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BROMINE CONTAINING

Brominated Additive Flame Retardants. Additive flame retardants are those that do not react in the appHcation designated. There are a few compounds that can be used as an additive in one appHcation and as a reactive in another. Tetrabromobisphenol A [79-94-7] (TBBPA) is the most notable example. Tables 5 and 6 Hst the properties of most commercially available bromine-containing additive flame retardants. [Pg.467]

Another approach to durable press—flame retardancy uses a combination of a cross-linking system, antimony(III) oxide, and a bromine-containing reactive additive, namely dibromoneopentyl glycol, to achieve dual properties (120,121). [Pg.490]

Bromine reacts with essentially all metals, except tantalum and niobium, although elevated temperatures are sometimes required, eg, soHd sodium does not react with dry bromine but sodium vapor reacts vigorously. Metals such as lead, magnesium, nickel, and silver react with bromine to form a surface coat of bromide that resists further attack. This protective coating allows lead and nickel to be used as linings in bromine containers. Metals tend to be corroded by bromine faster in the presence of moisture than without, probably because of the formation of hydrobromic and hypobromous acids. [Pg.280]

An important use of bromine compounds is in the production of flame retardants (qv). These are of the additive-type, which is physically blended into polymers, and the reactive-type, which chemically reacts during the formation of the polymer. Bromine compounds are also used in fire extinguishers. Brominated polymers are used in flame retardant appHcations and bromine-containing epoxy sealants are used in semiconductor devices (see... [Pg.289]

Odier bromine-containing dye intemiediates include 6-bromo-2,4-dinitroaniline [1817-73-8] C H BrN O, and 5,7-dibromoisatin [6374-91-0] CgH2Bi2N02. Bromodinitroaniline is used in making a2o dyes and dibromoisatin is used in making Alizarin Indigos B, 3R, and G. [Pg.298]

Flame Retardants. Bromine compounds make up an important segment of the market for flame retardants used in polymers. Additive flame retardants are added to polymers during processing reactive flame retardants react chemically to become part of the polymer chain itself. In addition to the compounds Hsted in Table 3, a number of proprietary mixtures and phosphoms—bromine-containing flame retardants are also sold (see Elame RETARDANTS, HALOGENATED, FLAAffi RETARDANTS). [Pg.298]

Pesticides. Bromine-containing pesticides are given in Table 4. [Pg.298]

Catalysts having improved poison resistance have been developed. Catalysts are available that can destroy chlorine-, fluorine-, or bromine-containing organic compounds (5). [Pg.508]

The self-extinguishing characteristics of the chlorine-containing resins are improved by incorporation of antimony oxide but this approach is not possible where translucent sheet is required. As an alternative to chlorine-based systems a number of bromine-containing resins have been prepared and, whilst claimed to be more effective, are not currently widely used. It is probably true to say that fire-retarding additives are used more commonly than polymers containing halogen groupings. [Pg.701]

A series of phosphorus- and bromine-containing FRs were synthesized and studied to understand their role, especially their combined effects. Thus, monocar-danyl phosphoric acid, its bromo derivatives and their formaldehyde condensates and crosslinked products [28,188] were prepared and their properties compared with analogous products made from phenol [28,189]. Table 14 gives the LOI values, char yields (Cy at 600°C), and thermal stability at 50% (T6o) decomposition. [Pg.429]

The conductivity of a number of bromine containing complexes with different quaternary ammonium cations was studied by Gerold (see Ref. 156]) with respect to the dependence on temperature and bromine... [Pg.184]

Oxidation of sulphoxides to sulphones may be brought about by the use of several different bromine-containing reagents which act as a source of electrophilic bromine. To date, these reagents have not received the same attention as their chlorine analogues. [Pg.981]

Initiator efficiency in terms of conversions and molecular weights were similar for model compounds and polymerizations. The influence of chlorine and bromine-containing counterions on polymerization was similar to that found in model study. [Pg.88]

In spite of the fact that biotechnology rather than chemical processing will probably provide the future greatly needed chirally pure compounds (ref. 1), we believe that simple chemical reactions starting from chiral natural compounds and proceeding under stereochemical control will eventually retain full importance. On the above grounds, we report on simple reactions which start from a-aminoacids, as an example of utilization of natural compounds, and move to related bromine containing compounds (Fig. 1). [Pg.160]

Thus, this first example of stereoselective radical reaction, initiated with the system based on Fe(CO)5, shows opportunities and prospects of using the metal complex initiators for obtaining the stereomerically pure adducts of bromine-containing compounds to vinyl monomers with chiral substituents. [Pg.192]

The phenol-contaminated sample was unique in yielding bromine containing none of the starting contaminant. Analysis of the bromine by FT-IR and INMR showed a complex mixture of brominated phenols and small amounts of other brominated hydrocarbons. The absence of phenol in the bromine product is not surprising, since phenol reacts with bromine at room temperature to make predominantly tribromophenol. [Pg.315]

INFLUENCE OF BROMINE-CONTAINING FIRE RETARDANTS ON THE PROCESSING AND PROPERTIES OF PLASTICS... [Pg.323]

Table 6 shows the flamability characteristics of an impact modified 2/1 polycarbonate/PET blend containing 6 % of the various flame retardants. The composition containing the brominated phosphate 60/4 is the only one which is V-0 by the UL-94 vertical burn test. At 10 % add-on, the all-bromine containing resin is V-1 and at 13 % add-on the all-phophorus containing resin is V-0. [Pg.353]

Study of the Thermal Behaviour of Bromine Containing Flame Retardants during Incineration... [Pg.364]

The other bromine atom comes from another bromine-containing molecule or ion. This is clearly not a problem in reactions with benzylic species since the benzene ring is not prone to such addition reactions. If the concentration is sufficiently low, there is a low probability that the proper species will be in the vicinity once the intermediate forms. The intermediate in either case reverts to the initial species and the allylic substitution competes successfully. If this is true, it should be possible to brominate an alkene in the allylic position without competition from addition, even in the absence of NBS or a similar compound, if a very low concentration of bromine is used and if the HBr is removed as it is formed so that it is not available to complete the addition step. This has indeed been demonstrated. ... [Pg.913]


See other pages where BROMINE CONTAINING is mentioned: [Pg.1908]    [Pg.314]    [Pg.486]    [Pg.397]    [Pg.85]    [Pg.298]    [Pg.298]    [Pg.511]    [Pg.452]    [Pg.148]    [Pg.482]    [Pg.794]    [Pg.436]    [Pg.9]    [Pg.969]    [Pg.981]    [Pg.189]    [Pg.181]    [Pg.181]    [Pg.194]    [Pg.335]    [Pg.400]    [Pg.121]    [Pg.194]    [Pg.435]    [Pg.480]   


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BROMINE CONTAINING COPOLYMER

BROMINE CONTAINING Subject

Barbiturates bromine-containing

Bromine-Containing Fire Retardants

Bromine-containing charge transfer

Bromine-containing chemicals

Bromine-containing compounds

Bromine-containing dyes

Bromine-containing flame retardants

Bromine-containing hypnotics

Bromine-containing substances

Chlorine and Bromine Containing Polyols

Chlorine and Bromine-Containing Compounds in a Mass Spectrum

Halogenated bromine-containing fire retardants

Reactions of the Bromine-containing Products

Ureides, bromine-containing

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