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2- formyl-7-methyl

Benzyloxy-3-oxo-1 -(formyl-methyl)- 495 exo-4, exo-9-Dihydroxy-exo-l-methyl-endo-5-(2-carboxy-athyl)-trans- 312... [Pg.950]

Oxidation of one molar proportion with sodium pieriodate produces two equivalents of formic acid, in accordance with the existence of hydroxyl groups attached to four contiguous carbon atoms. This oxidation (and also that carried out with lead tetraacetate) gives an aldehyde, whose semicar-bazone has an analysis corresponding to that of the semicarbazone of an ethyl formyl-methyl-furoate (XII). By oxidation of aldehyde XII with silver oxide in alkaline solution, 2-methyl-3,4-furandicarboxylic acid (XIV) was obtained this was identical with the compound described by Alder and Rickert.20 The identity was confirmed by preparation of the respective dianilides. The acid XIV has also been prepared by the reaction between the sodium salt of ethyl acetoacetate and ethyl bromopyruvate.9... [Pg.106]

CHj cho HjS/H3C - OH/wenig Piperidin 10-20", 30 min 2-A mino-3-formyl- /-methyl-indol 94 2... [Pg.975]

Antagonists of riboflavin include isoriboflavin, lumiflavin, aiaboflavin, hydroxyethyl analogue, formyl methyl analogue, galactoflavin, and flavin-monosulfate. Synergists include vitamins A. B, B(l, and B12, niacin, pantothenic acid, folic acid, biotin, tetraiodothyronine (thyroxine), insulin, and somatotrophin (growth hormone). [Pg.1700]

The use of iodoacetic acid as an aryl radical trapping agent has confirmed the intermediacy of aryl radicals in some hydrodediazoniation reactions, whether these are initiated or not.4 Spontaneous hydrodediazoniation of aryldiazonium fluoroborates occurs in warm dimethylformamide (DMF). Detailed study5 of the conversion of the 4-nitro derivative into nitrobenzene indicates a homolytic mechanism in which H-atom abstraction occurs from both sites in DMF with a formyl methyl preference of 3.5 1.0. High yields of mixed perfluorinated biaryls may be obtained by the catalytic dediazoniation of pentafluorobenzenediazonium ions in acetonitrile containing aromatic substrates and small amounts of iodide salts. The catalytic role of iodide and the isomeric product distributions indicate that arylation proceeds through the pentafluorophenyl radical in an efficient homolytic chain process.6... [Pg.242]

In 1 ml of ether was dissolved 20 mg of the crude 4b-methyl-ip,2a-bis-(2-formylmethyl)-2p-formyl-4p,7a-dihydroxyperhydrophenanthrene ip-methyl acetal 2p,4p-lactol methyl ether 7a-acetate. To this was added 3 ml of 70% aqueous acetic acid, and the homogeneous solution was allowed to stand at room temperature to 10 h. The material was extracted with ether, and extract was washed with aqueous sodium bicarbonate, dried over magnesium sulfate and concentrated to dryness under reduced pressure, yielding 15 mg of 4b-methyl-ip, 2a-bis-(2-formyl methyl)-2p-formyl-4p,7 a-dihydroxyperhydrophenanthrene 2p,4p-lactol 7a-acetate. [Pg.140]

Paukert JL, Straus LD, and Rahinowitz JC (1976) Formyl-methyl-methylenetetrahydro-folate synthetase- (combined). An ovine protein with multiple catalytic activities./owr-nal of Biological Chemistry 251, 5104-11. [Pg.446]

Dialkylamino-(formyl-methyl-amino)- E14a/3, 563 (CH20 + H3C-NH-CH0/ SOCl2 R2NH)... [Pg.47]

Acetyl-methyl- E4, 993 (Ethoxy-methylen)- E4, 995 (1-Methoxy-ethyliden)- E4, 995 3H-Diazirin 3-(Formyl-methyl)-3-methyl- E16c, 720 (Acetal-Spaltung)... [Pg.154]

Amin (Acetoxy-methyl)-formyl-methyl- IV/lb, 1025 Butanal 2-Methyl-4-nitro- E16d, 203 (M ichael-Addition)... [Pg.220]

Ether Bis-[(Formyl-methyl-ami-no)-methyl]- IV/lb, 1025 Hexansanre 6-Nitro- -amid E5, 1106... [Pg.313]

Methan (Benzyl-ethyl-amino)-(formyl-methyl-amino)- E14a/3, 563 (CH20 + HjC-NH-CHO/SOCl2 R2NH) 1,2,5-Oxadiazin 5-Phenyl-2-propyl-tetrahydro- E16a, 312 (aus Imidazolidin)... [Pg.1050]

Azetidin 3-Azido-l-(diethoxyphos-phoryl-methoxycarbonyl-methyl)-cis-4-(formyl-methyl)-2-oxo- E16b, 372 (Acetai CHO)... [Pg.1060]

Benzol 3-Acetamino-2-(formyl-methyl)-l -(2-methoxy-2-hydro-peroxy-ethyl)- IV/la, 31 Bernsteinsaure 2-(N-Benzyl-... [Pg.1163]

Formyl-methyl)-3-melhyl-7-(4-methyl-3-penlenyl)- 1209 Blcyclo 3.1. Ojhexane... [Pg.3335]

Acetoxy-7-(formyl-methyl)-7-(4-melhyl-3-pentenyl)- 1735 Cyclopropane... [Pg.3344]

H2C osW OC2H5 Q OC2H5 OHCT (2S, 3R, 6S)-2-Ethoxy-3-formyl-methyl-2-[(4-nitrobenzoyloxy-methyl]-2,3-dihydro-6Fl-pyran ... [Pg.571]

See other pages where 2- formyl-7-methyl is mentioned: [Pg.84]    [Pg.198]    [Pg.202]    [Pg.855]    [Pg.325]    [Pg.955]    [Pg.70]    [Pg.111]    [Pg.325]    [Pg.145]    [Pg.1108]    [Pg.424]    [Pg.134]    [Pg.325]    [Pg.153]    [Pg.281]    [Pg.575]    [Pg.588]    [Pg.634]    [Pg.963]    [Pg.986]    [Pg.1052]    [Pg.1137]    [Pg.1181]    [Pg.3227]    [Pg.3230]    [Pg.561]    [Pg.562]    [Pg.15]    [Pg.15]    [Pg.569]   
See also in sourсe #XX -- [ Pg.84 ]



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1 - benzyl - 5 - formyl - 2 - methyl

2- formyl-3-thienyl methyl

2- methoxy carbonyl- 1-methyl-, formylation

2-Formyl-l-methyl

3-Formyl-3-methyl-2- -2,3-dihydro

3-Methyl-2 -quinoxalinone formylation

5-Formyl-4-methyl-2-phenyl

Aldehydes (s. a. Formyl hydrocarbons (methyl groups

Dichloromethyl methyl ether formylation with

Ethyl 1 - butyl - 4 - formyl - 2 - methyl

Ethyl 4-formyl-2-methyl

Methyl 2 -formyl-2-diphenylcarboxylate

Methyl formyl acetate

Pyrrole 5-formyl-2-methyl-, ethyl ester

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