High-flux nuclear reactors

The straightforward way to obtain light actinides is by neutron irradiation of elements of lower atomic number. For example the production of Pa has been produced by the transmutation of Th with neutron produced in a high-flux nuclear reactor. 

The first transuranium elements, neptunium and plutonium, were obtained in tracer amounts from bombardments of uranium by McMillan and Abelson and by Seaborg, McMillan, Kennedy, and Wahl, respectively, in 1940. Both elements are obtained in substantial quantities from the uranium fuel elements of nuclear reactors. Only plutonium is normally recovered and is used as a nuclear fuel since, like 235U, it undergoes fission its nuclear properties apparently preclude its use in hydrogen bombs. Certain isotopes of the heavier elements are made by successive neutron capture in 239Pu in high-flux nuclear reactors (> 1015 neutrons cm-2 sec- ). Others are made by the action of accelerated heavy ions of B, C, N, O or Ne on Pu, Am or Cm. 

Cf (bred in high flux nuclear reactors) by irradiating them with beams of neutron-rich light ions of or The idea was to start with a target close in mass to the final nucleus and use... 

Requires dedicated processing facility Requires high flux nuclear reactor... 

Actinium and protactinium are decay products of the naturally occurring uranium isotope U and are present in uranium minerals in such low concentration that recovery from natural sources is a very difficult and unrewaidii task. By comparison, it is relatively straightforward to obtain actinium, protactinium, and most of the remaining transuranium elements by neutron irradiation of elements of lower atomic number in nuclear reactors [2-4]. Thus, actinium has been produced in multigram quantities by the transmutation of radium with neutrons produced in a high-flux nuclear reactor ... 

Uranium-235 Enrichment. The enrichment of uranium is expressed as the weight percent of in uranium. For natural uranium the enrichment level is 0.72%. Many appHcations of uranium requite enrichment levels above 0.72%, such as nuclear reactor fuel (56,57). Normally for lightwater nuclear reactors (LWR), the 0.72% natural abundance of is enriched to 2—5% (9,58). There are special cases such as materials-testing reactors, high flux isotope reactors, compact naval reactors, or nuclear weapons where enrichment of 96—97% is used. 

The very first nuclear reactor built, where the main objective was to perform condensed matter research, was the High Flux Beam Reactor (HFBR) at Brookhaven National Laboratory, Upton, NY. The first self-sustaining chain reaction at the HFBR took place on Halloween, 1965. For over 30 years, the HFBR was one of the premier beam reactors in the world, matched only by the ILL reactor in Grenoble, France. These reactor-based sources have been a continuous and reliable source of thermal neutrons for research in a wide range of different scientific fields from physics, chemistry, materials science, and biology to engineering and isotope emichment. The instrumentation that is in place at these sources has seen steady improvement from the days when Nobel laureates, Brockhouse and Shull, performed their pioneering work at these facilities. 

Reformer tube heating with a high-temperature nuclear reactor is performed with helium, typically at 950 °C, as the heat source. The aim of reaching a heat flux density similar to that of the conventional method can be achieved by employing a helium-heated counterflow heat exchanger (see Fig. 2-11). Helium under pressure shows excellent heat transfer properties. Furthermore, precautions must be taken to minimize the effects of asymmetry or hot gas streaks in the helium flow as well as a non-uniform process gas flow. The materials of a helium-heated steam reformer should be selected such that the... 

COOK, D.H., et al., Achieving increased spent fuel storage capacity at the High Flux Isotope Reactor (HFIR) , Phoc. Topical Mtg on DOE Spent Nuclear Fuel — Challenges and Initiatives, Salt Lake City, 1994, USDOE, Washington, DC, (1994) 163-169. 

Figure 21.8 shows the High Flux Isotope Reactor at Oak Ridge National Laboratory, where technicians produce transuranium elements by bombarding plutonium-239 with neutrons. Neutrons are produced by nuclear fission, a process discussed in Section 21.7. 

In 1934, scientists discovered that when they bombarded natural bismuth (209Bi) with neutrons, 210Bi, the parent of polonium, was obtained. Milligram amounts of polonium may now be prepared this way, by using the high neutron fluxes of nuclear reactors. 

Approximately 5% of the U.S. consumption of is in agriculture. Boron is a necessary trace nutrient for plants and is added in small quantities to a number of fertilizers. Borates are also used in crop sprays for fast rehef of boron deficiency. Borates, when apphed at relatively high concentration, act as nonselective herbicides. Small quantities of borates are used in the manufacture of alloys and refractories (qv). Molten borates readily dissolve other metal oxides usage as a flux in metallurgy is an important apphcation. Other important small volume apphcations for borates are in fire retardants for both plastics and ceUulosic materials, in hydrocarbon fuels for fungus control, and in automotive antifreeze for corrosion control (see Corrosion and corrosion inhibitors). Borates are used as neutron absorbers in nuclear reactors. Several borates, which are registered with the Environmental Protection Agency (EPA) can be used for insecticidal purposes, eg, TIM-BOR. 

---