Injection mold resin flow

Extrusion Resins. Extmsion of VDC—VC copolymers is the main fabrication technique for filaments, films, rods, and tubing or pipe, and involves the same concerns for thermal degradation, streamlined flow, and noncatalytic materials of constmction as described for injection-molding resins (84,122). The plastic leaves the extmsion die in a completely amorphous condition and is maintained in this state by quenching in a water bath to about 10°C, thereby inhibiting recrystallization. In this state, the plastic is soft, weak, and pHable. If it is allowed to remain at room temperature, it hardens gradually and recrystallizes partially at a slow rate with a random crystal arrangement. Heat treatment can be used to recrystallize at controlled rates. 

The brominated phosphate is an efficient flame retardant for polycarbonate resin. UL-94 ratings of V-0 with oxygen index values of greater than 40 are obtained. Polycarbonate resin containing brominated phosphate processes with greater ease than resin containing brominated polycarbonate as measured by injection molding spiral flow measurements. The heat distortion temperature is reduced... 

The three flame retardants are compared in Table VI. Brominated phosphate disperses readily in the resin presumably due to its high solubility in aromatics. Resin containing brominated polycarbonate is relatively difficult to process as measured by injection molding spiral flow measurements. 

Figure 12.7 Rheological data (ISO 11403-2) for a high-impact injection molding resin that has a volumetric flow rate (IS01133, 200°C/5.0kg) of 13...

Flow Properties - Melt Index values for five of the polyesters were determined as a function of both temperature and inherent viscosity. While it is difficult to compare the flow behavior of polymers of differing molecular weights, it appears that all of the compositions for which values could be obtained would be attractive candidates for injection molding resins at the proper molecular weight range. 

Applications such as thin-wall injection molded containers require processability for easier flow and faster cycle times, and impact strength for durability and crack resistance—especially at low temperatures for refrigerated and frozen food applications. Yet for typical HDPE injection molding resins, when the processing index is decreased for improved mold flow and extrudability, dart impact also decreases. 

The spiral test is used for classifying injection molding resins with respect to their melt flow behavior. By plying dimensional analysis to measured flow curves of thermoplastic resins a relationship was obtained to predict the flow length as a function of melt temperature, mold temperature, injection speed, injection pressure and spiral geometry. 

Suspension Polymers. Methacrylate suspension polymers are characterized by thek composition and particle-size distribution. Screen analysis is the most common method for determining particle size. Melt-flow characteristics under various conditions of heat and pressure are important for polymers intended for extmsion or injection molding appHcations. Suspension polymers prepared as ion-exchange resins are characterized by thek ion-exchange capacity, density (apparent and wet), solvent sweUing, moisture holding capacity, porosity, and salt-spHtting characteristics (105). 

Processing PC resins by extmsion or injection-molding methods requires melt temperatures of 290—320°C. High melt viscosity at low shear rates prevents mold flash and drool. At injection shear rates, apparent viscosities decrease, and easy melt flow allows manufacture of large, complex parts. 

Siloxane containing polyester, poly(alkylene oxide) and polystyrene type copolymers have been used to improve the heat resistance, lubricity and flow properties of epoxy resin powder coatings 43). Thermally stable polyester-polysiloxane segmented copolymers have been shown to improve the flow, antifriction properties and scratch resistance of acrylic based auto repair lacquers 408). Organohydroxy-terminated siloxanes are also effective internal mold release agents in polyurethane reaction injection molding processes 409). 

The injection-molding press was producing a part and runner system that had a mass of 2.15 kg. The mass was plasticated using a 120 mm diameter, 8L/D screw. The screw used for the process had a barrier melting section that extended to the end of the screw, as shown by the specifications in Table 11.9. That is, the screw did not have a metering channel. Instead, the last sections of the barrier section were required to produce the pressure that was needed to flow the resin through the nonreturn valve and into the front of the screw. The specific rotational flow rate for the screw for the IRPS resin was calculated at 9.3 kg/(h-rpm) based on the depth of the channel at the end of the transition section. The screw was built with an extremely low compression ratio and compression rate of 1.5 and 0.0013, respectively. For IRPS resins and other PS resins, screws with low compression ratios and compression rates tend to operate partially filled. The compression ratio and compression rate for the screw are preferred to be around 3.0 and 0.0035, respectively. The flight radii on the screw were extremely small at about 0.2 times the channel depth. For IRPS resin, the ratio of the radii to the channel depth should be about 1. 

The cure of thermoset resins involves the transformation of a liquid resin, first with an increase in viscosity to a gel state (rubber consistency), and finally to a hard solid. In chemical terms, the liquid is a mixture of molecules that reacts and successively forms a solid network polymer. In practice the resin is catalyzed and mixed before it is injected into the mold thus, the curing process will be initialized at this point. The resin cure must therefore proceed in such a way that the curing reaction is slow or inhibited in a time period that is dictated by the mold fill time plus a safety factor otherwise, the increase in viscosity will reduce the resin flow rate and prevent a successful mold fill. On completion of the mold filling the rate of cure should ideally accelerate and reach a complete cure in a short time period. There are limitations, however, on how fast the curing can proceed set by the resin itself, and by heat transfer rates to and from the composite part. 

---