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Incomplete sampling

Contractors at Sites B, D, G, I, and J had incomplete sampling practices and as a result were not able to evaluate PPE levels based on monitoring data. Eor example, both contractors SSAHPs at Site I lacked provisions for monitoring site hazards such as metals, pesticides, herbicides, and semi-volatile organic compounds (SVOCs) that could not be evaluated with a PID. Since worker exposures to the range of hazards on site had not been characterized, PPE was not selected based on its performance relative to the nature and level of site hazards. [Pg.190]

Others have looked at the zone sampling problem. The theory of incomplete sampling of the first dimension was studied by Seeley (2002). Carr has also commented about the sampling (Stoll et al., 2006) that few users of 2DLC have sampled the first dimension adequately to minimize the 2D broadening effect from incomplete sampling. [Pg.26]

Seeley, J.V. (2002). Theoretical study of incomplete sampling of the first dimension in comprehensive two-dimensional chromatography. J. Chromgr. A 962, 21-27. [Pg.33]

Estimator a rule or method for estimating a parameter of the parent population, usually from an incomplete sample. [Pg.109]

Degradation Creatine and creatine phosphate spontaneously cyclize at a slow, but constant, rate to form creatinine, which is excreted in the urine. The amount of creatinine excreted is proportional to the total creatine phosphate content of the body, and thus can be used to estimate muscle mass. When muscle mass decreases for any reason (for example, from paralysis or muscular dystrophy), the creatinine content of the urine falls. In addition, any rise in blood creatinine is a sensitive indicator of kidney malfunction, because creatinine is normally rapidly removed from the blood and excreted. A typical adult male excretes about 15 mmol of creatinine per day. The constancy of this excretion is sometimes used to test the reliability of collected 24-hour urine samples—too little creatinine in the submitted sample may indicate an incomplete sample. [Pg.285]

The requirements for the collection of representative samples are documented in the SAP. If all of these requirements are met in the course of field implementation, the collected samples will be representative of the population of interest. The goal for sampling completeness will be also met. Deviations from the SAP requirements have a potential to degrade the DQIs of representativeness and completeness and, consequently, the usability of a data set. The most damaging errors that may take place during field implementation are the collection of unrepresentative samples incomplete sampling that produces data gaps and incomplete documentation that... [Pg.89]

The cone calorimeter,71 which is a dynamic flow-through fire test, can also be used to assess smoke obscuration. The rankings tend to be quite different from those found with the static smoke chamber and are much more realistic. Several empirical parameters have been proposed to make this compensation for incomplete sample consumption, including one called the smoke factor (SmkFct), determined in small-scale RHR calorimeters.188 It combines the two aspects mentioned earlier the light obscuration (as the total smoke released) and the peak RHR. [Pg.649]

Only increasing understanding of complexity, dynamic range, incomplete sampling, false positive matches, and integration of diverse datasets for plasma and serum proteins will lay the foundation for validation of novel in vitro diagnostics in cancer [123],... [Pg.128]

It is difficult to draw many conclusions from this work, given the incomplete sampling of the water configurations. However, it does appear that microsolvation does decrease the range of activation barriers with increased a-branching. When four water molecules are included in the cluster, the relative activation barriers for reaction with methyl, ethyl, o-propyl, and tert-butyl chlorides are 0.0,2.5,6.7, and 7.3, respectively. This computed compression of the activation barrier range (especially relative to that observed in the gas phase) is not as great as what is observed in experiment (see Table 6.6), but the trend is correct. Furthermore, PCM alone does... [Pg.388]

A summary of some of the polymer-derived SiCN fibers is presented in Table 1. This table includes the polymer precursor systems for these fibers, the compositional data, and the developing companies. Reliable elemental analyses of these fibers are often diflScult to obtain because of incomplete sample combustion. In addition, many of these fiber compositions are being changed as their development proceeds. [Pg.598]

In order to demonstrate the size effect, Burnham [26] has made a series of MD calculations with different lattice-cells, having 64, 128, 256 and 512 water molecules at 100 K. The potential function used was again TIP4P. As one can see from Fig. 6, the size effect is quite dramatic. The 64 and 128 water cells give a DOS with highly structured noise. In more complex systems, some of these features could be mistaken for real peaks. Indeed, in the case of ice the noise at 28 meV was often believed to be one of the two peaks observed in the INS spectrum. This incomplete sampling of the BZ is also demonstrated LD simulation in Fig. 3. [Pg.492]

A second issue is that the integral equations do not account explicitly for the stochastic character of experimental data. This requires solution of the Kramers-Kronig relations in an expectation sense, as discussed in the following section. The methods used to address the incomplete sampled frequency range will be described in a subsequent section. [Pg.439]

The filtered backprojection can be applied to 3D image reconstruction with some manipulations. The 3D data sinograms are considered to consist of a set of 2D parallel projections, and the FBP is applied to these projections by the Fourier method. The iteration methods also can be generally applied to the 3D data. However, the complexity, large volume, and incomplete sampling of the data due to the finite axial length of the scanner are some of the factors that limit the use of the FBP and iterative methods directly in 3D reconstruction. To circumvent these difficulties, a modified method of handling 3D data is commonly used, which is described below. [Pg.82]

In the case of column chromatographic techniques, the separated " Tc impurities are detected indirectly, after separation, accepting incomplete sample recovery. Some components of a Tc pharmaceutical remain on the column. In fact, reduced, hydro-lized " Tc activity is commonly retained on the column. [Pg.136]

The results of in-vitro XRF and AAS investigations show a systematic difference which resulted from incomplete sample preparation in the case of AAS measurements (Fig. 4). It is known from literature that classical sample preparation with HNO3 or H2SO4/H2O2 does not lead to a total breakdown of arsenic compounds. The recorded systematical difference of 20% for the results of AAS in comparison to in-vitro XRF can easily be adapted to the complementary measuring technique because of the linearity over several magnitudes. [Pg.222]

The in-situ XRF investigations allow a rapid screening on arsenic contaminations in the field and thus a dedicated sampling from the resulting hotspots. The comparison of XRF and complementary AAS data showed a general difference resulting from incomplete sample preparation required for AAS investigations. [Pg.238]

Lu, N., Adhikari, J., Kofke, D.A. Variational formula for the free energy based on incomplete sampling in a molecular simulation, Phys. Rev. E 2003, 68, 026122. [Pg.53]

Finally, the calculated free energy should be compared to available experimental data. It is important to note that poor agreement with experiment does not necessarily mean that the simulation was poor. Reproduction of experimentally determined free energies has not been used as a criterion in the design of most force fields. It has been shown that the quality of a particular force field cannot be determined without considering the effects of incomplete sampling. [Pg.120]

Homogenization in water and further filtration or centrifugation Inorganic analytes and pesticides (dithiocarbamates, glyphosate, and metabolites) Soil, sediment, and particulate matter and biological material Incomplete sample dissolution... [Pg.383]


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See also in sourсe #XX -- [ Pg.100 ]




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