Mass volumetric

For calculation of the volumetric flow rate only the cross section area of the pipe is to be known. In order to give flow under standard conditions the temperature and pressure must be measured, and for conversion to mass flow the composition or density of the gas must be determined. These process parameters are often monitored by calibrated instrumentation. 

To ensure that S eas is determined accurately, we calibrate the equipment or instrument used to obtain the signal. Balances are calibrated using standard weights. When necessary, we can also correct for the buoyancy of air. Volumetric glassware can be calibrated by measuring the mass of water contained or delivered and using the density of water to calculate the true volume. Most instruments have calibration standards suggested by the manufacturer. 

After removing the membranes from an eggshell, the shell is dried and its mass recorded as 5.613 g. The eggshell is transferred to a 250-mL beaker and dissolved in 25 mL of 6 M HCl. After filtering, the solution containing the dissolved eggshell is diluted to 250 mL in a volumetric flask. A 10.00-... 

In molecular weight determinations it is conventional to dissolve a measured mass of polymer m2 into a volumetric flask and dilute to the mark with an appropriate solvent. We shall use the symbol Cj to designate concentrations in mass per volume units. In practice, 100-ml volumetric flasks are often used, in which case C2 is expressed in grams per 100 ml or grams per deciliter. Even though these are not SI units, they are encountered often enough in the literature to be regarded as conventional solution units in polymer chemistry. 

The value of the saturation concentration,, is the spatial average of the value determined from a clean water performance test and is not corrected for gas-side oxygen depletion therefore K ji is an apparent value because it is determined on the basis of an uncorrected. A tme volumetric mass transfer coefficient can be evaluated by correcting for the gas-side oxygen depletion. However, for design purposes, can be estimated from the surface saturation concentration and effective saturation depth by... 

Meters can be further divided into three subgroups depending on whether fluid velocity, the volumetric flow rate, or the mass flow rate is measured. The emphasis herein is on common flow meters. Devices of a highly specialized nature, such as biomedical flow meters, are beyond the scope of this article. 

Characteristics of ECM. By use of Faraday s laws if is the mass of metal dissolved, and because m = r p where r is the corresponding volume and p the density of the anode metal, the volumetric removal rate of anodic metal Tjdot is given by... 

Before a source analysis program is undertaken, it is important to decide which information is really required. Sampling sites must be selected with care. Choice of the site can significantly affect accuracy and cost. Care must also be taken in the selection of sampling points at the site. Measurement usually involves the deterrnination of temperature, concentration, and characterization of the gas contaminants. It also requires the mass rates of emission of each contaminant, therefore concentration and volumetric flow data are required. 

Precision mass and volumetric methods use very precise measurements of pressure and/or level in the tank to detect leaks. The tank must be closed so that no Hquid enters or leaves the tank. The threshold of detection and fuimel required to perform a rehable test become greater as tank size increases. 

Critical Volume The critical volume of a compounci is the volume occupieci by a set mass of a compounci at its critical temperature anci pressure. While useful in itself, the critical volume is extensively useci in equations for estimating volumetric fractions. 

Kcfl Overall volumetric gas-pbase mass-transfer dilute systems kmoP[(s-m )(mole-fraction solute in gas)] (lbmol)/[(b-ft (mole-fraction solute in gas)]... 

For theJth. component, my = m iDy is the component mass flow rate in stream i is the mass fraction of component j in stream i and q is the net reaction rate (mass generation minus consumption) per unit volume V that contains mass M. If it is inconvenient to measure mass flow rates, the product of density and volumetric flow rate is used instead. 

Volumetric Mass-Transfer Coefficients and Kia Experimental determinations of the individual mass-transfer coefficients /cg and /cl and of the effective interfacial area a involve the use of extremely difficult techniques, and therefore such data are not plentiful. More often, column experimental data are reported in terms of overall volumetric coefficients, which normally are defined as follows ... 

Extrapolation of KgO data for absorption and stripping to conditions other than those for which the origin measurements were made can be extremely risky, especially in systems involving chemical reactions in the liquid phase. One therefore would be wise to restrict the use of overall volumetric mass-transfer-coefficient data to conditions not too far removed from those employed in the actual tests. The most reh-able data for this purpose would be those obtained from an operating commercial unit of similar design. 

To illustrate the development of a physical model, a simplified treatment of the reactor, shown in Fig. 8-2 is used. It is assumed that the reac tor is operating isothermaUy and that the inlet and exit volumetric flows and densities are the same. There are two components, A and B, in the reactor, and a single first order reaction of A B takes place. The inlet concentration of A, which we shall call Cj, varies with time. A dynamic mass balance for the concentration of A (c ) can be written as follows ... 

The usual measuring device for feed flow is a magnetic flowmeter, which is a volumetric device whose output F must be multiplied by density p to produce mass flowMo- For most aqueous solutions which are fed to evaporators, the product of density and the function of solid content appearing above is linear with density ... 

One manner in which size may be computed, for estimating purposes, is by employing a volumetric heat-transfer concept as used for rotary diyers. It it is assumed that contacting efficiency is in the same order as that provided by efficient lifters in a rotaiy dryer and that the velocity difference between gas and solids controls, Eq. (12-52) may be employed to estimate a volumetric heat-transfer coefficient. By assuming a duct diameter of 0.3 m (D) and a gas velocity of 23 m/s, if the solids velocity is taken as 80 percent of this speed, the velocity difference between the two would be 4.6 m/s. If the exit gas has a density of 1 kg/m, the relative mass flow rate of the gas G becomes 4.8 kg/(s m the volumetric heat-transfer coefficient is 2235 J/(m s K). This is not far different from many coefficients found in commercial installations however, it is usually not possible to predict accurately the acdual difference in velocity between gas and soRds. Furthermore, the coefficient is influenced by the sohds-to-gas loading and particle size, which control the total solids surface exposed to the gas. Therefore, the figure given is only an approximation. 

Traditional Design Method The traditionally employed conventional procedure for designing packed-tower gas-absorption systems involving chemical reactions makes use of overall volumetric mass-transfer coefficients as defined by the equation... 

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