Limitations liquid injection molding

Liquid colors can be used in injection molding and extrusion. Thin films usually require large amounts of color and so are not usually made with liquid color. Thick films and sheet are suitable applications for Liquid. Usually, 1-3% is the practical limit for a letdown ratio, but liquids have been used up to 8% in special circumstances. For letdown ratios of 1 % and less, liquid color is often the preferred method of coloring or introducing additives. 

Commercially, suspension polymerizations have been limited to the free radical polymerization of water-insoluble liquid monomers to prepare a number of granular polymers, including polystyrene, poly(vinyl acetate), poly(methyl methacrylate), polytetrafluoroethylene, extrusion and injection-molding grades of poly(vinyl chloride), poly(styrene-co-acrylonitrile) (SAN), and extrusion-grade poly(vinylidene chloride-covinyl chloride). It is possible, however, to perform inverse suspension polymerizations, where water-soluble monomer (e.g., acrylamide) is dispersed in a continuous hydrophobic organic solvent. 

Several years ago, industry discovered that both minimum and maximum temperature and pressure limits exist for optimum injection molding of polystyrene. Samples injected below these minimums would not fill the molds. Those injected above the maximum limits would stick to the mold. Boyer ascribed the lower temperature limit to the liquid-liquid (T/i) transition in polystyrene. In the present experiments, the molding temperature at which the pellet boundaries no longer reform on reheat seem to fall in the neighborhood of this liquid-liquid transition. 

The cure of thermoset resins involves the transformation of a liquid resin, first with an increase in viscosity to a gel state (rubber consistency), and finally to a hard solid. In chemical terms, the liquid is a mixture of molecules that reacts and successively forms a solid network polymer. In practice the resin is catalyzed and mixed before it is injected into the mold thus, the curing process will be initialized at this point. The resin cure must therefore proceed in such a way that the curing reaction is slow or inhibited in a time period that is dictated by the mold fill time plus a safety factor otherwise, the increase in viscosity will reduce the resin flow rate and prevent a successful mold fill. On completion of the mold filling the rate of cure should ideally accelerate and reach a complete cure in a short time period. There are limitations, however, on how fast the curing can proceed set by the resin itself, and by heat transfer rates to and from the composite part. 

Melting (plasticating) the plastic is accomplished in a plasticator (screw in barrel as described in Chapter 3). This melt is forced into a clamped mold cavity. The liquid, molten plastic from the injection cylinder of the injection machine is transferred through various flow channels into the cavities of a mold where it is finally shaped into the desired object by the confines of the mold cavity. What makes this apparently simple operation complex is the limitations of the hydraulic or electrical circuitry used in the actuation of the injection plunger and the complicated flow paths involved in the filling of the mold (Chapter 17). Finally opening the mold to eject the plastic after keeping the material confined under pressure as the heat in the melt is removed to solidify the plastic into the shape desired. 

Spin casting can use plastic molds, such as silicone, to produce close tolerance, highly cost effective, limited production in a variety of materials. The process uses easily adjustable centrifugal force to inject liquid thermoset plastics into a circular disc-shaped elastomeric mold under pressure, completely and rapidly filling the mold cavities. 

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