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Further Implications

The experimental results in Fig. 26 have a further implication that the nominal value of surface energy does not associate directly with the friction level. The FFM measurements of friction force between gold surfaces and Si tips... [Pg.179]

As noted, deep-well-injected wastes are relatively dilute. Therefore, ignitability is not a significant consideration in deep-well injection, although in a concentrated form, individual compounds may exhibit this property. Ignitability has no further implications for the fate of deep-well-injected waste. [Pg.785]

As discussed below, if the two media used for separation in 2DLC are correlated with respect to the retention mechanism, the peak capacity will be lower than expected from the product approximation. The dependence of the peak capacity product on the correlation between retention mechanisms is covered in Chapter 3. Furthermore, as pointed out by Carr and coworkers (Stoll et al., 2006), if the second dimension sampling of the first dimension is undersampled, the potential peak capacity will not be able to be utilized. This is discussed in the theory of zone sampling section below. Further implications of peak capacity limitations due to sampling have been recently given by Tanaka and coworkers (Horie et al., 2007). [Pg.15]

The irreproducibility (98,100) of the Pesci decarboxylations [Eqs. (84) and (86)] (97,99) has further implications since the decarboxylation products were claimed to undergo novel nucleophilic displacements of mercury (96,97,99). Some reported nucleophilic demercurations of an authentic mercurial (96) could not be repeated (98). A Pesci type hemidecarboxylation of 5-norbornene-2,3-dicarboxylic acid has been reported by Takahashi (101), but this has also been found to be irreproduci-ble (101a). [Pg.261]

Further implications of this equation are that at one pH unit below or above the pKa, an ionizable group will be 91 percent unionized (protonated) or 91 percent ionized (unprotonated), respectively. Two pH units below or above translate to a 99 percent unionized or 99 percent ionized state. [Pg.14]

As a result of these investigations, it gradually became evident that in-sewer processes under aerobic conditions had further implications in terms of removing easily biodegradable organic matters from wastewater intended for advanced treatment. [Pg.249]

As a further implication, A// cannot be the same as a. In fact, from the Eyring theory, we can show readily that... [Pg.418]

The effects of longitudinal and transversal structures for the purpose of correcting waterways, however, has further implications for various key characteristics of waterways. Table 3 provides an overview ([55] modified). [Pg.86]

Let us consider some of the further implications of Figure 1.1. The view that cellular life can be arrived at from inanimate matter may imply in principle the possibility of reproducing it in the lab. Why not, if all we need is a bunch of molecules in a properly reactive environment This way of thinking is the basis of the experimental work on the origin of life. In fact, the best way to demonstrate the validity of this view would be to make life in the laboratory - the age-old Faustian dream. We do not know how the process of the transition to life really occurred in nature, so how can we reproduce it in the laboratory The answer to this question is conceptually simple, as pointed out by Escheiunoser and Kisakiirek (1996) ... [Pg.3]

From this mechanism the linear complex formed in reaction (47) may be visualized as the intermediate in the formation of the cyclic transition-state structure in step (48). Further implications of these quenching studies with respect to the mechanism of the primary bond-scission reaction (49) will be discussed in the next section. [Pg.257]

A system underpinned by commercially made screen-printed electrochemical cells was described by Palmisano et al. [19]. The cells were converted into biosensors for lactate in milk and yoghurt by addition of an electrochemically polymerised barrier to interference and a layer composed of lactate oxidase, glutaraldehyde and BSA. These steps appeared to have been carried out by hand. As there was no outer diffusion-limiting membrane, the linear range of the sensors was quite small (0-0.7 mM). They were incorporated into a FIA with a microdialysis unit based on a planar membrane and a buffer reservoir (earlier work used a microdialysis fibre with a platinum electrode [29]. The concentration of lactate was determined in various milks (0.27-1.64 mM), and in raw milk (c. 0.5-0.9 mM) left to degrade on the laboratory bench. The recovery of the microdialysis unit, 2.6%, implied that the sensor had an ability to return measurable currents for very low concentrations of lactate. A further implication is that the electro-polymerised layer was very effective at preventing interference. [Pg.672]

At this point, we should also mention some further implications of the impact of methanogenesis on diagenetic carbonates. Authigenic carbonates derived from DIC produced from the oxidation of methane according to... [Pg.421]

This is a reasonable energy, fairly close to half of the binding energy of H2 (103.5 kcal/mol) as expected for a hydrogenase enzyme. Further implications of these energies will be discussed at the end of this section where an energy diagram is constructed. [Pg.113]

This argument shows that the locality hypothesis fails for more than two electrons because the assumed Frechet derivative must be generalized to a Gateaux derivative, equivalent in the context of OEL equations to a linear operator that acts on orbital wave functions. The conclusion is that the use by Kohn and Sham of Schrodinger s operator t is variationally correct, but no equivalent Thomas-Fermi theory exists for more than two electrons. Empirical evidence (atomic shell structure, chemical binding) supports the Kohn-Sham choice of the nonlocal kinetic energy operator, in comparison with Thomas-Fermi theory [288]. A further implication is that if an explicit approximate local density functional Exc is postulated, as in the local-density approximation (LDA) [205], the resulting Kohn-Sham theory is variation-ally correct. Typically, for Exc = f exc(p)p d3r, the density functional derivative is a Frechet derivative, the local potential function vxc = exc + p dexc/dp. [Pg.74]

Earlier studies have shown that alpinigenine (82) is derived from two molecules of tyrosine67 by way of tetrahydropalmatine (79) and possibly its N-methyl derivative (80).68 Recent results69 further implicate (79) and (80), which were... [Pg.17]

For politics and society to come to reasonable decisions about risks in public interest, it is not enough to consider only the results of (scientific) risk assessment. In order to understand the concerns of people affected and various stakeholders, information about both risk perceptions and the further implications of the direct consequences of a risk is needed and should be taken into account by risk management.3... [Pg.16]

For comparison, the measured adsorption rate for PNP to the air/water interface gave a rate constant of it = 4.4 0.2 x 10 s but a desorption rate of 6 2 s [52]. The rapid adsorption to the air/water interface is quite consistent with the very rapid establishment of the SHG signal from PNP at the dodecane/water interface observed in these flow cell experiments. However, the observed decay rate constant in the presence of TBP of ca. 0.5 s is much faster than the desorption rate constant that would be implied from the air/water experiments. This further implicates a reorganization process involving bonding between TBP and PNP as the cause of the loss of SHG intensity, which results in an overall loss of orientational order. [Pg.13]

A further implication is that the coefficient of friction of a fully-burnished film is probably determined more by the burnishing pressure then by the subsequent operating pressure, since the films represented by the horizontal line apparently have similar surfaces while the operating pressures vary from 1.5 to lOOOMPa. [Pg.55]

We now consider the further implications of this argument. It may be shown that the correct result is obtained for the temperature dependence of the equilibrium vapour pressure. At equilibrium it is assumed that there are atoms bound by two bonds and 2 bound by one bond. Because of the difference between and... [Pg.158]


See other pages where Further Implications is mentioned: [Pg.61]    [Pg.173]    [Pg.95]    [Pg.82]    [Pg.125]    [Pg.304]    [Pg.388]    [Pg.89]    [Pg.733]    [Pg.289]    [Pg.206]    [Pg.35]    [Pg.733]    [Pg.423]    [Pg.17]    [Pg.213]    [Pg.151]    [Pg.97]    [Pg.125]    [Pg.73]    [Pg.218]    [Pg.13]    [Pg.14]    [Pg.219]    [Pg.164]    [Pg.76]    [Pg.127]    [Pg.279]    [Pg.251]    [Pg.174]    [Pg.184]   


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