Glass fiber thermoplastics

Fig. 6.8. Fracture toughness, K, of short glass fiber-thermoplastics injection molded composites as a function of weight fraction of fiber, fVr. (O) and (A) polyethylene terephthalate (PET) matrix ( ) and (A) polycarbonate (PC) matrix. Notches made transverse (O, ) and parallel (A, A) to the mold fill direction,...

Fig. 6.9. Normalized fracture toughness, (Kc - AKQ)/K. of short glass fiber-thermoplastics injection molded composites as a function of reinforcing effectiveness parameter, ft (O) polyetheretherketone (PEEK) matrix (K = 6.5 MPa m) (A) polytetrafluoroethylene (PTFE) matrix (K = 1.9 MPaym).

In use are stamping compression molding presses. Plastic used can be TS sheet molding compounds (SMCs) and stampable reinforced thermoplastic sheet (STX) material (STX is a registered tradename Azdel Inc., Shelby, NC). It is usually composed of a glass fiber-thermoplastic RTP (Chapter 15). 

Table 9.12 Chemical resistant loss in tensile strength and flexural strain of glass fiber/thermoplastic (wt%) (courtesy of LNP)...

Problem Progress toward more affordable long-glass-fiber thermoplastic applications is limited by conventional com-pounding/moldlng practices. 

Vegetable Fiber/Glass Fiber Thermoplastic Composites... 

K. Behzad. Studies on Mechanical Characterization and Water Resistance of Glass Fiber/Thermoplastic Polymer Bio Nano composites. J. Appl. Polym. Sci. 123, 2396-2391 (2012). 

Kord, B. Studies on mechanical characterization and water resistance of glass fiber/ thermoplastic polymer bionanocomposites. JApplPolym Sci. 2012,123,2391-2396. 

PRODUCTION OF A TRACTOR CAB ROOF MODULE USING DIRECT IN-LINE COMPOUNDING OF LONG GLASS FIBER THERMOPLASTICS... 

Reinforced Thermoplastic Sheet. This process uses precombined sheets of thermoplastic resin and glass fiber reinforcement, cut into blanks to fit the weight and size requirements of the part to be molded. The blanks, preheated to a specified temperature, are loaded into the metal mold and the material flows under mol ding pressure to fiU the mold. The mold is kept closed under pressure until the temperature of the part has been reduced, the resin solidified, and demolding is possible. Cycle time, as with thermosetting resins, depends on the thickness of the part and the heat distortion temperature of the resin. Mol ding pressures are similar to SMC, 10—21 MPa (1500—3000 psi), depending on the size and complexity of the part. 

Polypropylene sheet has been used most extensively however, thermoplastic polyester, polycarbonate, and nylon versions are available (see Elastomers, synthetic Polycarbonates). Continuous strand glass fiber mat is the typical reinforcement. The limited number of sheet suppHers reduces potential for competitive pricing. 

Fig. 5. Interlaminar fracture toughness, for a number of thermosetting and thermoplastic composites (36,37). Open white bars represent glass-fiber composites shaded bars are for carbon fibers. The materials are A, polyester (unidirectional) B, vinyl ester (CSM = chopped strand mat) C, epoxy (R/BR1424) D, epoxy (T300/914) E, PPS F, PES and G, PEEK. To convert J/m to fdbf/in. multiply by 2100.

Poly(phenylene ether). The only commercially available thermoplastic poly(phenylene oxide) PPO is the polyether poly(2,6-dimethylphenol-l,4-phenylene ether) [24938-67-8]. PPO is prepared by the oxidative coupling of 2,6-dimethylphenol with a copper amine catalyst (25). Usually PPO is blended with other polymers such as polystyrene (see PoLYETPiERS, Aromatic). However, thermoplastic composites containing randomly oriented glass fibers are available. 

This material is a tme amorphous thermoplastic with a T of 185°C and can be made into thermoforming composite with 20—40 wt % glass fiber (see... 

Some of the common types of plastics that ate used ate thermoplastics, such as poly(phenylene sulfide) (PPS) (see Polymers containing sulfur), nylons, Hquid crystal polymer (LCP), the polyesters (qv) such as polyesters that ate 30% glass-fiber reinforced, and poly(ethylene terephthalate) (PET), and polyetherimide (PEI) and thermosets such as diaHyl phthalate and phenoHc resins (qv). Because of the wide variety of manufacturing processes and usage requirements, these materials ate available in several variations which have a range of physical properties. 

PPO is an engineering thermoplastic with excellent properties. To improve its mechanical properties and dimensional stability, PPO can he blended with polystyrene and glass fiber. Articles made from PPO could be used up to 330°C it is mainly used in items that require higher temperatures such as laboratory equipment, valves, and fittings. 

Thermoplastic RPs (RTPs), even with their relatively lower properties when compared to thermoset RPs (RTSs), consume about 55wt% of all RP products. Practically all of the RTPs are injection molded with very fast cycles using short glass fiber producing highly automated and high performance products. 

PBT is mainly used as glass-fiber-reinforced engineering thermoplastic, although PBT fibers can also be made. PBT crystallizes much more rapidly than PET and... 

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