Interfacial wear mechanism

The elements of such a system consist of the primary body, the counter body, the interfacial medium and surrounding medium. Wear is a result of the action of the collective stress on the structure respectively on the elements of the tribological system and manifests itself in energetic and material interactions between these elements. It is defined by the wear parameters. Basically all wear mechanisms can occur abrasion, adhesion, tribo-chemical reactions or wear caused by fatigue. In the case of the extrusion of ceramic bodies, corrosion must be considered as another harmful mechanism. When determining the elements of the tribosystem for the... 

Fig. 1 Schematic description of cohesive and interfacial wear processes from the two terms non interacting model of friction (from [96]). Bulk ploughing involves the dissipation of the frictional work within a volume of the order of the cube of the contact radius. Interfacial shear corresponds to the dissipation of the frictional energy in much thinner regions and at greater energy densities. Cohesive wear processes (cracking, tearing, microcutting...) are governed by the cohesive strength of the polymer. Mechanisms such as transfer film formation correspond to interfacial wear and do not readily correlate with accessible bulk failure properties...

Multiwalled carbon nanotubes (MWCNTs) were proven to also contribute to the increase in the wear resistance and to the reduction of the friction coefficient in modified BMI resins (Liu et al. 2007a), especially when MWCNTs are functionalized with carboxylic groups. This is because they induce a change in the main wear mechanism—from adhesive wear in neat resin to abrasive attrition—by changing the self-lubricating property of the worn surface, the dispersion of filler in the matrix, and the interfacial adhesion between filler particles and matrix. 

The benefits may arise indirectly through enhanced thermal conductivity and creep resistance or through a subtle modification of the wear mechanism. It is the latter that are of particular interest in the context of interfacial wear phenomenon. 

Wear. Ceramics generally exhibit excellent wear properties. Wear is deterrnined by a ceramic s friction and adhesion behavior, and occurs by two mechanisms adhesive wear and abrasive wear (43). Adhesive wear occurs when interfacial adhesion produces a localized Kj when the body on one side of the interface is moved relative to the other. If the strength of either of the materials is lower than the interfacial shear strength, fracture occurs. Lubricants (see Lubricants and lubrication) minimize adhesion between adj acent surfaces by providing an interlayer that shears easily. Abrasive wear occurs when one material is softer than the other. Particles originating in the harder material are introduced into the interface between the two materials and plow into and remove material from the softer material (52). Hard particles from extrinsic sources can also cause abrasive wear, and wear may occur in both of the materials depending on the hardness of the particle. 

The recovery of petroleum from sandstone and the release of kerogen from oil shale and tar sands both depend strongly on the microstmcture and surface properties of these porous media. The interfacial properties of complex liquid agents—mixtures of polymers and surfactants—are critical to viscosity control in tertiary oil recovery and to the comminution of minerals and coal. The corrosion and wear of mechanical parts are influenced by the composition and stmcture of metal surfaces, as well as by the interaction of lubricants with these surfaces. Microstmcture and surface properties are vitally important to both the performance of electrodes in electrochemical processes and the effectiveness of catalysts. Advances in synthetic chemistry are opening the door to the design of zeolites and layered compounds with tightly specified properties to provide the desired catalytic activity and separation selectivity. 

If one considers that wear damage also results in energy dissipation, this approach can tentatively be applied to wear. Accordingly, wear processes can be classified as cohesive or interfacial depending on the length scales associated with particles detachment mechanisms (Fig. 1). 

Wear is the process of physical loss of material. In sliding contacts this can arise from a number of processes in order of relative importance they are adhesion, abrasion, corrosion and contact fatigue. Wear occurs because of local mechanical failure of highly stressed interfacial zones and the mode of failure is influenced by environmental factors. 

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