Flue gases furnace

Molasses Bagasse Filter muds Flue gases Furnace ash... 

Example 6.4 The process in Fig. 6.2 is to have its hot utility supplied by a furnace. The theoretical flame temperature for combustion is 1800°C, and the acid dew point for the flue gas is 160°C. Ambient temperature is 10°C. Assume = 10°C for process-to-process heat transfer but = 30°C for flue-gas-to-process heat transfer. A high value for for flue-gas-to-process heat... 

Desulfurize the flue gas. A whole range of processes have been developed to remove SO, from flue gases, such as injection of limestone into the furnace, absorption into wet limestone after the furnace, absorption into aqueous potassium sulfite after the furnace, and many others.However, the byproducts from many of these desulfurization processes cause major disposal problems. 

Assessments of control, operabiHty and part load performance of MHD—steam plants are discussed elsewhere (rl44 and rl45). Analyses have shown that relatively high plant efficiency can be maintained at part load, by reduction of fuel input, mass flow, and MHD combustor pressure. In order to achieve efficient part load operation the steam temperature to the turbine must be maintained. This is accompHshed by the use of flue gas recirculation in the heat recovery furnace at load conditions less than about 75% of fiiU load. 

PPS fiber has excellent chemical resistance. Only strong oxidising agents cause degradation. As expected from inherent resia properties, PPS fiber is flame-resistant and has an autoignition temperature of 590°C as determined ia tests at the Textile Research Institute. PPS fiber is an excellent electrical iasulator it finds application ia hostile environments such as filter bags for filtration of flue gas from coal-fired furnaces, filter media for gas and liquid filtration, electrolysis membranes, protective clothing, and composites. 

After the waterwaH tubes deHver the saturated steam back into the top of the boHer dmm, moisture is separated out by a series ofbaffl.es, steam separators, and cormgated screens. The water removed drops down into the hot water contained in the steam dmm. The steam travels out through either a dry pipe, which leads to a superheater header, or a series of superheater tubes that connect directiy into the top of the steam dmm. The superheater tubes wind back into the top of the furnace and/or a hot flue-gas backpass section, next to the economizer, where heat from the combustion gases exiting the furnace superheats the steam traveling through the tubes. 

In ECS s 1986 repowefing project Babcock and Wilcox (B W) constmcted a bubbling-bed section to ECS s existing 125 MWe pulverized-coal furnace to produce 31.3 t/h of lime, usiag cmshed coal as the source of heat to calciae limestone ia the fluidized bed. A portion of the lime is drawn from the bed as bottom ash and a portion is collected as fly ash. Both portions are transferred to a cement (qv) plant adjacent to the boiler. The hot flue gas from the EBC flows iato the existing main pulverized-coal furnace, ia which a B W LIMB system was also iastaHed to absorb sulfur dioxide dufing those times when the EBC is not operating. 

Efficiency. Since only 35 to 50% of fired duty is absorbed in the radiant section, the flue gas leaving the radiant chamber contains considerable energy that can be extracted efficiently in the convection section of the furnace. In the convection section, the feed is preheated along with dilution steam to the desired crossover temperature. Residual heat is recovered by generating steam. The overall thermal efficiency of modem furnaces exceeds 93%, and a value of 95% is not uncommon. 

Instead of gas turbine exhaust, air preheat has been used in some plants to reduce fuel consumption. Flue gas leaving the furnace stack passes through an air preheater, and the preheated air is suppHed to the burners. By using mostly hearth burners, the duct work and the investment cost can be minimised with air preheat and gas turbine exhaust. It is also possible with 100% waH-fired furnaces, and has been proven in commercial operation (34). 

In AFBC units, heat is removed from the flue gas by a convection-pass tube bank. The particulates leaving the boiler with the flue gas consist of unreacted and spent sorbent, unburned carbon, and ash. Multiclones after the convection pass remove much of the particulate matter and recvcle it to the combustor, increasing the in-furnace residence time an improving combustion efficiency and sulfur retention performance. Bubbling PFBC units do not have convection-pass tube banks and do not recycle solids to the boiler. 

FIG. 27-35 Low-NOj burner with air-staging and flue-gas recirculation for use in bigh-temperature furnaces. (Hauck Manufactuiing Company. Developed and patented by the Gas Research Institute.)... 

Flue gas recirculation (FGR) is the rerouting of some of the flue gases back to the furnace. By using the flue gas from the economizer outlet, both the furnace air temperature and the furnace oxygen concentration can be reduced. However, in retrofits FGR can be very expensive. Flue gas recirculation is typically applied to oil- and gas-fired boilers and reduces NO, emissions by 20 to 50%. Modifications to the boiler in the form of ducting and an energy efficiency loss due to the power requirements of the recirculation fans can make the cost of this option higher. 

Maximize the recovery of sulfur by operating the furnaces to increase the SO, content of the flue gas and by providing efficient sulfur conversion. Use a double-contact, double-absorption process. 

Natural gas containing 98% methane and 2% nitrogen by volume is burned in a furnace with 15% excess air. The fuel consumption is 20 cubic meters per second, measured at 290°K and 101.3 kPa (or 14.7 psia). The problem is to determine how much air is required under these conditions. In addition, we want to determine the baseline environmental performance of the furnace by calculating the quantity and composition of the flue gas. 

By this method it is possible to determine the total concentration of reduced-sulfur compounds or the concentration of TRS compounds, as in a paper pulp plant. The oxidation temperature of the furnace is about 800 °C. The flue gas must contain a minimum of 1% oxygen to ensure that all TRS compounds are fully oxidized to sulfur dioxide. 

By recirculating a part of the flue gas to the furnace, the combustion zone turbulence is increased, the temperature is lowered and the oxygen concentration is reduced. All of these factors lead to a reduction of NO, fonnation. 

Postcombustion processes are designed to capture NO, after it has been produced. In a selective catalytic reduction (SCR) system, ammonia is mixed with flue gas in the presence of a catalyst to transform the NO, into molecular nitrogen and water. In a selective noncatalytic reduction (SNCR) system, a reducing agent, such as ammonia or urea, is injected into the furnace above the combustion zone where it reacts with the NO, to form nitrogen gas and water vapor. Existing postcombustion processes are costly and each has drawbacks. SCR relies on expensive catalysts and experiences problems with ammonia adsorption on the fly ash. SNCR systems have not been proven for boilers larger than 300 MW. 

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