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Alkyl fluorides Friedel-Crafts reaction, intermediate

Concerning my research during my Dow years, as I discuss iu Chapter 4, my search for cationic carbon intermediates started back in Hungary, while 1 was studying Friedel-Crafts-type reactions with acyl and subsequently alkyl fluorides catalyzed by boron trifluoride. In the course of these studies I observed (and, in some cases, isolated) intermediate complexes of either donor-acceptor or ionic nature. [Pg.72]

Because of their Lewis acidity, the MX5 species, usually the fluorides or the chlorides, can act as catalysts in cyclotrimerizing or linearly polymerizing acetylenes (although in the latter case metal alkylidene intermediates may be important) and in Friedel-Crafts and related alkylation reactions. They also polymerize THF and can catalyze the hydrolysis of acetonitrile.21... [Pg.902]


See other pages where Alkyl fluorides Friedel-Crafts reaction, intermediate is mentioned: [Pg.84]    [Pg.25]    [Pg.102]    [Pg.514]    [Pg.299]    [Pg.310]    [Pg.387]   
See also in sourсe #XX -- [ Pg.3 , Pg.299 ]

See also in sourсe #XX -- [ Pg.299 ]

See also in sourсe #XX -- [ Pg.3 , Pg.299 ]




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Alkyl fluorides

Alkyl fluorides Friedel-Crafts reactions

Alkyl intermediate

Fluoride alkylation

Friedel Crafts alkylation

Friedel-Crafts alkylations

Friedel-Crafts reaction : alkylation

Friedel-Crafts reaction alkylation reactions

Friedel-Crafts reaction intermediates

Friedel-Crafts reactions alkylations

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