Laser-induced charge transfer

One of the diatomic molecular ions very often used for testing low temperature environments is Nj, most probably because it can be easily probed via exciting the A state with cheap laser-diodes. This allows one to determine the rotational and translational temperature of stored ions with the method of laser induced charge transfer. The slightly endothermic (179 meV) charge transfer with At is used in the following way. In a first step photons induce the transition... 

Fig. 5 (a) Schematic illustration of the structure of a quantum dot sensitized solar cell (QDSC), and (b) schematic illustration of photo induced charge transfer processes following a laser pulse... 

Hamilton C E, Bierbaum V M and Leone S R 1985 Product vibrational state distributions of thermal energy charge transfer reactions determined by laser-induced fluorescence in a flowing afterglow Ar" + CC -> CC (v= 0-6) + Ar J. Chem. Rhys. 83 2284-92... 

Sonnenfroh D M and Leone S R 1989 A laser-induced fluorescence study of product rotational state distributions in the charge transfer reaction Ar <-i. i, ) + Ni Ar + MfXjat 0.28 and 0.40 eV J. them. Phys. 90 1677-85... 

Collet E, Lemee-Cailleau MH, Buron-Le Cointe M, Cailleau H, Wulff M, Luty T, Koshihara S, Meyer M, Toupet L, Rabiller P, Techert S (2003) Laser-induced ferroelectric structural order in an organic charge-transfer crystal. Science 300 612-615... 

Figure 6.10 Ultrafast efficient switching in the five-state system via SPODS based on multipulse sequences from sinusoidal phase modulation (PL). The shaped laser pulse shown in (a) results from complete forward design of the control field. Frame (b) shows die induced bare state population dynamics. After preparation of the resonant subsystem in a state of maximum electronic coherence by the pre-pulse, the optical phase jump of = —7r/2 shifts die main pulse in-phase with the induced charge oscillation. Therefore, the interaction energy is minimized, resulting in the selective population of the lower dressed state /), as seen in the dressed state population dynamics in (d) around t = —50 fs. Due to the efficient energy splitting of the dressed states, induced in the resonant subsystem by the main pulse, the lower dressed state is shifted into resonance widi die lower target state 3) (see frame (c) around t = 0). As a result, 100% of the population is transferred nonadiabatically to this particular target state, which is selectively populated by the end of the pulse.

Photo-induced electron transfer between [Ru(bpy)3]2+-like centres covalently bound to positively-charged polymers (N-ethylated copolymers of vinylpyridine and [Ru(bpy)2(MVbpy)]2+) and viologens or Fe (III) has been studied using laser flash photolysis techniques. It is found that the backbone affects the rates of excited state quenching, the cage escape yield, and the back electron transfer rate because of both electrostatic and hydrophobic interactions. The effect of ionic strength on the reactions has been studied. Data on the electron transfer reactions of [Ru(bpy)3]2+ bound electrostatically or covalently to polystyrenesulphonate are also presented. 

Kliiner et al. [19] has analyzed the bimodal velocity distributions observed in NO desorption from NiO(0 01) shown in Fig. 24 by calculating a full ab initio potential energy surface (PES) for an excited state in addition to the PES for the ground state. Calculation of the electronically excited state uses a NiOj cluster embedded in a semi-infinite Madelung potential of point charges 2. The excited state relevant for laser-induced desorption is an NO -like intermediate, where one electron is transferred from the cluster to the NO molecule. 

Auerbach (37) recorded with a diode laser in a thin film of a solvent-coated polymer-metal ion salt complex (e.g., poly-2-vinylpyridine-AgNO3). Using short-duration pulses (120 ns) of 820-nm light (10 mW), he showed that high reflectivity marks could be created that could be read with a lower power diode laser. The mechanism is believed to involve thermally induced electron transfer from the polymer to the metal ion forming localized metal areas (Ag + e — Ag°). The concept is not limited to silver salts of gold, copper, and tellurium can be used. Polymers other than vinylpyridine that can form charge-transfer complexes with metal ions should function as electron-transfer binders. 

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