Hexyl formaldehyde

Nitroethane and formaldehyde are first reacted to give 2-methyl-2-nitro-1,3-propanediol. This is reacted with 2-ethylhexylamine and formaldehyde to give 5-nitro-1,3-bis(2-ethyl-hexyl)-5-methyl-hexahydropyrimidine. 

Photolytic. Major products reported from the photooxidation of 2,3-dimethylbutane with nitrogen oxides are carbon monoxide and acetone. Minor products included formaldehyde, acetaldehyde and peroxyacyl nitrates (Altshuller, 1983). Synthetic air containing gaseous nitrous acid and exposed to artificial sunlight (A. = 300-450 nm) photooxidized 2,3-dimethylbutane into acetone, hexyl nitrate, peroxyacetal nitrate, and a nitro aromatic compound tentatively identified as a propyl nitrate (Cox et al., 1980). 

Other li acetylides Li-C=C-R with R = hexyl [21] or benzylether dendrons [22, 23] (up to the fourth generation) have also been attached to (Figure 3.3), and various different electrophiles have been used to complete the reaction with the intermediate li-fuUeride (Scheme 3.2 and Figure 3.3). Besides the protonation, alkyl-, benzyl-, cycloheptatrienyl-, benzoyl- or vinylether-derivatives or formaldehyde and dichloro-acetylene were used as electrophiles [12,20]. Most of these electrophiles are attached to the anion in the expected C-2 position. The 1,4-adducts are available by quenching the anion with the tropylium cation or benzoyl chloride [12]. The fuUerene anion can be stabilized by introduction of benzylether dendrons. The lifetimes of the anions change with the size of the dendrons [22]. 

Ether, ethyl vinyl. See Ethylvinylether Ether, hexyl methyl. See Methyl hexyl ether Ether hydrochloric. See Ethyl chloride Etherified acrylated melamine-formaldehyde resin. See Melamine-formaldehyde resin, etherified acrylated... 

Plastisan B. See Melamine cyanurate Plastistab 2900. See Epoxy resin Plastoflex 2307. See Epoxidized soybean oil Plastolein 9048. See Dibutyl azelate Plastolein 9051. See Di-n-hexyl azelate Plastolein 9058. See Di octyl azelate Plastolein 9232. See Epoxidized soybean oil Plastolein 9404. See PEG-3 dipelargonate Plastopal ATB, AWB, Plastopal BTA, BTB, BTI, BTM, Plastopal CB, CBX, HVB, Plastopal FIB, FA, Plastopal . See Urea-formaldehyde resin... 

Hexyl decanolc acid Hydrogenated tallowtrimonlum chloride Hydroxypropyl-o-cyclodextrin Hydroxypropyl-P-cyclodextrin Hydroxypropyl-y-cyclodextrin 12-Hydroxystearyl alcohol ,Isobutyl oleate lsocyanatopropyltriethoxysilane ,lsononyl stearate Isopropyl alcohol Isostearyl alcohol Lauryl alcohol Melamine-formaldehyde resin Methacrylatochromic chloride 2-Methoxy-5-nitroaniline Methyl methacrylate Methyl palmitate Mineral oil Natural rubber Octoxynol-70 Octyl acrylate 2-Octyl dodecanoic acid Octyl laurate Oleamine Oleth-5 phosphate Papain PEG-180 PEG-3 dimethyl ether PEG-8 ditallate PEG-12 ditallate PEG-14 laurate PEG-14 oleate PEG-5 stearate PEI-15 PEI-30... 

In the second series of experiments, the products from the photo-oxidation of diethyl ether, carried out in a Teflon bag reactor at ppm and ppb levels, have been determined by withdrawing vapour samples and monitoring by gas chromatography, HPLC and by chemiluminescence analysis. The major reaction products which have been measured are ethyl formate, ethyl acetate, acetaldehyde, formaldehyde, PAN, methyl nitrate and ethyl nitrate. The products observed arise from the decomposition reactions of the 1-ethoxyethoxy radical and from its reaction with oxygen. The data enable the establishment of a quantitative mechanism for the photo-oxidative reaction. In addition the rate of conversion of NO to NO2, determined by chemiluminescence analysis, shows that for each molecule of ether reacted only one molecule of NO is converted to NO2. In further end-product analyses experiments, the OH radical initiated photo-oxidation of n-hexane or the photolyses of 2- or 3-hexyl nitrites were studied to examine the... 

The primary products which were quantified include 3-hexyl nitrate, 2-hexyl nitrate, n-butyl nitrate, 3-hexanone, 2-hexanone, formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde and 5-hydroxy-2-hexanone. 2,5-hexanedione was quantified but is thought to be a secondary product, and 5-nitrooxy-2-hexanol was detected but reliable quantification was not possible. 

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