Hanging mercury dropping electrode

Mercury electrodes (a) hanging mercury drop electrode (b) dropping mercury electrode (c) static mercury drop electrode. 

Potential-excitation signal and voltammogram for anodic stripping voltammetry at a hanging mercury drop electrode. 

Faraday s law (p. 496) galvanostat (p. 464) glass electrode (p. 477) hanging mercury drop electrode (p. 509) hydrodynamic voltammetry (p. 513) indicator electrode (p. 462) ionophore (p. 482) ion-selective electrode (p. 475) liquid-based ion-selective electrode (p. 482) liquid junction potential (p. 470) mass transport (p. 511) mediator (p. 500) membrane potential (p. 475) migration (p. 512) nonfaradaic current (p. 512)... 

Electrodes. The Hanging Mercury Drop Electrode is traditionally associated with the technique of stripping voltammetry and its capabilities were investigated by Kemula and Kublik.51 In view of the importance of drop size it is essential to be able to set up exactly reproducible drops, and this can be done as explained in Section 16.8 for the S.M.D.E. 

DME = dropping mercury electrode HMDE = hanging mercury drop electrode MFE = mercury film... 

The mercury film electrode has a higher surface-to-volume ratio than the hanging mercury drop electrode and consequently offers a more efficient preconcentration and higher sensitivity (equations 3-22 through 3-25). hi addition, the total exhaustion of thin mercury films results in sharper peaks and hence unproved peak resolution in multicomponent analysis (Figure 3-14). 

There are several types of mercury electrodes. Of these, the dropping mercury electrode (DME), the hanging mercury drop electrode (HMDE), and mercury film electrode (MFE) are the most frequently used. 

The properties of anodic layers of HgS formed on mercury in sulfide solutions have been investigated in comparison with anodic sulfide layers of cadmium and bismuth. Also, the electrochemistry of mercury electrodes in aqueous selenite solutions has been studied (see Sect. 3.2.1). The problem with the presence of several cathodic stripping peaks for HgSe in acidic Se(IV) solutions has been addressed using various voltammetric techniques at a hanging-mercury-drop electrode [119]. 

Fig, 16. Anodic stripping voltammogram for at the hanging mercury drop electrode. (Reprinted with permission from W. R. Heineman, in Water Quality Measurement The Modem Analytical Techniques , (H. B. Mark, Jr. and J. S. Mattson, eds.) Marcel Dekker New York, 1981)... 

HMDE Hanging mercury dropping electrode mass spectrometry... 

The electrodes usually consist of mercury or deposited mercury or occasionally of inert solid material further, they are mainly of a stationary type (in the stripping step as the crucial analytical measurement, but not in the concentration step, where often the solution is stirred or the electrode is rotated). Considering the mercury, only exceptionally has a sessile mercury drop electrode (SMDE)91 or a slowly growing DME(drop time 18 min and phase-selective recording of stripping curve)92 been applied. Most popular are the hanging mercury drop electrode (HMDE) and the mercury film or thin-film electrode (MFE or MTFE). 

Figure 12. Current-potential curves for Ni(II)-cyclam (1 mM) in an aqueous 0.1 M KC104 solution (pH 4.5) under N2 (a) or C02 (b) at a hanging mercury drop electrode.135 Scan rate 0.1 V/s.

J.M. Sevilla, T. Pineda, A.J. Roman, R. Madueno, and M. Blazquez, The direct electrochemistry of cytochrome c at a hanging mercury drop electrode modified with 6-mercaptopurine. J. Electroanal. Chem. 451, 89-93 (1998). 

Acebal et al. [401] discussed the quantitative behaviour of lead (and copper) when voltammetric determinations are done at mercury film electrodes and hanging mercury drop electrodes. The samples were collected in polyethylene bottles and, generally, were not acidified immediately after collection. This might place some doubt on the results reported. 

Van den Berg [510] carried out direct determinations of molybdenum in seawater by adsorption voltammetry. The method is based on complex formation of molybdenum (VI) with 8-hydroxyquinoline (oxine) on a hanging mercury drop electrode. The reduction current of adsorbed complexions was measured by differential pulse adsorption voltammetry. The effects of variation of pH and oxine concentration and of the adsorption potential were examined. The method was accurate up to 300 nmol/1. The detection limit was 0.1 nmol/1. 

Donat and Bruland [217] determined low levels of nickel and cobalt in seawater by a voltammetric technique, and the nioxime complexes of the two elements were concentrated on a hanging mercury drop electrode. The current resulting from the reduction of Co (II) and Ni (II) was measured by differential pulse cathodic stripping voltammetry. Detection limits are 6 pM (cobalt) and 0.45 nM (nickel). 

Platinum was determined in seawater by adsorptive cathodic stripping voltammetry in a method described by Van den Berg and Jacinto [531]. The formazone complex is formed with formaldehyde, hydrazine, and sulfuric acid in the seawater sample. The complex is adsorbed for 20 minutes at -0.925 V on the hanging mercury drop electrode. The detection limit is 0.04 pM platinum. 

Van den Berg and Huang [292] determined uranium (VI) in seawater by cathodic stripping voltammetry at pH 6.8 of uranium (Vl)-catechol ions. A hanging mercury drop electrode was used. The detection limit was 0.3 nmol/1 after... 

Cyclohexane-1,2-dione dioxime (nioxime) complexes of cobalt (II) and nickel (II) were concentrated from 10 ml seawater samples onto a hanging mercury drop electrode by controlled adsorption. Cobalt (II) and nickel (II) reduction currents were measured by differential pulse cathodic stripping voltammetry. Detection limits for cobalt and nickel were 6 pM and 0.45 mM, respectively. The results of detailed studies for optimising the analytical parameters, namely nioxime and buffer concentrations, pH, and adsorption potential are discussed. 

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