Ionic layer

Nicolau YF, Dupuy M, Brunei M (1990) ZnS, CdS, and Zni j Cdj S thin films deposited by the successive ionic layer adsorption and reaction process. J Electrochem Soc 137 2915-2924... 

Thermal motion of the ions in the EDL was included in the theories developed independently by Georges Gouy in Erance (1910) and David L. Chapman in England (1913). The combined elfects of the electrostatic forces and of the thermal motion in the solution near the electrode surface give rise to a diffuse distribution of the excess ions, and a diffuse EDL part or diffuse ionic layer with a space charge Qy x) (depending on the distance x from the electrode s surface) is formed. The total excess charge in the solution per unit surface area is determined by the expression... 

The reverse emulsion stabilized by sodium dodecylsulfate (SDS, R0S03 Na+) retards the autoxidation of dodecane [24] and ethylbenzene [21,26,27]. The basis for this influence lies in the catalytic decomposition of hydroperoxides via the heterolytic mechanism. The decay of hydroperoxides under the action of SDS reverse micelles produces olefins with a yield of 24% (T=413 K, 0.02mol L 1 SDS, dodecane, [ROOH]0 = 0.08 mol L 1) [27], The thermal decay gives olefins in negligible amounts. The decay of hydroperoxides apparently occurs in the ionic layer of a micelle. Probably, it proceeds via the reaction of nucleophilic substitution in the polar layer of a micelle. 

Successive Ionic Layer Adsorption and Reaction (SILAR) and Related Sequential Solution-Phase Deposition Techniques... 

Nicolau, Y. F. 1985. Solution deposition on thin solid compound films by a successive ionic-layer adsorption and reaction process. Appl. Surf. Sci. 22-23 1061-1074. 

Tolstoi, V. P. 1993. Synthesis of thin-layer structures by the ionic layer deposition method. Russ. Chem. Rev. 62 237-242. 

Pathan, H. M. Lockhande, C. D. 2004. Deposition of metal chalcogenide thin films by successive ionic layer adsorption and reaction (SILAR) method. Bull. Mater. Sci. 27 85-111. 

Lindroos, S. 1997. The successive ionic layer adsorption and reaction (SILAR) growth and characterization of ZnS and ZnS Mn thin films. Ph.D. thesis. University of Helsinki, Helsinki, Finland. 

Gao, X. D. Li, X. M. Yu, W. D. 2004. Morphology and optical properties of amorphous ZnS films deposited by ultrasonic-assisted successive ionic layer adsorption and reaction method. Thin Solid Films 468 43 17. 

Kanniainen, T. Lindroos, S. Prohaska, T. Friedbacher, G Leskela, M. Grasserbauer, M. Niinisto, L. 1995. Growth of zinc sulfide thin films with the successive ionic layer adsorption and reaction method as studied by atomic force microscopy./. Mater. Chem. 5 985-9. 

Valkonen, M. R Lindroos, S. Kanniainen, T. Leskela, M. Resch, R. Friedbacher, G Grasserbauer, M. 1998. Atomic force microscopy studies of ZnS films grown on (100) GaAs by the successive ionic layer adsorption and reaction method. J. Mater. Res. 13 1688-1692. 

Lindroos, S. Valkonen, M. Leskela, M. 1999. Growth of Zn02/Zn0 thin films by successive ionic layer adsorption and reaction—SILAR—technique. Adv. Sci. Technol. 20 43-50. 

Lindroos, S. Leskela, M. 2000. Growth of zinc peroxide (Zn02) and zinc oxide (ZnO) thin films by the successive ionic layer adsorption and reaction—SILAR— technique. Inter. J. Inorg. Mater. 2 197-201. 

Tolstoi, V. P Tolstobrov, E. V. 1994. Cu02/Ba02 superlattices grown by ionic layering. Inorg. Mater. 30 875-878. 

Tolstoy, V. P. 1997. The peroxide route of the successive ionic layer deposition procedure for synthesizing nanolayers of metal oxides, hydroxides and peroxides. Thin Solid Films 307 10-13. 

Park, S. DiMasi, E. Kim, Y.-I. Han, W. Woodward, P. M. Vogt, T. 2002. The preparation and characterization of photocatalytically active Ti02 thin films and nanoparticles using successive-ionic-layer-adsorption-and-reaction. Thin Solid Films 515 1250-1254. 

Tolstoi, V. R Tolstobrov, E. V. 2002. Synthesis of highly oriented a-Pb02 layers on the surfaces of single-crystal sihcon and quartz by successive ionic layer deposition. Russ. J.Appl. Chem. 75 1529-1531. 

Tolstoy, V. P. Murin, I. V. Reller, A. 1997. The synthesis of Mn(IV) oxide nanolayers by the successive ionic layer deposition method. Appl. Surf. Sci. 112 255-257. 

Gulina, L. B. Tolstoi, V. R Murin, I. V. 2001. Study of Co—Mn—O— and Li—Co—Mn—O—containing layers synthesized by successive ionic layer deposition on silica surface. Russ. J. Appl. Chem. 74 1955-1957. 

Nicolau, Y. F. Menard, J. C. 1990. Procedure for solution growth of zinc sulfide, cadmium sulfide, and zinc cadmium sulfide (Zn xCdxS) thin films by successive ionic-layer adsorptions and reactions. J. Appl. Electrochem. 20 1063-1066. 

Sasagawa, M. Nosaka, Y. 2002. Electrochemical evaluation of the roles of chelating reagents in Cd ion adsorption on CdS surface for the successive ionic layer adsorption and reaction (SILAR) deposition. J. Electroanal. Chem. 536 141-144. 

Valkonen, M. P. Ritala, M. Lindroos, S. Leskela, M. 1998. Solid solution CdxZni xS thin films grown by atomic layer epitaxy and successive ionic layer adsorption and reaction techniques. Mater. Sci. Forum 287-288 367-370. 

Puiso, J. 2004. Growth kinetics and properties of lead sulfide thin films deposited on crystalline silicon using successive ionic layer adsorption and reaction method. Ph.D. thesis. Kaunas University of Technology, Kaunas, Lithuania. 

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