High pressure volumetric lines

Unusual are set-ups combining Tian-Calvet calorimetry and high pressure volumetric lines. One of the few examples is reported in the work of Anikina and Verbetsky... 

For sulfated ash digestions, either 250-ral Vycor beakers or dishes may be used (Fisher Scientific). The microwave digestion vessels used were high pressure. Teflon lined, 45-mL Model 4782 bombs that are available from Pair Instrument Company, Moline, Illinois, USA. The polypropylene volumetric flasks used to dilute digested samples to volume are available from Fisher Scientific. 

Thermodynamic consistency tests for binary vapor-liquid equilibria at low pressures have been described by many authors a good discussion is given in the monograph by Van Ness (VI). Extension of these methods to isothermal high-pressure equilibria presents two difficulties first, it is necessary to have experimental data for the density of the liquid mixture along the saturation line, and second, since the ideal gas law is not valid, it is necessary to calculate vapor-phase fugacity coefficients either from volumetric data for... 

Figure 15 gives a diagrammatic representation of a volumetric line which is used in connection with a high-temperature Calvet microcalorimeter 67). Other volumetric lines which have been described present the same general features (15, 68). In the case of corrosive gases or vapors, metallic systems may be used 69). In all cases, a sampling system (A in Fig. 15) permits the introduction of a small quantity of gas (or vapor) in a calibrated part of the volumetric line (between stopcocks Ri and Ro in Fig. 15) where its pressure Pi is measured (by means of the McLeod gage B in Fig. 15). The gas is then allowed to contact the adsorbent placed in the calorimeter cell C (by opening stopcock Ro in Fig. 15). The heat evolution is recorded and when it has come to completion, the final equi-...

A major factor in fluidized bed behavior is the interaction between the gas flow from individual orifices and the particle and gas mixture within the bed. The jet penetration and the subsequent bubble formation have an important influence upon solids and gas mixing and, ultimately, upon the usefulness of the bed for reactor purposes. While flow visualization data are available at ambient pressures and temperatures, the natures of jet penetration and bubble development at high pressures and temperatures are not easily measured. Typical data on bubble size and bubble velocity at ambient conditions are shown, represented by the small size symbols, in Figure 2. It is well known that bubble volume can be correlated as a function of gas volumetric flow rate ( ) and that bubble velocity is related to the size of the bubble radius ( ). Such semi-empirical correlations are indicated as solid lines in that figure. 

Barolo et al. (1998) developed a mathematical model of a pilot-plant MVC column. The model was validated using experimental data on a highly non-ideal mixture (ethanol-water). The pilot plant and some of the operating constraints are described in Table 4.13. The column is equipped with a steam-heated thermosiphon reboiler, and a water-cooled total condenser (with subcooling of the condensate). Electropneumatic valves are installed in the process and steam lines. All flows are measured on a volumetric basis the steam flow measurement is pressure- and temperature-compensated, so that a mass flow measurement is available indirectly. Temperature measurements from several trays along the column are also available. The plant is interfaced to a personal computer, which performs data acquisition and logging, control routine calculation, and direct valve manipulation. 

A high volumeteric air flow at a low linear velocity is desired. A high volumetric flow gives the parison a minimum time to cool before coming in contact with the mold, and provides a more uniform rate of expansion. A low linear velocity is desirable to prevent a venturi effect (see above). Volumetric flow is controlled by the line pressure and the orifice diameter. Linear velocity is controlled by flow control valves close to the orifice. 

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