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Iodination vinyl

A good starting point for this chemistry would be a allylic alcohol. Conversion of this allylic alcohol into a chlorinated or brominated vinyl ketone can be accomphshed using oxalyl halides [179]. A gold-catalyzed process that affords the iodinated vinyl ketones was successful at room temperature [183]... [Pg.654]

The majority of preparative methods which have been used for obtaining cyclopropane derivatives involve carbene addition to an olefmic bond, if acetylenes are used in the reaction, cyclopropenes are obtained. Heteroatom-substituted or vinyl cydopropanes come from alkenyl bromides or enol acetates (A. de Meijere, 1979 E. J. Corey, 1975 B E. Wenkert, 1970 A). The carbenes needed for cyclopropane syntheses can be obtained in situ by a-elimination of hydrogen halides with strong bases (R. Kdstcr, 1971 E.J. Corey, 1975 B), by copper catalyzed decomposition of diazo compounds (E. Wenkert, 1970 A S.D. Burke, 1979 N.J. Turro, 1966), or by reductive elimination of iodine from gem-diiodides (J. Nishimura, 1969 D. Wen-disch, 1971 J.M. Denis, 1972 H.E. Simmons, 1973 C. Girard, 1974),... [Pg.74]

A poly( -vinyl-2-pyrroHdinone)-iodine complex [25655-41-8] (PVP-iodine), has been used extensively in hospitals and elsewhere because of its germicidal, bactericidal, fungicidal, and generally disinfecting properties (150). It is sold as a solution that contains about 10% available, or active, iodine and about 5% inactive iodine, in the form of iodide ion (see Disinfectants and antiseptics Industrial antimicrobial agents). [Pg.367]

The first-order decomposition rates of alkyl peroxycarbamates are strongly influenced by stmcture, eg, electron-donating substituents on nitrogen increase the rate of decomposition, and some substituents increase sensitivity to induced decomposition (20). Alkyl peroxycarbamates have been used to initiate vinyl monomer polymerizations and to cure mbbers (244). They Hberate iodine quantitatively from hydriodic acid solutions. Decomposition products include carbon dioxide, hydrazo and azo compounds, amines, imines, and O-alkyUiydroxylarnines. Many peroxycarbamates are stable at ca 20°C but decompose rapidly and sometimes violently above 80°C (20,44). [Pg.131]

PuUy hydroly2ed poly(vinyl alcohol) and iodine form a complex that exhibits a characteristic blue color similar to that formed by iodine and starch (171—173). The color of the complex can be enhanced by the addition of boric acid to the solution consisting of iodine and potassium iodide. This affords a good calorimetric method for the deterrnination of poly(vinyl alcohol). Color intensity of the complex is effected by molecular weight, degree of... [Pg.481]

The observation in 1949 (4) that isobutyl vinyl ether (IBVE) can be polymerized with stereoregularity ushered in the stereochemical study of polymers, eventually leading to the development of stereoregular polypropylene. In fact, vinyl ethers were key monomers in the early polymer Hterature. Eor example, ethyl vinyl ether (EVE) was first polymerized in the presence of iodine in 1878 and the overall polymerization was systematically studied during the 1920s (5). There has been much academic interest in living cationic polymerization of vinyl ethers and in the unusual compatibiUty of poly(MVE) with polystyrene. [Pg.514]

Imidazole, 4,5-dibromo-l-methyl-synthesis, S, 399 Imidazole, 4,5-di-t-butyl-synthesis, S, 483 X-ray diffraction, S, 350 Imidazole, 4,5-dichloro-chlorination, S, 398 synthesis, S, 398, 473 Imidazole, 4-(3,4-dichlorophenyl)-nitration, 5, 433 Imidazole, 4,5-dicyano-hydrolysis, S, 435-436 synthesis, S, 461, 472, 487 Imidazole, 4,5-dicyano-1-vinyl-synthesis, S, 387 Imidazole, 4,5-dihydro-mass spectra, 5, 360 Imidazole, 4-(dihydroxybutyl)-synthesis, S, 484 Imidazole, 4,5-diiodo-nitration, S, 396 synthesis, S, 400 Imidazole, 2,4-diiodo-5-methyl-iodination, S, 400 Imidazole, 1,2-dimethyl-anions... [Pg.651]

The chain is propagated by abstraction of iodine by the cyclized vinyl radical intermediate. [Pg.716]

The key features of Curran s productive and elegant tandem radical cyclization strategy are illustrated in a retrosynthetic analysis for hirsutene (1) (see Scheme 27). The final synthetic event was projected to be an intermolecular transfer of a hydrogen atom from tri-rc-butyltin hydride to the transitory tricyclic vinyl radical 131. The latter can then be traced to bicyclic tertiary radical 132 and thence to monocyclic primary radical 133 through successive hex-5-enyl-like radical cyclizations. It was anticipated that the initial radical 133 could be generated through the abstraction of the iodine atom from... [Pg.409]

A valuable feature of the Nin/Crn-mediated Nozaki-Takai-Hiyama-Kishi coupling of vinyl iodides and aldehydes is that the stereochemistry of the vinyl iodide partner is reflected in the allylic alcohol coupling product, at least when disubstituted or trans tri-substituted vinyl iodides are employed.68 It is, therefore, imperative that the trans vinyl iodide stereochemistry in 159 be rigorously defined. Of the various ways in which this objective could be achieved, a regioselective syn addition of the Zr-H bond of Schwartz s reagent (Cp2ZrHCl) to the alkyne function in 165, followed by exposure of the resulting vinylzirconium species to iodine, seemed to constitute a distinctly direct solution to this important problem. Alkyne 165 could conceivably be derived in short order from compound 166, the projected product of an asymmetric crotylboration of achiral aldehyde 168. [Pg.606]

Stoicescu and Dimonie103 studied the polymerization of 2-vinylfuran with iodine in methylene chloride between 20 and 50 °C. The time-conversion curves were not analysed for internal orders but external orders with respect to catalyst and monomer were both unity. Together with an overall activation energy of 2.5 kcal/mole for the polymerization process, these were the only data obtained. Observations about the low DP s of the products, their dark colour, their lack of bound iodine and the presence of furan rings in the oligomers, inferred by infrared spectra (not reported), completed the experimental evidence. The authors proposed a linear, vinylic structure for the polymer, and a true cationic mechanism for its formation and discussed the occurrence of an initial charge-transfer complex on the... [Pg.72]

It is to be noted that N-vinylcarbazole (NVC) undergoes also living cationic polymerization with hydrogen iodide at —40 °C in toluene or at —78 °C in methylene chloride and that in this case no assistance of iodine as an activator is necessary 10d). NVC forms a more stable carbocation than vinyl ethers, and the living propagation proceeds by insertion between the strongly interacting NVC-cation and the nucleophilic iodide anion. [Pg.92]

Reaction between vinylic boranes and iodine or NaOMe... [Pg.1650]

Elimination of vinyl groups, [14] addition of iodine to double bonds, ester cleavage detection by IR... [Pg.148]

The rate of polymerization of vinyl 2-ethylhexyl ether catalyzed by iodine is proportional to [/2] [M] in accordance with an initiation-rate-controlling process... [Pg.223]

Particularly the chlorinated compounds have enjoyed range of applications vinyl chloride (chloro-ethene) as monomer for the production of PVC, tetra- and trichloroethenes as solvents for degreasing, and the insecticides l,l,l-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) and isomers of hexachlorocyclohexane (HCH) (benzene hexachloride). The biodegradation of fluorinated aliphatic compounds is generally different from the outlines that have emerged from investigations on their chlorinated, brominated, and even iodinated analogues. They are therefore treated separately in Part 4 of this chapter. [Pg.349]


See other pages where Iodination vinyl is mentioned: [Pg.272]    [Pg.488]    [Pg.799]    [Pg.374]    [Pg.246]    [Pg.161]    [Pg.419]    [Pg.461]    [Pg.339]    [Pg.3]    [Pg.87]    [Pg.12]    [Pg.184]    [Pg.100]    [Pg.123]    [Pg.216]    [Pg.127]    [Pg.177]    [Pg.603]    [Pg.607]    [Pg.616]    [Pg.132]    [Pg.9]    [Pg.64]    [Pg.487]    [Pg.591]    [Pg.638]    [Pg.654]    [Pg.693]    [Pg.228]    [Pg.923]    [Pg.1424]    [Pg.425]   
See also in sourсe #XX -- [ Pg.51 , Pg.60 , Pg.90 , Pg.100 ]




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Iodination vinyl, with

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