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Graphite intercalation compound formation

Using dilatometry in parallel with cyclic voltammetry (CV) measurements in lmolL 1 LiC104 EC-l,2-dimethoxy-ethane (DME), Besenhard et al. [87] found that over the voltage range of about 0.8-0.3 V (vs. Li/Li+), the HOPG crystal expands by up to 150 percent. Some of this expansion seems to be reversible, as up to 50 percent contraction due to partial deintercalation of solvated lithium cations was observed on the return step of the CV. It was concluded [87] that film formation occurs via chemical reduction of a solvated graphite intercalation compound (GIC) and that the permselective film (SEI) in fact penetrates into the bulk of the HOPG. It is important to repeat the tests conducted by Besenhard et al. [87] in other EC-based electrolytes in order to determine the severity of this phenomenon. [Pg.435]

Dining interaction at ambient temperature in a bomb to produce poly (carbon monofluoride), admission of fluorine beyond a pressure of 13.6 bar must be extremely slow and carefully controlled to avoid a violently exothermic explosion [1], Previously it had been shown that explosive interaction of carbon and fluorine was due to the formation and decomposition of the graphite intercalation compound, poly (carbon monofluoride) [2], Presence of mercury compounds prevents explosion during interaction of charcoal and fluorine [3], Reaction of surplus fluorine with graphite or carbon pellets was formerly used as a disposal method, but is no longer recommended. Violent reactions observed when an exhausted trap was opened usually involved external impact on the metal trap, prodding the trap contents to empty the trap, or possibly ingress of moist air... [Pg.1513]

During interaction at ambient temperature in a bomb to produce poly(carbon monofluoride), admission of fluorine beyond a pressure of 13.6 bar must be extremely slow and carefully controlled to avoid a violently exothermic explosion [ 1 ]. Previously it had been shown that explosive interaction of carbon and fluorine was due to the formation and decomposition of the graphite intercalation compound, poly(carbon monofluoride)... [Pg.1574]

Ohzuku T, Iwakoshi Y, Sawai K. Formation of lithium-graphite intercalation compounds in nonaqueous electrolytes and their application as a negative electrode for a lithium ion (shuttlecock) cell. J Electrochem Soc 1993 140 2490-2498. [Pg.501]

GO does not seem to be suitable as a reversible battery electrode. The reason is the irreversible formation of covalent C-O(H) bonds in the course of anodic formation. According to Boehm and to Ubbelohde, graphite intercalation compounds do play the role of a precursor ... [Pg.393]

If GO is used as a host lattice for Li+ in aprotic electrolytes, reversibility is improved [577]. The potential level is distinctly more positive than with donor GIC, at about —1 V vs. SHE. An all-solid-state Li/GO battery with PE0/LiC104 as solid electrolyte was reported by Mermoux and Touzain [578], but rechargeability is poor. Recently, the structure of graphite oxide was studied by its fluorination at 50-2()0 °C [579]. C-OH bonds were transformed into C-F bonds. The examples, in conjunction with Section 2, show that the formation or cleavage of covalent C-O (C-F) bonds makes the whole electrochemical process irreversible. Application was attempted in lithium primary batteries, which have a voltage of 2-2.5 V. Really reversible electrodes are only possible, however, with graphite intercalation compounds, which are characterized by weak polar bonds. [Pg.393]

Reaction of graphite with [02] [AsFg] results in the formation of the salt [C8] [AsFg]. The catalytic properties of some graphite intercalation compounds render them of practical importance e.g. KCg is a hydrogenation catalyst. [Pg.348]

Cathodic reduction of graphite in dipolar aprotic solutions of alkali and [NRJ salts (e.g., in ethers, esters, amides) usually yields solvated cation intercalation compounds " however, at high cation density the solvent may be squeezed out . The corresponding phosphonium and sulfonium graphite intercalation compounds are unstable their formation is accompanied by reductive decomposition of these cations . [Pg.436]

Graphite Intercalation Compounds.— The reactions of graphitizable carbons leading to the formation of graphite intercalation compounds have been reviewed. Emphasis was placed on the insertion of alkali metals (Na), halogens (Brg), and acids (H2SO4). The effects of electronic structure and electron exchange on intercalation reactions were also considered. [Pg.238]

Another important feature for lithium graphite intercalation compounds in Li -containing electrolytes is the formation of solid electrolyte interface (SEI) film. During the first-cycle discharge of a lithium/carbon cell, a part of lithium atoms transferred to the carbon electrode electrochemically will react with the nonaque-ous solvent, which contributes to the initial irreversible capacity. The reaction products form a Lb-conducting and electronically insulating layer on the carbon surface. Peled named this film as SEI. Once SEI formed, reversible Lb intercalation into carbon, through SEI film, may take place even if the carbon electrode potential is always lower than the electrolyte decomposition potential, whereas further electrolyte decomposition on the carbon electrode will be prevented. [Pg.52]


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Compounds intercalation compound

Graphite compounds

Graphite intercalate

Graphite intercalates

Graphite intercalation

Graphite intercalation compound

Graphitic compounds

Intercalated graphite

Intercalates formation

Intercalating compounds

Intercalation compounds

Intercallation compounds

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