Karlin

Karlin, K.D. Metalloenzymes, structural motifs, and inorganic models. Science 261 701-708, 1993. 

K. D. Karlin and Z. Tyeklar (eds.). Bioinorganic Chemistry of Copper, Chapman Hall, New York, 1993, 506 pp. 

Karlin A (2002) Emerging structure of the nicotinic acetylcholine receptors. Nat Rev Neurosci 3 102-114... 

Arrow, Kenneth J., Karlin, Samuel, and Scarf, Herbert, Studies in the Mathematical Theory of Inventory and Production, Stanford University Press, Stanford, California, 1958. 

Karlin, K.D. Dithiolene Chemistry Synthesis, Properties, and Applications, vol. 52. Wiley, New York (2004)... 

Inspired by the results of aromatic-ring hydroxylation from the laboratory of Karlin and co-workers, a few groups provided further examples of such reactivity, including some structurally characterized complexes of modified m-xylyl-based pyridine-donor ligands (Schiff base and non-Schiff base acyclic ligands), as well as aliphatic amine donor ligands (179) (Cu-Cu 2.990 A),169 (180) (Cu-Cu 3.015 A),170 and (181) (Cu-Cu 2.999 A).171 172 A m-xylyl-based ligand system that was used by Mukherjee and co-workers in the formation of complex (181) also resulted in the isolation of a bis(/i-hydroxo)dicopper(II) complex (182) (Cu-Cu 3.004 A).171,172 Casella and co-workers demonstrated that when their dicopper(I) complex... 

To better understand copper-dioxygen coordination chemistry with varying ligand type, Karlin and co-workers synthesized and investigated spectroscopic and redox properties of many complexes (218) (t= 1.005) and (219) (r = 0.19), (220) (t = 0.50),209 (221) (r = 0.19) and (222)... 

To provide a model for nitrite reductases72 Karlin and co-workers characterized a nitrite-bound complex (226) (r = 0.05)214 In an endeavor to model nitrite reductase activity, Tanaka and co-workers prepared a few mononuclear complexes (227) (r = 0.74)215 (228) (r = 0.82),216 (229) (r = 0.97),217 (230) (r = 0.16),217 (231) (r = 0.07),217 and (232) (r = 0.43 and r = 0.53)217 and studied the electrochemical reduction of N02A As a part of their activity on modeling heme-copper terminal oxidases, Holm and co-workers prepared complex (233) (r = 0.96).218 Using a sterically hindered tris(pyridylmethyl)amine, Canary et al. prepared a complex (234) (r=1.00), studied its redox behavior, and discussed various factors that may contribute to the difference (higher potential for the new complex) in the redox potential of a Cu Cu1 couple between substituted and unsubstituted ligands.2 9... 

As a part of their work on copper(I)-dioxygen chemistry, Schindler and co-workers220 synthesized copper(I) (Section 6.6.4.2.2(iv)) and copper(II) complexes ((235) r = 0.12, and (236) r = 0.08) of a few tetradentate ligands, varying in their flexibility due to the presence of different chelate ring-forming arms, and studied their redox properties. Karlin and co-workers observed a... 

Karlin and co-workers synthesized a large number of mononuclear and dinuclear copper(I) complexes in their pursuit to understand the oxygenation behavior of copper(I) complexes (cf. Section 6.6.3.1.2(iv)). A listing of such complexes is provided in Table 5. Tolman and co-workers provided the answer to the question of bis(//-oxo)dicopper(III) core being capable of hydroxylating... 

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