Intimate relationships

Using the SFA teclmique, it could be demonstrated that there is an intimate relationship between adliesion hysteresis and friction [28, 29, 77]. Both processes dissipate energy tlnough non-equilibrium mechanisms... 

A criterion for the position of the extent of the mesomerism of type 9 is given by the bond order of the CO bond, a first approximation to W hich can be obtained from the infrared spectrum (v C=0). Unfortunately, relatively little is known of the infrared spectra of amide anions. How-ever, it can be assumed that the mesomeric relationships in the anions 9 can also be deduced from the infrared spectra of the free amides (4), although, of course, the absolute participation of the canonical forms a and b in structures 4 and 9 is different. If Table I is considered from this point of view, the intimate relationship betw-een the position of the amide band 1 (v C=0) and the orientation (0 or N) of methylation of lactams by diazomethane is unmistakeable. Thus the behavior of a lactam tow ard diazomethane can be deduced from the acidity (velocity of reaction) and the C=0 stretching frequency (orientation of methylation). Three major regions can be differentiated (1) 1620-1680 cm h 0-methylation (2) 1680-1720 cm i, O- and A -methylation, w ith kinetic dependence and (3) 1730-1800 em , A -methylation, The factual material in Table I is... 

The Dewar structure (IV) has never been seriously considered since it suffers from the same defects, in an accentuated form, as the Kekule structure. Its advantage over the other structures is largely that it explains the intimate relationship that usually obtains between the para positions in the benzene ring. 

Therapeutic communities are supervised communal drug-free living situations for opioid and nonopioid drug abusers. Because substance abuse is viewed as a disorder of the whole person, the goal is a dramatic alteration of the addict s entire lifestyle (DeLeon 1985). Addicts are expected to five in these communities for 6—18 months. Therefore, they are not indicated for people who have a strong intimate relationship or stable employment. The community is a surrogate fam-... 

The great variety of mineral deposits of Japan reflects the complex geotectonic environments. An intimate relationship exists between igneous and hydrothermal activity, which in turn reflects the plate tectonic history of Japan. Many Japanese ore deposits have produced many different metals, and they contain almost all common and useful minerals, although many deposits are small in size. 

I offer a different and complementary perspective on units which accommodates developmental processes explicitly and which articulates the intimate relationship between units of hereditary transmission and developmental expression. I argue that a process perspective on the temporal dimension of the transition problem, focusing on the propagation of developmental capacities, is a helpful addition to the spatial and functional perspectives. Reproduction is the process that, in general, forms the basis for evolution at a level and also for evolutionary transition to new levels. Processes of inheritance and replication can be understood as special cases of reproduction. In order to formulate a view of how processes of development and hereditary propagation are intertwined in reproduction, let us consider development further. 

Perhaps the common characteristic of all contributions to this volume is the permanent concern about the intimate relationships between the structural and electronic properties. Indeed, the careful design of increasingly complex molecular and supramolecular architectures allows us now to anticipate many molecular and solid state properties, but the final solid state structures are always the results of many competing interactions. The resulting electronic properties of these radical assemblies, whether conductivity or magnetism, are always very sensitive to minute modifications of their solid state structures and one of the main difficulties through... 

The intimate relationship between double layer emersion and parameters fundamental to electrochemical interfaces is shown. The surface dipole layer (xs) of 80SS sat. KC1 electrolyte is measured as the difference in outer potentials of an emersed oxide-coated Au electrode and the electrolyte. The value of +0.050 V compares favorably with previous determinations of g. Emersion of Au is discussed in terms of UHV work function measurements and the relationship between emersed electrodes and absolute half-cell potentials. Results show that either the accepted work function value of Hg in N2 is off by 0.4 eV, or the dipole contribution to the double layer (perhaps the "jellium" surface dipole layer of noble metal electrodes) changes by 0.4 V between solution and UHV. 

I found Curt to be thoughtful and candid in his remarks. So much so that during the interview I realized a part of me was braced for hearing painful truths about living with a partner who has MCS, truths which might be unspoken or denied within the boundaries of an intimate relationship, including my own. What I found, however, was that his love and compassion for Elizabeth enabled me to hear his frustration and grief with empathy. 

The importance of water in foods begins with the hydrological cycle and concludes with the consumption of safe, wholesome, and plentiful foods. In between, water is a vital component in the various stages of food production and preservation. Water in the final food product, whether fresh or processed, profoundly influences the chemistry, microbiological safety, nutritional value, texture, appearance, and taste of the food. Because of this intimate relationship between water and food quality and safety, a more complete understanding of water and its properties, behavior, and influence, alone and in foods, is of prime importance. 

Many attempts have been made to deduce thermodynamics from statistical mechanics, and no one can doubt the intimate relationship or even the complete identity of the two sciences. Nevertheless, it has not hitherto been found possible to proceed by a single path unambiguously from simple statistical assumptions to the laws of thermodynamics. This we hope to have accomplished in this paper and the following. 

It is reasonable to assume the effect of plant roots and tops on the soil would be the same. However, this is not the case. Plant roots profoundly affect the chemical characteristics of soil. Because they are in intimate contact with the soil, roots are constantly extracting nutrients and water from the soil and exuding materials into it. The intimate relationship, which includes physical, microbiological, biochemical, bioorganic, and chemical interactions between roots and soil, is illustrated in Figure 4.3. 

Our preliminary work strongly suggests that there is an intimate relationship between the MALDI ion signals for surface-adsorbed proteins and the affinity of the surface for binding those proteins. Although this relationship appears well demonstrated in the examples above, numerous questions remain to be answered. 

The intimate relationship between NMR parameters such as chemical shifts and spin-spin coupling constants and molecular geometry is particularly evident for derivatives with rigid frameworks. Therefore, structural and conformational effects are treated first as a separate topic and then in conjunction with specific compounds. As data on hydroxylamines, oximes and hydroxamic acids are not as extensive as those for other types of systems containing nitrogen or oxygen, comparisons with their respective parameters or effects have also been included wherever they are considered relevant. 

Thus far I have been describing how use of psychiatric medications influences the way people present themselves during the construction of intimate relationships. As the... 

Guyton de Morveaus paper, Memoire sur le development des prin-cipes de la Nomenclature methodique, made emphatic the intimate relationship between the nomenclature and the concept of simple body ... 

A fundamental change occurred in the biochemistry of the ancestor that allowed ingested PAs to be detoxified, retained, and transported safely throughout the larval body. The acquisition of the PA-specihc monooxygenase may have been the critical evolutionary innovation for the Arctiinae that sealed their intimate relationship with PA-containing plants. This specific enzyme allows them simultaneously to detoxify the PAs and render them mobile. Once sequestered, PAs could deter predators. 

C. myrodora. PAs transferred from the male to the female queen butterfly find their way into the eggs in substantial quantities (Dussourd et al, 1989). This transfer is not an isolated example. Studies by Brown (1984) indicated the presence of PAs in the male reproductive tract of several ithomiine species, and Boppre (1984b) has documented a diversity of breakaway particles in several danaines. The intimate relationships between the insects, their PAs, courtship behavior, and defense are clearly the result of convergence on an effective method of antipredatory defense (Wink and von Nickisch-Rosenegk, 1997). 

Among the hydrogenated derivatives, we distinguish dihydro from the tetrahydro/hexahydro class, as the former bear an intimate relationship to their aromatic analogues. 

The purpose of this chapter is a detailed comparison of these systems and the elucidation of the transition from regular to irregular dynamics or from mode-specific to statistical behavior. The main focus will be the intimate relationship between the multidimensional PES on one hand and observables like dissociation rate and final-state distributions on the other. Another important question is the rigorous test of statistical methods for these systems, in comparison to quantum mechanical as well as classical calculations. The chapter is organized in the following way The three potential-energy surfaces and the quantum mechanical dynamics calculations are briefly described in Sections II and III, respectively. The results for HCO, DCO, HNO, and H02 are discussed in Sections IV-VII, and the overview ends with a short summary in Section VIII. 

I hope that you can now see the intimate relationship between surge in a centrifugal compressor and the amperage load on the motor driver used to drive the compressor. Now, let s see if I cannot prove that the Second Law of Thermodynamics is quite in harmony with our practical experience. 

As might reasonably be expected on the basis of the intimate relationships between glucose-6-phosphatase and phospholipids discussed above,... 

Despite the importance of hydrodemetallation reactions and their intimate relationship to HDS, HDN, and HDO, relatively little is understood of the underlying fundamentals. Only recently have model compounds been used to explore the intrinsic reactivity of metal-bearing compounds and the nature of the catalytic sites responsible for these reactions. This is in sharp contrast to the wealth of model compound information existing in the literature on HDS (Gates et al., 1979 Mitchell, 1980 Vrinat, 1983), HDN (Katzer and Sivasubramanian, 1979 Satterfield and Yang, 1984 Ho, 1988) and HDO (Furimsky, 1983 Satterfield and Yang, 1983). 

Haan C, Kreis S, Margue C, Behrmann I. 2006. JAKs and cytokine receptors - An intimate relationship. Biochem Pharmacol. 72 1538-1546. 

Sociologists have long recognized and commented upon the significance of such close and intimate relationships... 

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