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Impurity problems extended impurities

C. The Recursion Method for the Localized and Extended Impurity Problem ... [Pg.133]

It may seem that an extended impurity problem could require an impossibly large cluster size. This is not true, however, basically because of the physical implications of translational symmetry away from the impurity region. In fact, the asymptotic limits of the continued fraction parameters and the cut in the real energy axis are determined by the perfect crystal only this allows a guideline for appropriate extrapolation of the recursion codffidents. [Pg.169]

If the critical impurities are known, then only a selected list of elements need to be examined, with some improvement in the cost effectiveness of the analysis. However, the list of elements to be included in the qualification analysis is often historical and related to the limitations of the analytical methods previously used for qualification rather than for technological reasons related to the end use of the metal. As a result, problems in application can arise for no obvious reason. The time and cost of extending the impurity list for GDMS analysis to include essentially all elements is minimal, considering the additional information gained. [Pg.621]

In principle it is possible to extend the method to produce block copolymers in which each of the blocks is monodisperse but the problems of avoiding impurities become formidable. Nevertheless, narrow size distributions, if not monodisperse ones, are achievable. [Pg.36]

If the p labels refer to lattice sites j, this matrix reduces to 6(k) in the KKR matrix M(k) and Eq. (15) can be shown to reduce to Eq. (14). The evaluation of is hindered by the free-electron poles in the b matrices. This has formed a barrier for electronic structure calculations of interstitial impurities, but in some cases this problem was bypassed by using an extended lattice in which interstitial atoms occupy a lattice site. For the calculation of Dingle temperatures [1.3] and interstitial electromigration [14] the accuracy was just sufficient. Recently this accuracy problem has been solved [15, 16]. [Pg.470]

With the progress of electrolysis the concentration of aluminum (and of other base impurities) increases as a result of this the contamination of the cathode deposit also increases. A stage may be reached when the contamination exceeds acceptable limits, thereby calling for a premature termination of electrolysis. It is for this reason that it is desirable to purify and recycle the electrolyte wherever possible so that electrorefining could be conducted for extended periods, without having to contend with the problem of excessive contamination. [Pg.716]

Since a relatively small number of analytes of interest have native fluorescent properties, derivatization reactions are frequently employed to enable this detection technique to be extended to a broader range of compounds. This is an excellent means of increasing the detectability for a whole range of molecules, but it is important to realize that there are certain limitations. First, it is difficult to obtain quantitative yields at low analyte concentrations. This implies that in some cases, the obtainable detection limit are not limited by the detector sensitivity, but instead by low yields in the derivatization reaction. Furthermore, to shift the equilibrium toward the product side at low analyte concentrations, as much as 104 times excess of fluorescent label may be necessary. Tow concentrations of impurities in the label can be present at levels greater than the analytes of interest and as a result, numerous interfering peaks in the chromatograms may be observed. These problems are discussed in detail in Ref. 181. [Pg.159]

The Schottky defect population in the electrolyte is rather too low for practical purposes. To overcome this problem the Lil is sometimes doped with Cal2. The extra I- ions extend the Lil structure, and the Ca2+ ions form substitutional impurity defects on sites normally reserved for Li+ ions. The consequence of this is that each Ca2+ ion in Lil will form one cation vacancy over and above those present due to Schottky defects in order to maintain charge neutrality. This can be written... [Pg.55]

Polyethylene has been studied spectroscopically in greater detail than any other polymer. This is primarily a result of its (supposedly) simple structure and the hope that its simple spectrum could be understood in detail. Yet as simple as this structure and spectrum are, a satisfactory analysis had not been made until relatively recently, and even then significant problems of interpretation still remained. The main reason for this is that this polymer in fact generally contains structures other than the simple planar zig-zag implied by (CH2CH2) there are not only impurities of various kinds that differ chemically from the above, but the polymer always contains some amorphous material. In the latter portion of the material the chain no longer assumes an extended planar zig-zag conformation, and as we have noted earlier, such ro-tationally isomeric forms of a molecule usually have different spectra. Furthermore, the molecule has a center of symmetry, which as we have seen implies that some modes will be infrared inactive but Raman active, so that until Raman spectra became available recently it was difficult to be certain of the interpretation of some aspects of the spectrum. As a result of this work, and of detailed studies on the spectra of n-paraffins, it now seems possible to present a quite detailed assignment of bands in the vibrational spectrum of polyethylene. [Pg.103]

The studies reviewed here are part of a continuing effort (4-10) to identify those properties of bimetallic systems which can be related to their superior catalytic properties. A pivotal question to be addressed of bimetallic systems (and of surface impurities in general) is the relative importance of ensemble (steric or local) versus electronic (nonlocal or extended) effects in the modification of catalytic properties. In gathering information to address this question it has been advantageous to simplify the problem by utilizing models of a bimetallic catalyst such as the deposition of metals on single- crystal substrates in the clean environment familiar to surface science. [Pg.196]

One of the most difficult problems for ab initio quantum chemistry is to determine the potential energy function for a chemical reaction on a metal surface. Why is this so First of all, the metal substrate is strongly delocalized. This means that the system cannot be modeled [1] by considering just a small or medium-sized cluster of metal atoms. On the other hand, the band structure techniques that would simplify calculations for a bare metal surface cannot be directly applied because the translational symmetry is broken by the presence of the reactants. As a result one has the difficulty of dealing with extended interactions without the benefit of simplifications due to symmetry. Many problems involving surfaces, interfaces, impurities, or defects in solid state materials fall under this broad rubric along with various solution phenomena as well. [Pg.148]


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See also in sourсe #XX -- [ Pg.169 ]




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