Producers, marginal

The approximate production of chemicals from a synthesis capacity equivalent to an annual processing of 500 billion cubic feet of natural gas is also shown in Table III and is there compared with the estimated production of the same chemicals in 1948. Even with such a large output, some of the chemicals now in high demand would be salable with only slight dislocations for marginal producers. Others would, of course, have a serious impact on present markets until substantial new outlets were developed. It seems reasonable to expect, however, that with new synthetic products being developed continually, all the chemicals could, in time, be marketed profitably. 

Marginal producers who will either curtail production or go out of business when the price drops... 

Seam margins are also important as this has a major impact on seam elasticity. The seam margin is due to the width of the needles on the sewing machine that produce the seam. Say, for example, a machine has two needles set at 6 mm apart. It will produce a wider seam margin as those needles set at 3 mm apart. Therefore, the wider seam margin produces a seam with a greater amount of elasticity than a narrow needle margin. 

Since adipic acid has been produced in commercial quantities for almost 50 years, it is not surprising that many variations and improvements have been made to the basic cyclohexane process. In general, however, the commercially important processes stiU employ two major reaction stages. The first reaction stage is the production of the intermediates cyclohexanone [108-94-1] and cyclohexanol [108-93-0], usuaHy abbreviated as KA, KA oil, ol-one, or anone-anol. The KA (ketone, alcohol), after separation from unreacted cyclohexane (which is recycled) and reaction by-products, is then converted to adipic acid by oxidation with nitric acid. An important alternative to this use of KA is its use as an intermediate in the manufacture of caprolactam, the monomer for production of nylon-6 [25038-54-4]. The latter use of KA predominates by a substantial margin on a worldwide basis, but not in the United States. 

Some treatments are practiced so widely that untreated material is essentially unknown ia the jewelry trade. The heating of pale Fe-containing chalcedony to produce red-brown carnelian is one of these. Another example iavolves turquoise where the treated material is far superior ia color stabiUty. Such treatments have traditionally not been disclosed. Almost all blue sapphire on the market has been heat treated, but it is not possible to distinguish whether it was near-colorless comndum containing Fe and Ti before treatment, or whether it had already been blue and was only treated ia an attempt at marginal improvement. The irradiation of colorless topa2 to produce a blue color more iatense than any occurring naturally is, however, self-evident, and treatments used on diamond are always disclosed. 

Catechol is produced by coproduction with hydroquinone starting from phenol. Other techniques such as coal extraction remain marginal. The installed capacities (- 25,000 t/yr) are now sufficient to cover the demand. Catechol is mainly used for synthesis in food, pharmaceutical, or agrochemical ingredients. A specific appHcation of / fZ-butylcatechol is as a polymerisation inhibitor. 

The largest cost to produce malt is the cost of barley. U.S. barley and malt prices from 1966 through 1992 are shown in Eigure 8, along with the spread between malt and barley prices. The spread or margin between malt and barley prices is expressed in /t of malt and assumes 5% of barley purchased is cleanout barley and that 92% of barley soHds ends up as malt. Barley and malt prices are pubHshed in The Brenners Bulletin (Thiensville, Wisconsin). 

Commodity chemical producers have varying records of performance in appHcations research. It is usually high on the priority Hst when the product is stiU evolving, eg, low density polyethylene in the late 1950s and early 1960s. In times of pinched profit margins, these services often have been dropped, sometimes to be reinstituted, especially if totally new uses appeared. 

An additional mole of ammonium sulfate per mole of final lactam is generated duting the manufacture of hydroxylamine sulfate [10039-54-0] via the Raschig process, which converts ammonia, air, water, carbon dioxide, and sulfur dioxide to the hydroxylamine salt. Thus, a minimum of two moles of ammonium sulfate is produced per mole of lactam, but commercial processes can approach twice that amount. The DSM/Stamicarbon HPO process, which uses hydroxylamine phosphate [19098-16-9] ia a recycled phosphate buffer, can reduce the amount to less than two moles per mole of lactam. Ammonium sulfate is sold as a fertilizer. However, because H2SO4 is released and acidifies the soil as the salt decomposes, it is alow grade fertilizer, and contributes only marginally to the economics of the process (145,146) (see Caprolactam). 

Chemical Toxicity. Radiopharmaceuticals are subject to the same requirements for safety as are other pharmaceuticals, and are tested for chemical toxicity in much the same manner. It is generally understood, however, that patients are likely to receive relatively few doses of any given radiopharmaceutical so that the effects of long-term chronic exposure to the compound rarely need be assessed. Safety margins, that is, the ratio of the adininistered dose to the lowest dose that produces an observable effect, are usually on the order of 100 or more. 

The word calcium is derived from calx, the Latin word for lime. The Romans used large quantities of calcium oxide or lime as mortar in constmction (see Lime and limestone). Because calcium compounds are very stable, elemental calcium was not produced until 1808 when a mercury amalgam resulted from electrolysis of calcium chloride in the presence of a mercury cathode. However, attempts to isolate the pure metal by distilling the mercury were only marginally successful. 

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