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Fluoride alkylation

Safety in the Operation of Hydrogen Fluoride Alkylation Plants. Universal Oil Products Co., Booklet No. 252. [Pg.231]

Although the basic chemical reactions have been thought, for many years, to be similar with either sulfuric or hydro -fluoric acid catalyst, extensive work with sulfuric acid described by Albright et al (24) has demonstrated that this is probably not the case. The need for more detailed work with hydrofluoric acid is cited. The following summarizes their report "The reaction mechanism for hydrogen fluoride alkylation also seems to be radically different than that for sulfuric acid alkylation. The alkylation mechanism which has been widely accepted in the past seems to be somewhat more satisfactory for hydrogen fluoride alkylation even though it is not for sulfuric acid... [Pg.318]

Tetra-n-butylammonium fluoride. ALKYL ARYL KETONES Cyanotrimethylsilane. [Pg.572]

In the first step of the reaction, a carbocation is formed from the reaction of an alkyl halide with AICI3. Alkyl fluorides, alkyl chlorides, alkyl bromides, and alkyl iodides can all be used. Vinyl halides and aryl halides cannot be used because their carbocations are too unstable to be formed (Section 10.8). [Pg.613]

Products with low 2-phenyl isomer content (13-22%) are produced by hydrogen fluoride alkylation of internal olefins from paraffin dehydrogenation. High 2-phenyl products (25-35%) are produced from aluminium chloride alkylation of chloroparaffins. Generally, high 2-phenyl products are preferred for use in liquid detergent applications because of the improved solubility found with the higher 2-phenyl level. Low 2-phenyl alkylates... [Pg.1032]

TABLE 6.8. Sulfuric Acid and Hydrogen Fluoride Alkylation. [Pg.219]

Benson, R., Safety in. . . Hydrogen Fluoride Alkylation Plants, Pei. Refiner, December, 1943, p. 116. [Pg.737]


See other pages where Fluoride alkylation is mentioned: [Pg.198]    [Pg.102]    [Pg.221]    [Pg.873]    [Pg.48]    [Pg.169]    [Pg.245]    [Pg.112]    [Pg.112]    [Pg.124]    [Pg.294]    [Pg.856]    [Pg.62]    [Pg.62]    [Pg.62]   
See also in sourсe #XX -- [ Pg.229 , Pg.230 , Pg.253 ]




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Alkali metal fluorides alkyl halides

Alkyl fluoride-SbF5 complexes

Alkyl fluoride-antimony pentafluoride

Alkyl fluorides

Alkyl fluorides

Alkyl fluorides Fluoroalkanes

Alkyl fluorides Friedel-Crafts reaction, intermediate

Alkyl fluorides Friedel-Crafts reactions

Alkyl fluorides cleavage

Alkyl fluorides conductivity

Alkyl fluorides dissolving metals

Alkyl fluorides fluonde

Alkyl fluorides metal-ammonia

Alkyl fluorides mixture with antimony fluoride

Alkyl fluorides primary

Alkyl fluorides reduction with lithium aluminum hydride

Alkyl fluorides synthesis

Alkyl fluorides synthesis carboxylic acids

Alkyl fluorides synthesis fluorination

Alkyl fluorides synthesis nucleophilic substitution

Alkyl fluorides via Ireland silyl ester enolate rearrangement

Alkyl fluorides, activation

Alkyl fluorides, preparation

Alkyl fluorides, pyrolysis

Alkyl fluorides, reduction

Alkyl silyl-fluorides

Alkylation boron fluoride

Alkylation hydrogen fluoride

Alkylation hydrogen fluoride catalyst

Alkylation tetrabutylammonium fluoride

Alkylation using supported fluorides

Alkylation with hydrogen fluoride catalyst

Alkylation with isopropyl fluoride

Bicyclic Alkyl Fluorides

Fluoride-ion mediated desilylative alkylations

From Alkyl Tellurium Trifluorides and Cesium Fluoride

Hydrogen fluoride alkyl alcohols

Hydrogen fluoride, catalyst for alkylations

Hydrogen fluoride, liquid alkylation

Potassium alkyl fluoride reduction

Preparation from Alkyl Fluorides in Antimony Pentafluoride Solution

Preparation from Alkyl Fluorides in Antimony Pentafluoride Solution and Spectroscopic Studies

Secondary Alkyl Fluorides

Synthesis of Alkyl Fluorides

Tert-Butyl fluoride, alkylation with

Tertiary Alkyl Fluorides

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