Groundwater characteristics

Groundwater Characteristics of Differing Deposit Types Orogenic Gold... 

Simple indices such as this can be quite useful for ranking chemicals according to inherent leaching potential, but fall short of direct environmental relevance because they make no account of the soil and groundwater characteristics which exist in a given use zone. To factor in the latter, Aller et al. (23) developed a... 

Gordon, C., and Toze, S. 2003. Influence of groundwater characteristics on the survival of enteric viruses. J. Appl. Microbiol. 95 536—544. 

Groundwater monitoring is a necessary component in any investigation of subsurface contamination. A wide variety of information can be gleaned from the data including groundwater velocity and direction, and contaminant identification and concentration. These data can be combined with other observations to infer various characteristics of the contamination. Examples are source and timing of the release, and future location of the contaminant plume. 

A sohd waste is considered hazardous if it is either a Hsted waste or a characteristic waste. Listed wastes include a Hst of specific processes that generate a waste and a Hst of discarded commercial chemical products. There are four hazardous waste characteristics ignitabiHty, corrosivity, reactivity, and toxicity. The last refers to the leachabiHty of a waste and the resultant toxicity in the groundwater using the analytical method referred to as toxicity characteristic leaching procedure (TCLP). A Hst of substances included under TCLP is shown in Table 1. 

Leachate in landfills. Leachate may be defined as hquid that has percolated through sohd waste and has extracted dissolved or suspended materials from it. In most landfills, the liqiiid portion of the leachate is composed of the liquid produced from the decomposition of the wastes and liquid that has entered the landfill from external sources, such as surface drainage, rainfall, groundwater, and water form underground springs. Representative data on chemical characteristics of leachate are reported in Table 25-72. 

Pesticides vary widely in their chemical and physical characteristics and it is their solubility, mobility and rate of degradation which govern their potential to contaminate Controlled Waters. This, however, is not easy to predict under differing environmental conditions. Many modern pesticides are known to break down quickly in sunlight or in soil, but are more likely to persist if they reach groundwater because of reduced microbial activity, absence of light, and lower temperatures in the sub-surface zone. 

Many hydrologic reservoirs can be further subdivided into smaller reservoirs, each with a characteristic turnover time. For example, water resides in the Pacific Ocean longer than in the Atlantic, and the oceans surface waters cycle much more quickly than the deep ocean. Similarly, groundwater near the surface is much more active than deep reservoirs, which may cycle over thousands or millions of years, and water frozen in the soil as permafrost. Typical range in turnover times for hydrospheric reservoirs on a hillslope scale (10-10 m) are shown in Table 6-4 (estimates from Falkenmark and Chapman, 1989). Depths are estimated as typical volume averaged over the watershed area. 

As discussed before, groundwater samples can be collected when a sufficient volume of water has been removed from the well (e.g., three to five well volumes) and groundwater parameters have stabilized. If parameters have not stabilized after five well volumes have been removed, then the well may be sampled (acceptance of sampling following the fifth purge volume is dependent on the study objectives). Table 1 summarizes the criteria used for establishing the stability of groundwater parameters. The time intervals between the parameter measurements depend on the well characteristics and the hydraulic properties of the aquifer and must be sufficiently spaced to provide results representative of aquifer properties. ... 

The chemical preservation of a sample is dependent on the chemistry of the ground-water (e.g., pH) and on the chemical characteristics of the pesticide being studied. Preservatives can be added to the sample containers in the field or prepared in advance at the laboratory. To determine the need for a chemical preservative in the field (i.e., pH analyses), test the groundwater collected during the purging process and not the sample collected for analysis. 

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