Other halogen oxides

The decomposition of a number of inorganic compounds which contain both halogen and oxygen atoms, such as COCl2, NOC1, SOCl2, C102F, are discussed in Chapter 3. 

Studies of the decomposition of this substance have been carried out in order to further understanding of the mechanism of the deflagration of ammonium perchlorate440 and of the reactions occurring in perchloric acid fuel flames441. 

For temperatures in excess of 320 °C the gas-phase decomposition of anhydrous H0C103 (or of its dihydrate) is a homogeneous, unimolecular reaction close to its first-order limit at pressures in excess of 20 torr440. Levy440 obtained a value 

The subsequent reaction steps which lead to the overall stoichiometry HOCIO3 = 0.5 H2O+0.5 Cl2 +1.75 02 

1 JANAF Thermochemical Tables, D. R. Stull (Ed.), Dow Chemical Co., Midland, Mich., 1965. 

---

See other GLASS INCIDENTS See other HALOGEN OXIDES... 

Bailar, 1973, Vol. 2, 1388 Hydrolysis may proceed explosively. See other HALOGEN OXIDES... 

Dining preparation of tungsten(IV) dibromide oxide, appropriate proportions of reactants are heated in an evacuated sealed glass ampoule to 400-500°C. Initially only one end should be heated to prevent excessive pressure bursting the ampoule. See other GLASS INCIDENTS See other halogens, oxidants... 

See Potassium Non-metal oxides See other halogen oxides, oxidants... 

See Other HALOGEN OXIDES, OXIDANTS, OXYGEN FLUORIDES... 

See other halogen oxides, irradiation decomposition incidents, oxygen... 

See Trioxygen difluoride Various materials See other HALOGENS, OXIDANTS... 

Dioxygen dilluoride, 4320 Hexaoxygen dilluoride, 4327 Oxygen dilluoride, 4317 Trioxygen difluoride , 4323 See other halogen oxides... 

Two explosions were encountered in reactions involving the hypofluorite. See other HALOGEN OXIDES, HYPOHALITES, IODINE COMPOUNDS... 

---