Hollow-fiber separator feed pressure

Hollow-fiber separator comp os it ion-dependent permeab ility feed composition feed pressure fiber dimensions multistage pressure drop Horizontal decanters HTU... 

Show how the water flux and salt rejection would change with upstream pressure for a perfect cellulose acetate asymmetric membrane and a feed with an osmotic pressure of 20 atm. Use the dilfusivity and solubility values for NaCL (fl) Calculate the internal pressure drop for an oxygen-nitrogen hollow-fiber separator that has 600 pm outside diameter and 400 pm inside diameter fibers 1.0 m long. When = 751by/in. abs and = 15Iby/in. abs, the permeate flux is... 

Fig. 23. Two types of hollow-fiber modules used for gas separation, reverse osmosis, and ultrafiltration applications, (a) Shell-side feed modules are generally used for high pressure appHcations up to - 7 MPa (1000 psig). Fouling on the feed side of the membrane can be a problem with this design, and pretreatment of the feed stream to remove particulates is required, (b) Bore-side feed modules are generally used for medium pressure feed streams up to - 1 MPa (150 psig), where good flow control to minimise fouling and concentration polarization on the feed side of the membrane is desired.

Hollow-fiber membranes may be run with shell-side or tube-side feed, cocurrent, countercurrent or in the case of shell-side feed and two end permeate collection, co- and countercurrent. Not shown is the scheme for feed inside the fiber, common practice in lower-pressure separations such as air. 

Let us consider the following case of removing an inorganic salt from an aqueous stream. It is desired to reduce the salt content of a 26 m /hr water stream (Qf) whose feed concentration, Cp, of 0.035 kmol/m (approximately 2,000 ppm). The feed osmotic pressure (rrp) is 1.57 atm. A 30 atm (Pp) booster pump is used to pressurize the feed. Sixteen hollow fiber modules are to be employed for separation. The modules are configured in parallel with the feed distributed equally among the units. The following properties are available for the HFRO modules ... 

We have been studying the novel process for CO2 separation named membrane/absorption hybrid method. The advantages of this process are that high gas permeance and selectivity were obtained. The concept of this process is shown in Fig. 1. Both feed gas and absorbent solution are supplied to the inside of hollow fibers. While Ae liquid flows upward inside the hollow fibers, absorbent solution absorbs CO2 selectively and it becomes a rich solution. Most of rich solution permeates the membrane to the permeate side maintained at reduced pressure, where it liberated CO2 to become a lean solution. Compared to a conventional gas absorption... 

Whereas the liquid-solid filtration processes described so far can separate particles down to a size of around 10 xm, for smaller particles that need to be separated, a porous polymer membrane can be used. This process, known as microfiltration, retains particles down to a size of around 0.05. im. A pressure difference across the membrane of 0.5 to 4 bar is used. The two most common practical arrangements are spiral wound and hollow fiber. In the spiral wound arrangement, flat membrane sheets separated by spacers for the flow of feed and filtrate are wound into a spiral and inserted in a pressure vessel. Hollow... 

The one-pass system consists of a feed tank, filter, pump, and membrane system (Fig. 6). The feed tank contains whiskey at approximately 100° proof. It is filtered through a cellulose filter and then pumped into the membrane system where the separation takes place. Dupont B-10 A ram id hollow fiber membranes are used in series or parallel and are able to withstand the high pressures, 689—1034 kPa (6.8—10 atm), necessary to achieve separation. 

The types of hollow fiber membranes in production are illustrated in Figure 3.32. Fibers of 50- to 200-p.m diameter are usually called hollow fine fibers. Such fibers can withstand very high hydrostatic pressures applied from the outside, so they are used in reverse osmosis or high-pressure gas separation applications in which the applied pressure can be 1000 psig or more. The feed fluid is applied to the outside (shell side) of the fibers, and the permeate is removed down the fiber bore. When the fiber diameter is greater than 200-500 xm, the feed fluid is commonly applied to the inside bore of the fiber, and the permeate is removed from the outer shell. This technique is used for low-pressure gas separations and for applications such as hemodialysis or ultrafiltration. Fibers with a diameter greater than 500 xm are called capillary fibers. 

Figure 11.26 Performance of a 37 m2 hollow fiber silver-nitrate-impregnated facilitated transport membrane for the separation of propylene/propane mixtures. The feed pressure was 5-13 atm the permeate was a hexane liquid sweep stream. The vertical dotted lines show when the membrane was regenerated with fresh silver nitrate solution [27]. Reprinted with permission from R.D. Hughes, J.A. Mahoney and E.F. Steigelmann, Olefin Separation by Facilitated Transport Membranes, in Recent Developments in Separation Science, N.N. Li and J.M. Calo (eds) (1986). Copyright CRC Press, Boca Raton, FL...

The hollow-fiber module is often used when the feed stream is relatively clean, such as in gas separation and pervaporation. It has also been used in the case of seawater desalination, but pretreatment is needed. The module construction given in Fig. 15 A is a typical RO module, where a central pipe is used to uniformly distribute the feed solution throughout the module. This is to avoid the problem of channelling in outside-in model, which means the feed has a tendency to flow along a fixed path, thus reducing the effective membrane surface area. In gas separation, as shown in Fig. 15B, the outside-in model is used to avoid high pressure losses inside the fiber and to attain a high membrane area (13). 

With respect to gas separation hollow fiber modules, the chemical compatibility and the mechanical stability of the fibers and potting are paramount. High pressure modules use shell-side feed while low pressure modules... 

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