acetate has been reported. Evidence has been presented for the (205,24i ) configuration of (65). ... [Pg.196]

Diterpenoids (7-oxo-dehydroabietic and 15-hydroxy-7-oxo-dehydroabietic acid) triterpenoids (isomasticadienonic, masticadienonic, moronic and oleanonic acids) alkanes (C25-C33), wax esters (C o-Cso), hydroxy wax esters (C42-CS4) hydroxyaromatic acids fatty adds steranes and hopanes... [Pg.801]

See other pages where Masticadienonic acid is mentioned: [Pg.227]    [Pg.339]    [Pg.156]    [Pg.384]    [Pg.384]    [Pg.384]    [Pg.244]    [Pg.257]    [Pg.270]    [Pg.773]    [Pg.227]    [Pg.339]    [Pg.156]    [Pg.384]    [Pg.384]    [Pg.384]    [Pg.244]    [Pg.257]    [Pg.270]    [Pg.773]    [Pg.16]   
See also in sourсe #XX -- [ Pg.242 ]

See also in sourсe #XX -- [ Pg.773 ]



SEARCH



Iso-masticadienonic acid

© 2024 chempedia.info