Halogens metal oxides

Sulfur dioxide Halogens, metal oxides, polymeric tubing, potassium chlorate, sodium hydride... 

Sulfides Sulfur Sulfur dioxide Sulfuric acid Sulfuryl dichloride Acids, powerful oxidizers, moisture Oxidizing materials, halogens Halogens, metal oxides, polymeric tubing, potassium chlorate, sodium hydride Chlorates, metals, HC1, organic materials, perchlorates, permanganates, water Alkalis, diethyl ether, dimethylsulfoxide, dinitrogen tetroxide, lead dioxide, phosphorus... 

Precaution Flamm. explosion limits 2-95% powerful reducing agent ignites violently with oxidants incompat. with Cu/alloys, brass, Fe, Fe salts, halogens, metal oxides, metallic Hg, org. materials dissolves and swells many plastics... 

Examples of halogen-metal oxide flame retardants Sb203 (1 0%) with chlorinated PP or phthalimide derivative (40-57% chlorine) with aliphatic or aromatic bromine compounds. 

Magnesium Air, beryllium fluoride, ethylene oxide, halogens, halocarbons, HI, metal cyanides, metal oxides, metal oxosalts, methanol, oxidants, peroxides, sulfur, tellurium... 

Phosphorus, white Air, oxidants of all types, halogens, metals... 

Hydrated metal oxides such as alumina hydrate are usually used alone because these are not synergistic with the halogens. They are useful ia apphcations ia which the halogens are excluded or low processing temperatures are used. 

DMF can also be manufactured from carbon dioxide, hydrogen, and dimethylamine ia the presence of halogen-containing transition-metal compounds (18). The reaction has also been performed with metal oxides and salts of alkaU metals as promoters (19). 

At elevated temperatures, CaH2 reacts with halogens, sulfur, phosphoms, alcohols, and ammonia. At high temperatures, it reacts with refractory metal oxides and haUdes. Calcium hydride is substantially inert to organic compounds that do not contain acidic hydrogens. 

Meta.1 Oxides. Halogen-containing elastomers such as polychloropreae and chlorosulfonated polyethylene are cross-linked by their reaction with metal oxides, typically ziac oxide. The metal oxide reacts with halogen groups ia the polymer to produce an active iatermediate which then reacts further to produce carbon—carbon cross-links. Ziac chloride is Hberated as a by-product and it serves as an autocatalyst for this reaction. Magnesium oxide is typically used with ZnCl to control the cure rate and minimize premature cross-linking (scorch). 

Cross-linking reactions for the polyisobutylene-type polymers depend on adding a reactive site, usually an aHyUc hydrogen or halogen. These reactive sites allow vulcanization with sulfur and accelerators or metal oxides (76,77). 

Other routes include the high-temperature halogenation of metal oxides, sometimes in the presence of carbon, to assist removal of oxygen the source of halogen can be X2, a volatile metal halide CX4 or another organic halide. A few examples of the many reactions that have been used industrially or for laboratory scale preparations are ... 

Experience has shown that the oxygen distribution in the products of a metallized military explosive favors the formation of the metal oxide. Any remaining oxygen then forms steam with the H of the expl. If any oxygen is still available it forms C02, and any unreacted C atoms then show up as free carbon in the products. (Confinement of the expls favors the formation of C02 and C at the expense of CO). In halogenated expls HX appears to be formed in preference to H20 and H2... 

It is not affected by halogens or acids, except for phosphoric and hydrofluoric acids. Phosphoric acid attacks fused silica at temperatures of 300-400°C, and hydrofluoric acid attacks it at room temperature, forming silicon tetrafluoride and water. At high temperatures silica reacts with caustic alkalis, certain metallic oxides, and some basic salts, and cannot be used for incinerating these materials. Over 1600°C, fused silica is reduced to silicon by carbon. It can also be reduced at high temperature by hydrogen. It is unaffected by water under normal conditions but is attacked by strong solutions of alkalis. 

This metal is very electropositive. In the powdered state it is extremely inflammable in the presence of a flame or simply when heated. It reacts violently with halogens and oxidants. 

See Potassium Non-metal oxides See other halogen oxides, oxidants... 

See Dichlorine oxide Halogens Metal nitrates Nitric acid, all above, Oxygen, below... 

See Carbon dioxide Halogens etc. Metal oxides Metal oxosalts, all above ... 

See Halogens or Interhalogens Metal halides Metal oxides Non-metal oxides, all above Ammonium nitrate Metals MRH 4.15/64... 

Halogens, or Interhalogens See Bromine pentalluoride Acids, etc. Chlorine trilluoride Metals, etc. Fluorine Non-metal oxides... 

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