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Formula Lewis

So far we have emphasized structure in terms of electron bookkeeping We now turn our attention to molecular geometry and will see how we can begin to connect the three dimensional shape of a molecule to its Lewis formula Table 1 6 lists some simple com pounds illustrating the geometries that will be seen most often m our study of organic chemistry... [Pg.29]

The Lewis rules are relatively straightforward easiest to master and the most familiar You will find that your ability to write Lewis formulas increases rapidly with experience Get as much practice as you can early m the course Success m organic chemistry depends on writing correct Lewis structures... [Pg.93]

Orbital hybridization descriptions because they too are based on the shared electron pair bond enhance the information content of Lewis formulas by distinguishing... [Pg.93]

There remains one topic to be discussed in our survey of chemical bonding in organic compounds. For most compounds, all the molecules have the same structure, whether or not this structure can be satisfactorily represented by a Lewis formula. But for many other compounds there is a mixture of two or more structurally distinct compounds that are in rapid equilibrium. When this phenomenon, called tauto-merism, exists, there is a rapid shift back and forth among the molecules. In most cases, it is a proton that shifts from one atom of a molecule to another. [Pg.73]

For more electropositive elements, which have an inferior number of valence electrons in the first place, and which in addition have to supply electrons to a more electronegative partner, the number of available electrons is rather small. They can gain electrons in two ways first, as far as possible, by complexation, i.e. by the acquisition of ligands and second, by combining their own atoms with each other. This can result in the formation of clusters. A cluster is an accumulation of three or more atoms of the same element or of similar elements that are directly linked with each other. If the accumulation of atoms yields a sufficient number of electrons to allow for one electron pair for every connecting line between two adjacent atoms, then each of these lines can be taken to be a 2c2e bond just as in a common valence bond (Lewis) formula. Clusters of this kind have been called electron precise. [Pg.138]

Lewis formulas are representations of molecules or ions which show... [Pg.105]

See Exercise 7-46 Solution for more appropriate Lewis formulas due to formal charge examination.)... [Pg.113]

A molecule or polyatomic ion for which two or more Lewis formulas with the same arrangements of atoms can be drawn to describe the bonding is said to exhibit resonance. The two structures given here do not have the same arrangement of atoms, and hence are not resonance structures. [Pg.114]

The Lewis formula predicts 2 electron groups around the central Be atom and a linear electronic geometry. There are no lone pairs on the Cd atom, so the molecular geometry is the same as the electronic geometry linear (Section 8-5). [Pg.119]

The Lewis formula for the molecule (type AB4) predicts 4 electron groups around the central Sn atom and a tetrahedral electronic geometry. Since there are no lone pairs on Sn, the molecular geometry is also tetrahedral (Section 8-7). [Pg.119]

This polyatomic ion (type AB6), like (c), does not obey the octet rule without modification since 12 electrons must be shared to form 6 Sb-F bonds. Sb is a 5 A element, but the charge on the ion gives an extra electron which participates in bonding. The Lewis formula predicts 6 electron groups around the central Sb atom and an octahedral electronic geometry. There are no lone pairs on the Sb atom, so the ionic geometry is the same as the electronic geometry (Section 8-12). [Pg.119]

The Lewis formula for the ion (type AB3U) predicts 4 electron groups around O including 1 lone pair of electrons. The electronic geometry is tetrahedral and the ionic geometry is trigonal pyramidal (Section 8-8). [Pg.120]

The Lewis formula shows 6 electron groups around the central P atom. The electronic geometry and the ionic geometry are both octahedral because there are no lone pairs of electrons on P (Section 8-12). [Pg.121]

The Lewis formula shows 5 electron groups around the central P atom and its electronic geometry is trigonal bipyramidal. The ionic geometry is a seesaw due to the presence of 1 lone pair of electrons on the central P atom (Section 8-11). [Pg.121]

The Lewis formula predicts 5 electron groups around the central I atom and a trigonal bipyramidal electronic geometry. This ionic geometry is linear. [Pg.122]

The Lewis formula of N02+ (type AB2) shows 2 electron groups around the central N atom. [Pg.131]

The Lewis formulas predict spid hybridization of P in PF5 (5 electron groups), changing to spid1 hybridization of P in PF6 (6 electron groups). [Pg.131]

The Lewis formulas predict sp hybridization of C in both molecules since both C atoms have 2 electron groups around them. [Pg.131]

The Lewis formulas predict sp2 hybridization of A1 in A1I3 (3 electron groups) changing to sp3 hybridization of A1 in A1I4 (4 electron groups). [Pg.131]

The Lewis formula predicts 2 electron groups around each C atom, resulting in the linear structure of C302. [Pg.134]

In Chapter 2, we saw molecular and empirical formulas. Recall that the molecular formula indicates the kind and actual number of atoms present. The empirical formula simply shows the kind of atoms present and their lowest whole number ratio. In this chapter, structural formulas are important. The Lewis formula of a compound is an example of a structural formula. A structural formula shows the number and type of atoms present, as well as the bonding pattern. The bonding pattern shows which atoms bond to each other. It usually... [Pg.129]

A Lewis structure can show the bonding pattern in a covalent compound. In Lewis formulas, we show the valence electrons that are not involved in bonding as dots surrounding the element symbols. The valence electrons involved in bonding are present as dashes. There are several ways of deriving the Lewis structure, but here is one that works well for most compounds that obey the octet rule. [Pg.133]

Diboracyclopropane 1A may serve as an example to illustrate the principles discussed above. With the carbon atom tetrahedrally coordinated by two hydrogen and two boron atoms its classical structure is well described by the Lewis formula in Scheme 3.2-1. Hyperconjugation between the CH bonds and the formally empty p orbitals at the boron atoms leads to only a relatively minor reorganization of electron density compared with that suggested by the Lewis formula. [Pg.269]

Removal of one of the methylene protons generates a carbanionic center, but the corresponding single Lewis formula is a poor description of the electronic structure. More mesomeric forms of 2A may be written to give a more adequate fomu-lation. Alternatively, a circle may be drawn to symbolize the 3c2e n bond in 2A, resulting from overlapping p orbitals perpendicular to the plane of atoms involved. [Pg.269]


See other pages where Formula Lewis is mentioned: [Pg.13]    [Pg.25]    [Pg.412]    [Pg.13]    [Pg.25]    [Pg.774]    [Pg.956]    [Pg.19]    [Pg.72]    [Pg.120]    [Pg.120]    [Pg.125]    [Pg.130]    [Pg.134]    [Pg.134]   
See also in sourсe #XX -- [ Pg.32 , Pg.164 ]

See also in sourсe #XX -- [ Pg.101 , Pg.108 , Pg.109 ]

See also in sourсe #XX -- [ Pg.71 , Pg.79 , Pg.81 ]




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