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Functionalities tertiary amine basic

The higher activity of primary amines in the reaction involving enones as Michael acceptors has also been extended to the use of different bifunctional catalysts (Scheme 3.19), which usually contain a primary amine functionality connected to a basic site by means of a chiral scaffold, as is the case in the use of 280 and 55. These diamine catalysts have been found to be excellent promoters of the Michael reaction of enones with cyclic 1,3-dicarbonyl compounds and malonates respectively, the tertiary amine basic site present at the catalyst structure being responsible for assisting in the deprotonation of the Michael donor in order to increase the concentration of the nucleophile species. In a different approach, bifunctional thiourea-primary amine catalyst 56a has also... [Pg.84]

To synthesize new surfactants, having incorporated both structural elements, the known siloxanyl modified halogenated esters and ethers of dicyclopentadiene [5] were treated with different amines according to the reaction scheme. Triethylamine yielded quaternary ammonium salts directly. Alternatively, after reaction with diethylamine or morpholine, the isolated siloxanyl-modified tertiary amines were also converted to quaternary species. To obtain anionic surfactants, the halogenated precursors were initially reacted with n-propylamine. In subsequent reaction steps the secondary amines formed were converted with maleic anhydride into amides, and the remaining acid functions neutralized. Course and rate of each single reaction strongly depended on the structure of the initial ester or ether compound and the amine applied. The basicity of the latter played a less important role [6]. [Pg.267]

Titration experiments on the nitrile-terminated dendrimers in water show for DAB-dendr-(CN)A pKa values of 3.2 and 4.8. The corresponding calculated pKa values are 3.1 and 4.1 respectively (using the pKalc program, version 2.0, Com-pudrug chemistry). For DAB-dendr-(CN)s only the two inner nitrogen atoms can be protonated in acetonitrile, due to the low basicity of the four other ones. This is confirmed with calculated pKa values of the four outer tertiary nitrogen atoms in DAB-dendr-(CN)s, ranging from 2.0 to 3.2. The presence of the electropositive nitrile-functions and the protonated inner tertiary amines can account for this phenomenon. [Pg.613]

A number of other heterocycllcs have been similarly studied and shown by H nmr, to produce quaternary ammonium salts with living polyTHF.2- Moreover, their rates of reaction are a direct function of their basicities, the following order of reactivities being observed ethyl pyridine > pyridine > isoquinoline > quinoline > acridine. Aliphatic tertiary amines also react in the same way the order of reactivities was found to be triethylame > tributylamlne > dlethylanillne. In all cases studied, the quaternary ammonium salt once formed did not exchange with any excess oxonium lone. [Pg.347]

Tertiary amines catalyze the homopolymerization of epoxy resins in the presence of hydroxyl groups, a condition which generally exists since most commercial resins contain varying amounts of hydroxyl functionality (B-68MI11501). The efficiency of the catalyst depends on its basicity and steric requirements (B-67MI11501) in the way already discussed for amine-catalyzed isocyanate reactions. A number of heterocyclic amines have been used as catalytic curatives pyridine, pyrazine, iV,A-dimethylpiperazine, (V-methylmorpholine and DABCO. Mild heat is usually required to achieve optimum performance which, however, is limited due to the low molecular weight polymers obtained by this type of cure. [Pg.406]

The structures of some of the better known plant alkaloids are shown in Figure 23-1. You will recognize some of them by name even if you have never seen their structures before. Many of the alkaloids are polycyclic structures and have other functional groups in addition to basic nitrogen. You will see that the nitrogens of alkaloids frequently are tertiary amine functions. [Pg.1098]

Commercially available basic resins that are available employed for neutralizing HC151 contain a tertiary amine or pyridinyl functionality, which readily traps proton species. Some examples are amine-based morpholinomethyl (3) and piperidinemethyl (4) resins (Fig. 3). [Pg.397]

A simple method of modifying promoiety acidity or basicity is to select other more acidic or basic ionizable functional groups. Convenient solubilizing moieties for ester prodrugs where the formulation pH should be between 3.5 and 5 would be those containing eithersulfonicKypid or tertiary amine ( ia > 8) functionalities. Quaternary ammonium-containing moieties, such as the choline esters mentioned earlier, would also be excellent choices for water-soluble derivatives if solubility was the only consideration (Anderson and Conradi, 1987). [Pg.440]

The central ring systems found to yield antiviral compounds have included fluorene (fluorenone), dibenzofuran, dibenzothiophene, fluoranthene, anthraquinone, acenaphthene, xanthene, thioxanthene, phenothiazine, carbazole, phenanthrene and others. The side chains were represented by basic ethers, basic ketones, basic esters plus carboxamides, sulphonamides, alkanols, methylene and others attached to the various ring systems. The amine function was usually substituted to the tertiary amine with various alkyl substituents although a few ring types (e.g., pyrrole or piperidino) were synthesized. [Pg.126]


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Amines basicity

Amines functionality

Amines functions

Amines tertiary

Basicity function

Functional amine

Functionality basic

Functionalized amines

Tertiary amine functionality

Tertiary basic functionality

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