Gallium phthalocyanine

Doping a nano-structured Ti02 electrode sensitized with tetrasulfonated gallium phthalocyanine with tetrasulfonated zinc porphyrin (ZnTsPP) greatly enhances the photoelectric conversion at long wavelengths, with 20- and 60-fold improvement of the quantum efficiency at 680 and 700 nm [195],... 

Another possible approach to the octupolar route is the axial substitution of appropriate metallic phthalocyanines. The introduction of a substituent in the axial position breaks the centrosymmetry of the Pc macrocycle and adds to the molecule a non-negligible octupolar character and a dipole moment perpendicular to the surface of the phthalocyanine. It is well-known that the combination of dipolar and octupolar features yields interesting NLO properties. Some examples of axially substituted phthalocyanines have been reported, namely, titanium(IV) [60], gallium(III) [60] and indium(III) derivatives [61] axially substituted by different ligands. Particularly, titanium and gallium phthalocyanines have been measured by EFISH and HRS. 

N. Brasseur, H. Ali, R. Langlois, J.E. van Lier (1987). Biological activities of phthalocyanines - VII. Photoinactivation of V-79 Chinese hamster cells by selectively sulfonated gallium phthalocyanines. Photochem. PhotobioL, 46,139-1AA. 

Approaches to the formation of condensed isoindolones 05COC1261. Axially modified gallium phthalocyanines and naphthalocyanines for optical limiting 05CSR517. 

Klofta, T., W.J. Buttner, and N.R. Armstrong (1986). Effect of crystallite size and hydrogen and oxygen uptake in the photoelectrochemistries of thin films of chloro-gallium phthalocyanine. J. Electrochem. Soc. 133, 1531-1532. 

Gallium alkoxides physical properties, 345 Gallium complexes dimethyl sulfoxide, 488 phthalocyanines, 863 porphyrins, 821 Gallium(III) complexes porphyrins evolution, 961 tropolones rearrangement, 382 Gallium isopropoxides synthesis... 

The synthesis, by Professor Malcolm Kenny at Case Western Reserve University, of a series of silicon phthalocyanine polymers (SiPc) (aggregates of the monomer of this series, m-SiPc, are discussed here) and of a series of aluminum and gallium, fluoro and chloro phthalocyanines (AIPc-Cl, GaPc-Cl, AIPc-Cl, GaPc-F) allowed us to study several oriented systems (16). 

Huly a Yanika, Duygu Ay dma, Mahmut Durmus. (2009). Peripheral and nonperipheral tetrasubstituted aluminum., gallium and indium phthalocyanines Synthesis, photophysics and photochemistry. J. Photochemistry and Photobiology A Chemistry 206,18-26. 

Phthalocyanines Copper indium diselenide (CuInSe2) Indium antimonide (InSb) indium phosphide (InP) Indium gallium nitride (InGaN) Cadmium telluride (CdTe)... 

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