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Pyrroles furans

Figure 8.15 The carbon Is X-ray photoelectron spectra of furan, pyrrole and thiophene. The sulphur Ip spectrum of thiophene is also shown. (Reproduced with permission from Gelius, U., Allan, C. J., Johansson, G., Siegbahn, H., Allison, D. A. and Siegbahn, K., Physica Scripta, 3, 237, 1971)... Figure 8.15 The carbon Is X-ray photoelectron spectra of furan, pyrrole and thiophene. The sulphur Ip spectrum of thiophene is also shown. (Reproduced with permission from Gelius, U., Allan, C. J., Johansson, G., Siegbahn, H., Allison, D. A. and Siegbahn, K., Physica Scripta, 3, 237, 1971)...
Metal-Induced Cycloadditions. The effect of coordination on the metal-iaduced cyclo additions of maleic anhydride and the isostmctural heterocycles furan, pyrrole, and thiophene has been investigated (47). Each heterocycle is bound to an Os(II) center in the complex... [Pg.450]

NH2)50s(2,3-T -L)], where L = furan, pyrrole, and thiophene. Although neither the furan nor thiophene complexes react with maleic anhydride over a period of 10 days, the pyrrole complex (15) reacts rapidly at room temperature and 101.3 kPa to form a mixture of endo (17) and exo (16) complexes. An a2omethine ylide intermediate was postulated as the key intermediate through which maleic anhydride added to the 2- and 5-positions of the coordinated pyrrole ring. [Pg.450]

There are several examples of the formation of pyridazines from other heterocycles, such as azirines, furans, pyrroles, isoxazoles, pyrazoles or pyrans and by ring contraction of 1,2-diazepines. Their formation is mentioned in Section 2.12.6.3.2. [Pg.52]

The much less sophisticated PPP approximation has been shown to well reproduce the electronic spectral features not only of the monocyclic furan, pyrrole, thiophene, selenophene and tellurophene but also many of the benzo fused derivatives as well (79MI30101, 68JPC3975, 68MI30100). [Pg.3]

Dihydrofuran (376) and 2,5-dihydrofuran (377) react with nitrile oxides to give furo[2,3-6 ]isoxazoles (378) and furo[3,4-rf]isoxazoles (379), respectively, as cycloadducts. The double bonds of furan, pyrrole and thiophene also react when the nitrile oxide is generated in situ. Thus furan and benzonitrile oxide gave (380), and with 2-methyl-2-oxazoline the cycloadduct (381) was obtained (71AG(E)810). These and related cycloadditions are discussed in Chapter 4.36. [Pg.148]

Table 7 also indicates that the rate enhancements for a 3- and 5-methyl group vary significantly among 1,2-azoles. The difference between the increments in log units for a 3-and 5-methyl group, which should vary directly with bond fixation in the ground state, is larger for isoxazole (1.4) than for pyrazole (0.7) and for isothiazole (0.2). This indicates that the aromaticity increases in the same order and contributes the first quantitative evidence that the 1,2-azoles follow the same aromaticity order as furan < pyrrole < thiophene. [Pg.22]

The heteroaromatic compounds can be divided into two broad groups, called n-excessive and n-deficient, depending on whether the heteroatom acts as an electron donor or an electron acceptor. Furan, pyrrole, thiophene, and other heterocyclics incorporating an oxygen, nitrogen, or sulfur atom that contributes two n electrons are in the rr-exeessive group. This classification is suggested by resonance structures and confirmed by various MO methods. ... [Pg.569]

In a series of papers in late 1884 and early 1885, Paal and Knorr demonstrated that several 1,4-dicarbonyls could be transformed into furans, pyrroles, and thiophenes. Paal first discovered this transformation and used it to prepare di-, tri-, and tetrasubstituted furans. For example, dicarbonyl 3 yielded disubstituted furan 4 upon treatment with weak acid. [Pg.168]

B. Conjugate Acids 1. Furan, Pyrrole, and Thiophene Cations... [Pg.93]

Chemistry of conjugated heterocycles built from furan pyrrole, or thiophene ring fused with bicyclic (norbomadiene, bomene, or azanorbomene) skeletons 98YGK192. [Pg.246]

Fischer-type carbene complexes in the synthesis of furan, pyrrole, 5//-furanone, and 5//-pyrrolone derivatives 98YGK413. [Pg.246]

With respect to aromatic substrates, the Vilsmeier formylation reaction works well with electron-rich derivatives like phenols, aromatic amines and aromatic heterocycles like furans, pyrroles and indoles. However various alkenes are also formylated under Vilsmeier conditions. For example the substituted hexatriene 6 is converted to the terminal hexatrienyl aldehyde 7 in 70% yield ... [Pg.281]

The Electron Diffraction Investigation of the Structure of Benzene, Pyridine, Pyrazine, Butadiene-1,3, Cyclopentadiene, Furan, Pyrrole, and Thiophene... [Pg.657]

Fig. 5.—-Calculated intensity curves for furan, pyrrole, and thiophene. Fig. 5.—-Calculated intensity curves for furan, pyrrole, and thiophene.
Furan, Pyrrole, and Thiophene.-—The carbon-heteroatom distances found in furan, pyrrole, and thiophene correspond to 5 = = 5%, 12 = = 6%, and 17 = = 10% double-bond character, respectively. Resonance of the normal structure I with structures of the types II and III (X = O, NH, S) is assumed to be responsible for this double-bond character, while excited structures characteristic... [Pg.665]

Keywords furans, pyrroles, thiophenes, phospholes, oxazoles, pyrones, pyr-idones, oxazinones, high pressure... [Pg.323]

The use of microwaves for the preparation of aromatic five-membered heterocycles has been intensely investigated with excellent results in terms of yields and purities of the products prepared. The Paal-Knorr reaction, namely the cyclocondensation of a 1,4-dicarbonyl compound to give furans, pyrroles and thiophenes has been successfully carried out with the aid of microwaves. [Pg.217]

One may consider phospholes to belong to the family of five-membered P-heterocycles pyrrole, furan, and thiophene. A significant difference, however, is that the phospholes described in the literature display only a slight extent of aromaticity. This is well demonstrated by the comparison of the Bird-indexes [32] of benzylphosphole [33], furan, pyrrole, and thiophene (Fig. 1). The Bird-index is an indicator of aromaticity based on the bond-equalizaton. It is the maximum (100) for benzene. [Pg.152]

The heteroaromatic compounds like furans, pyrroles or thiophenes cannot be generally used as dienes in Diels-Alder syntheses, because at the higher temperature required for the addition of less reactive dienophiles, the equilibrium is on the side of the starting materials due to the unfavorable T AS term comparable to the benzenoid aromatic compounds as mentioned. High pressure again shows the two effects already discussed the shift of the equilibrium toward the products and the enhancement of the rate of reaction which allows the temperature of reaction to be lowered. One... [Pg.575]


See other pages where Pyrroles furans is mentioned: [Pg.326]    [Pg.69]    [Pg.3]    [Pg.14]    [Pg.14]    [Pg.16]    [Pg.16]    [Pg.30]    [Pg.33]    [Pg.8]    [Pg.85]    [Pg.315]    [Pg.946]    [Pg.194]    [Pg.657]    [Pg.666]    [Pg.667]    [Pg.668]    [Pg.159]    [Pg.69]    [Pg.280]    [Pg.43]    [Pg.858]    [Pg.272]    [Pg.118]    [Pg.526]    [Pg.580]    [Pg.111]    [Pg.199]   
See also in sourсe #XX -- [ Pg.314 ]




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