Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Karlin Group Tridentate Model Compounds

Oxygenation rates were first examined for the system [Cu (R-XYL-H)]2+. In the model described here, two bis [2-(2-pyridyl)ethyl] amine (PY2) units are linked by a xylyl spacer group (R = H). Although initially proposed as a crude hemocyanin model, this system now is studied as a model for tyrosinase and is an example of hydrocarbon oxygenation taking place under mild conditions—that is, 1 atm 02 [Pg.219]

A thorough kinetic and thermodynamic analysis of this model system (small positive or negative enthalpies of formation are canceled by more negative entropies of formation) led Karlin s group to conclude that the stability of dioxygen binding is driven by favorable enthalpies, but unfavorable reaction entropies preclude observation of Cu2-02 at room temperatures.412 [Pg.220]


See other pages where Karlin Group Tridentate Model Compounds is mentioned: [Pg.217]    [Pg.217]    [Pg.226]    [Pg.293]   


SEARCH



Karlin

Model compounds

Modelling compounds

Tridentate

© 2024 chempedia.info